无机盐工业
主管:中海油天津化工研究设计院有限公司
主办:中海油天津化工研究设计院有限公司
   中海油炼油化工科学研究院(北京)有限公司
   中国化工学会无机酸碱盐专业委员会
ISSN 1006-4990 CN 12-1069/TQ
催化材料

催化裂化过程中铁的钝化机理及其对催化剂抗铁污染性能的影响

  • 杜晓辉 ,
  • 刘涛 ,
  • 薛亚刚 ,
  • 王世存 ,
  • 高雄厚
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  • 1.中国石油石油化工研究院兰州化工研究中心,甘肃 兰州 730060
    2.中国石油石油化工研究院昆冈 先进制造(北京)有限公司,甘肃 兰州 730060
    3.中国石油兰州石化分公司,甘肃 兰州 730060
杜晓辉(1983— ),男,博士,高级工程师,研究方向为炼油催化剂及新材料;E-mail:duxiaohui01@petrochina.com.cn
高雄厚(1963— ),男,博士,教授级高级工程师,研究方向为炼油催化剂新技术、新材料、新工艺;E-mail:gaoxionghou@petrochina.com.cn

收稿日期: 2024-12-20

  网络出版日期: 2025-06-12

Passivation mechanism of iron in catalytic cracking and its effect on catalyst′s anti⁃iron contamination performance

  • DU Xiaohui ,
  • LIU Tao ,
  • XUE Yagang ,
  • WANG Shicun ,
  • GAO Xionghou
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  • 1. Lanzhou Petrochemical Research Center,Petrochemical Research Institute,PetroChina,Lanzhou 730060,China
    2. Kungang Advanced Manufacturing(Beijing) Co. ,Ltd. ,Petrochemical Research Institute,PetroChina,Lanzhou 730060,China
    3. Lanzhou Petrochemical Company,PetroChina,Lanzhou 730060,China

Received date: 2024-12-20

  Online published: 2025-06-12

摘要

以氧化镁、活性氧化铝和硝酸镧为原料,通过喷雾干燥法制备催化裂化金属捕集助催化剂CatClean,以提升催化裂化催化剂的抗铁污染性能,制备的金属捕集助催化剂CatClean主要由质量分数为60%的MgO与质量分数为30%的La2O3组成,磨损指数为1.3%/h。采用浸渍法进行铁污染,在催化裂化催化剂中添加或未添加CatClean的情况下,通过XRD、XPS、NH3-TPD、H2-TPR、EDX-Mapping等方法研究抗铁组分对催化剂反应性能的影响。结果表明:铁污染导致催化裂化催化剂的比表面积显著降低;在高温水热条件下,CatClean中的La2O3与铁反应生成稳定的LaFeO3相,可有效抑制铁对催化剂的负面影响,未观察到MgFe2O4相的生成。EDX-Mapping结果进一步表明,铁元素可在催化剂与CatClean颗粒间迁移并被有效捕集。反应性能评价结果表明,当铁污染量为1.0%(质量分数)时,在反应转化率基本相当的条件下,焦炭产率降低0.78%~0.98%、干气产率降低0.30%~0.33%、总液收增加0.91%~0.95%,显著降低催化剂的副产物选择性,提高催化剂的抗铁污染性能。

本文引用格式

杜晓辉 , 刘涛 , 薛亚刚 , 王世存 , 高雄厚 . 催化裂化过程中铁的钝化机理及其对催化剂抗铁污染性能的影响[J]. 无机盐工业, 2026 , 58(1) : 115 -122 . DOI: 10.19964/j.issn.1006-4990.2024-0689

Abstract

To enhance the resistance of catalytic cracking catalysts to iron contamination,a metal⁃trapping additive named CatClean was developed using magnesium oxide(MgO),activated alumina(Al2O3),and lanthanum nitrate[La(NO33] as raw materials via a spray drying method.The resulting CatClean was primarily consist of 60% MgO and 30% La2O3,with a wear index of 1.3%/h.Iron contamination was introduced through an impregnation method,and the effects of CatClean on catalyst performance were systematically investigated using XRD,XPS,NH3-TPD,H2-TPR,and EDX-Mapping techniques.The results indicated that iron contamination significantly reduced the surface area of the catalytic cracking catalyst.Under high⁃temperature hydrothermal conditions,La2O3 in CatClean reacted with iron to form a stable LaFeO3 phase,effectively mitigating the adverse effects of iron:No formation of MgFe2O4 was detected.EDX-Mapping further revealed that iron species could migrate between catalyst and CatClean particles and be effectively captured.Performance evaluations demonstrated that at an iron contamination level of 1.0%,the addition of CatClean reduced the coke yield by 0.78%~0.98%,the dry gas yield by 0.30%~0.33%,and increased the total liquid yield by 0.91%~0.95%,without significantly affecting conversion.These findings confirmed that CatClean significantly reduced the selectivity toward undesired by⁃products and enhanced the catalyst′s resistance to iron contamination.

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