氮化硼纳米片的制备及其在电解水中应用的研究进展
收稿日期: 2025-02-17
网络出版日期: 2025-09-23
基金资助
国家自然科学基金项目(21501103);山东省科技型中小企业创新能力提升工程项目(2023TSGC0580);山东师范大学本科生科研基金项目(BKJJ2025058)
Research progress on preparation of boron nitride nanosheets and its application in water electrolysis
Received date: 2025-02-17
Online published: 2025-09-23
氢能源一直被认为是化石能源最有潜力的替代者。电解水制氢是一种简单有效的方法，但其中涉及的析氢和析氧反应均为缓慢的动力学过程，这严重阻碍了电解水制氢的商业化应用，因此开发低成本、高效、稳定的催化剂来提升电解水的效率是当前迫切需要解决的问题。氮化硼纳米片因其具有独特的二维结构、优异的抗氧化性、热稳定性、宽带隙等特点，使其在电解水析氢和析氧反应中表现出优异的电催化活性。因此，氮化硼纳米片在电解水领域中有着广阔的应用前景。论文综述了近些年国内外氮化硼纳米片的主要制备方法，包括机械剥离法、化学剥离法和化学气相沉积，并分析了这些方法的优缺点。同时，还综述了氮化硼纳米片在电解水领域中应用的研究进展，包括析氢反应和析氧反应。最后，对氮化硼纳米片在制备方法和电解水领域的未来发展趋势进行了展望。
杜淼 , 刘琦 , 王佳仪 , 董浩然 , 牛静 , 黄馨仪 , 殷九洲 , 于长江 . 氮化硼纳米片的制备及其在电解水中应用的研究进展[J]. 无机盐工业, 2025 , 57(9) : 13 -20 . DOI: 10.19964/j.issn.1006-4990.2025-0073
Hydrogen energy is considered to be one of the most potential alternative energy sources for fossil energy.Hydrogen production by electrolysis of water is a simple and effective method，but the hydrogen evolution reaction（HER） and oxygen evolution reactions（OER） involved in this process are slow kinetic reactions which seriously hindering the commercialization of hydrogen production by water electrolysis.Therefore，the development of low-cost，efficient and stable catalysts to improve the efficiency of the water electrolysis process is an urgent problem to be solved.Boron nitride nanosheets（BNNSs） have shown excellent catalytic activity in the electrochemical hydrogen and oxygen evolution，due to their unique two-dimensional structure，excellent oxidation resistance，thermal stability and wide gap.Therefore，BNNSs showed broad application prospect in the field of water splitting.The main preparation methods of BNNSs at home and abroad in recent years were reviewed，including mechanical stripping，chemical exfoliation and chemical vapor deposition，and their advantages and disadvantages were analyzed.In addition，the application of BNNSs in water electrolysis was reviewed，including HER and OER.Finally，the current problem and solution were summarized and the future research direction was prospected.
| [1] | IHSANULLAH I.Boron nitride-based materials for water purification：Progress and outlook［J］.Chemosphere，2021，263：127970. |
| [2] | WENG Qunhong， WANG Xuebin， WANG Xi，et al.Functionalized hexagonal boron nitride nanomaterials：Emerging properties and applications［J］.Chemical Society Reviews，2016，45（14）：3989-4012. |
| [3] | ZHANG Huanhuan， LIU Yanyan， SUN Kang，et al.Applications and theory investigation of two-dimensional boron nitride nanomaterials in energy catalysis and storage［J］.EnergyChem，2023，5（6）：100108. |
| [4] | WU Min， YANG Liusi， ZHOU Yuanliang，et al.BaTiO3-assisted exfoliation of boron nitride nanosheets for high-temperature energy storage dielectrics and thermal management［J］.Chemical Engineering Journal，2022，427：131860. |
| [5] | 杜淼，张光荣.石墨烯的制备及其应用研究进展［J］.无机盐工业，2019，51（3）：12-15. |
| DU Miao， ZHANG Guangrong.Progress in preparation and application of graphene［J］.Inorganic Chemicals Industry，2019，51（3）：12-15. | |
| [6] | YUAN Hao， LI Ting， WANG Yang，et al.Surface modification of BNNS bridged by graphene oxide and Ag nanoparticles：A strategy to get balance between thermal conductivity and mechanical property［J］.Composites Communications，2021，27：100851. |
| [7] | CAI Qiran， LI Luhua， MATETI S，et al.Boron nitride nanosheets：Thickness-related properties and applications［J］.Advanced Functional Materials，2024，34（40）：2403669. |
| [8] | JIANG Hao， XIE Yuhui， HE Mukun，et al.Highly thermally conductiveand flame-retardant waterborne polyurethane composites with 3D BNNS bridging structures via MagneticField assistance［J］.Nano-Micro Letters，2025，17（1）：138. |
| [9] | WANG Yang， YANG Zhaohui， JIA Bingzheng，et al.Natural deep eutectic solvent-assisted construction of silk nanofibrils/boron nitride nanosheets membranes with enhanced heat-dissipating efficiency［J］.Advanced Science，2024，11（36）：2403724. |
| [10] | WANG Congling， LONG Yanyang， DENG Yuxian，et al.Hexagonal boron nitride nanomaterials for biomedical applications［J］.BMEMat，2024，2（2）：e12068. |
| [11] | ROY S， ZHANG Xiang， PUTHIRATH A B，et al.Structure，properties and applications of two-dimensional hexagonal boron nitride［J］.Advanced Materials，2021，33（44）：2101589. |
| [12] | WU Ni， YANG Wang， CHE Sai，et al.Green preparation of high-yield and large-size hydrophilic boron nitride nanosheets by tannic acid-assisted aqueous ball milling for thermal management［J］.Composites Part A：Applied Science and Manufacturing，2023，164：107266. |
| [13] | CHEN Shaohua， XU Runzhang， LIU Jiaman，et al.Simultaneous production and functionalization of boron nitride nanosheets by sugar-assisted mechanochemical exfoliation［J］.Advanced Materials，2019，31（10）：1804810. |
| [14] | WU Zijian， WANG Zhengfang， WANG Meng，et al.Preparation of sandwich-structured thermally conductive and insulating composite materials based on electrospinning combined with hot pressing technology［J］.Advanced Composites and Hybrid Materials，2024，8（1）：69. |
| [15] | SHAN Qian， DING Qihui， WANG Xiyan，et al.Electrochemical preparation of hydroxylated boron nitride nanosheets for solid-state flexible supercapacitors using deep eutectic solvent and water mixture as electrolytes［J］.Langmuir，2022，38（26）：8169-8178. |
| [16] | SHAN Qian， SHI Xiaofei， WANG Xiyan，et al.Preparation of functionalized boron nitride nanosheets by high-gravity liquid phase exfoliation technology［J］.Chemical Engineering and Pro-cessing-Process Intensification ，2021，169：108602. |
| [17] | GAUTAM C， CHELLIAH S.Methods of hexagonal boron nitride exfoliation and its functionalization：Covalent and non-covalent approaches［J］.RSC Advances，2021，11（50）：31284-31327. |
| [18] | LI Yongwei， HUANG Taoqing， CHEN Min，et al.Simultaneous exfoliation and functionalization of large-sized boron nitride nano-sheets for enhanced thermal conductivity of polymer composite film［J］.Chemical Engineering Journal，2022，442：136237. |
| [19] | WANG Ning， YANG Guang， WANG Haixu，et al.A universal method for large-yield and high-concentration exfoliation of two-dimensional hexagonal boron nitride nanosheets［J］.Materials Today，2019，27：33-42. |
| [20] | YAMADA H， INOTSUME S， KUMAGAI N，et al.Chemical vapor deposition growth of BN thin films using B2H6 and NH3 ［J］.Phy- sica Status Solidi（b），2020，257（2）：1900318. |
| [21] | ZENG Xianghui， CHEN Hui， WU Jinfeng，et al.Growth of vertically aligned BN nanosheets via Fe-catalyzed thermal chemical vapor deposition［J］.Ceramics International，2022，48（3）：3489-3494. |
| [22] | WANG Heng， XU Man， PING Hang，et al.Surface-diffusion mechanism for synthesis of substrate-free and catalyst-free boron nitride nanosheets［J］.Journal of the European Ceramic Society，2020，40（15）：5324-5331. |
| [23] | YIN Teng， LONG Liyuan， TANG Xian，et al.Advancing applications of black phosphorus and BP-analog materials in photo/electrocatalysis through structure engineering and surface modulation［J］.Advanced Science，2020，7（19）：2001431. |
| [24] | WANG Ran， HAN Jiecai， XU Ping，et al.Dual-enhanced doping in ReSe2 for efficiently photoenhanced hydrogen evolution reaction［J］.Advanced Science，2020，7（9）：2000216. |
| [25] | SUN Hongming， TIAN Caiying， FAN Guilan，et al.Boosting activity on Co4N porous nanosheet by coupling CeO2 for efficient electrochemical overall water splitting at high current densities［J］.Advanced Functional Materials，2020，30（32）：1910596. |
| [26] | ZHANG Jian， ZHANG Qiuyu， FENG Xinliang.Support and interface effects in water-splitting electrocatalysts［J］.Advanced Materials，2019，31（31）：1808167. |
| [27] | MU Xueqin， GU Jiani， FENG Feiyan，et al.RuRh bimetallene nanoring as high-efficiency pH-universal catalyst for hydrogen evolution reaction［J］.Advanced Science，2021，8（2）：2002341. |
| [28] | LI Meng， WANG Xuan， LIU Kun，et al.Reinforcing Co-O covalency via Ce（4f）─O（2p）─Co（3d） gradient orbital coupling for high-efficiency oxygen evolution［J］.Advanced Materials，2023，35（30）：2302462. |
| [29] | LI Zesheng， LI Bolin， YU Mei，et al.Amorphous metallic ultrathin nanostructures：A latent ultra-high-density atomic-level catalyst for electrochemical energy conversion［J］.International Journal of Hydrogen Energy，2022，47（63）：26956-26977. |
| [30] | HE Yongmin， LIU Liren， ZHU Chao，et al.Amorphizing noble metal chalcogenide catalysts at the single-layer limit towards hydrogen production［J］.Nature Catalysis，2022，5（3）：212- 221. |
| [31] | CHENG Hongfei， YANG Nailiang， LIU Guigao，et al.Ligand-exchange-induced amorphization of Pd nanomaterials for highly efficient electrocatalytic hydrogen evolution reaction［J］.Advanced Materials，2020，32（11）：1902964. |
| [32] | DONG Jinhu， GAO Lijun， FU Qiang.Hexagonal boron nitride meeting metal：A new opportunity and territory in heterogeneous catalysis［J］.The Journal of Physical Chemistry Letters，2021，12（39）：9608-9619. |
| [33] | ZHU Yinlong， LIN Qian， ZHONG Yijun，et al.Metal oxide-based materials as an emerging family of hydrogen evolution electrocatalysts［J］.Energy & Environmental Science，2020，13（10）：3361-3392. |
| [34] | BAI Yichao， XU Youan， SUN Linxuan，et al.Two-dimensional nanosheets by liquid metal exfoliation［J］.Advanced Materials，2025，37（8）：2416375. |
| [35] | SHARMA A， CHAKRABORTY B.Role of intrinsic point defects on electrocatalytic activity of a metal-free two-dimensional Poly-aramid for enhanced hydrogen evolution reaction［J］.International Journal of Hydrogen Energy，2024，85：299-309. |
| [36] | SUN Kaian， WU Xueyan， ZHUANG Zewen，et al.Interfacial water engineering boosts neutral water reduction［J］.Nature Communications，2022，13：6260. |
| [37] | SHTANSKY D V， MATVEEV A T， PERMYAKOVA E S，et al.Recent progress in fabrication and application of BN nanostructures and BN-based nanohybrids［J］.Nanomaterials，2022，12（16）：2810. |
| [38] | BAWARI S， KALEY N M，PAL S，et al.On the hydrogen evolution reaction activity of graphene-hBN van der Waals heterostructures［J］.Physical Chemistry Chemical Physics，2018，20（22）：15007-15014. |
| [39] | GUHA Anku， VEETTIL VINEESH T， SEKAR A，et al.Mechanistic insight into enhanced hydrogen evolution reaction activity of ultrathin hexagonal boron nitride-modified Pt electrodes［J］.ACS Catalysis，2018，8（7）：6636-6644. |
| [40] | TOMBOC G M， KIM T， JUNG S，et al.Modulating the local coordination environment of single-atom catalysts for enhanced catalytic performance in hydrogen/oxygen evolution reaction［J］.Small，2022，18（17）：2105680. |
| [41] | PRABAKARAN K， INGAVALE S B， KAKADE B.Three dimensional NiS2-Ni（OH）2/CNT nanostructured assembly for supercapacitor and oxygen evolution reaction［J］.Journal of Alloys and Compounds，2020，812：152126. |
| [42] | ZHAO Jie， GUO Yue， ZHANG Zhiqi，et al.Out-of-plane coordination of iridium single atoms with organic molecules and cobalt-iron hydroxides to boost oxygen evolution reaction［J］.Nature Nanotechnology，2024，20（1）：57-66. |
| [43] | XIE Xiaohong， DU Lei， YAN Litao，et al.Oxygen evolution reaction in alkaline environment：Material challenges and solutio-ns［J］.Advanced Functional Materials，2022，32（21）：2110036. |
| [44] | ZHAI Panlong， WANG Chen， ZHAO Yuanyuan，et al.Regulating electronic states of nitride/hydroxide to accelerate kinetics for oxygen evolution at large current density［J］.Nature Communications，2023，14：1873. |
| [45] | ZHANG Xiao， YAN Feng， MA Xinzhi，et al.Regulation of morphology and electronic structure of FeCoNi layered double hydroxides for highly active and stable water oxidization cataly-sts［J］.Advanced Energy Materials，2021，11（48）：2102141. |
| [46] | WANG Yi， YANG Rong， DING Yajun，et al.Unraveling oxygen vacancy site mechanism of Rh-doped RuO2 catalyst for long-lasting acidic water oxidation［J］.Nature Communications，2023，14：1412. |
| [47] | YU Mingquan， BUDIYANTO E， TüYSüZ H.Principles of water electrolysis and recent progress in cobalt-，nickel-，and iron-based oxides for the oxygen evolution reaction［J］.Angewandte Chemie International Edition，2022，61（1）：e202103824. |
| [48] | CHEN Hui， LIANG Xiao， LIU Yipu，et al.Active site engineering in porous electrocatalysts［J］.Advanced Materials，2020，32（44）：2002435. |
| [49] | ZHANG Rongrong， PAN Lun， GUO Beibei，et al.Tracking the role of defect types in Co3O4 structural evolution and active motifs during oxygen evolution reaction［J］.Journal of the American Chemical Society，2023，145（4）：2271-2281. |
| [50] | ZHAO Changxin， LIU Jianing， WANG Juan，et al.Recent advances of noble-metal-free bifunctional oxygen reduction and evolution electrocatalysts［J］.Chemical Society Reviews，2021，50（13）：7745-7778. |
| [51] | JOSHI P， YADAV R， HARA M，et al.Contribution of B，N-co-doped reduced graphene oxide as a catalyst support to the activity of iridium oxide for oxygen evolution reaction［J］.Journal of Materials Chemistry A，2021，9（14）：9066-9080. |
| [52] | SHAH A K， QURESHI M. In situ grown cuboidal MnCo2O4/h boron nitride heterojunction：A noble metal-free approach based on efficient hole extraction for electrochemical oxygen evolution reaction［J］.ACS Applied Energy Materials，2022，5（2）：1551-1559. |
| [53] | HAO Yixin， HUNG S F， TIAN Cheng，et al.Polarized ultrathin BN induced dynamic electron interactions for enhancing acidic oxygen evolution［J］.Angewandte Chemie International Edition，2024，63（18）：e202402018. |
| [54] | ZHAN Wei， WANG Hongyan， GAO Jinling，et al.Hexagonal boron nitride/reduced graphene oxide heterostructures as promising metal-free electrocatalysts for oxygen evolution reaction driven by boron radicals［J］.Small Structures，2023，4（11）：2300167. |
| [55] | ZHAO Guoqiang， LUO Zhouxin， ZHANG Baohua，et al.Epitaxial interface stabilizing iridium dioxide toward the oxygen evolution reaction under high working potentials［J］.Nano Research，2023，16（4）：4767-4774. |
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