无机盐工业
主管:中海油天津化工研究设计院有限公司
主办:中海油天津化工研究设计院有限公司
   中海油炼油化工科学研究院(北京)有限公司
   中国化工学会无机酸碱盐专业委员会
ISSN 1006-4990 CN 12-1069/TQ
工业技术

固定床过氧化氢生产工艺后处理工序的应用探讨

  • 成小强 ,
  • 马俊 ,
  • 冯彬 ,
  • 白立光 ,
  • 赵晓东
展开
  • 黎明化工研究设计院有限责任公司,河南 洛阳 471000
成小强(1987— ),男,硕士,化工工程师,主要研究方向为过氧化氢技术及过程强化工作;E-mail:chengzhiqiangcool@163.com

收稿日期: 2024-04-07

  网络出版日期: 2025-02-20

Discussion on application of post-treatment process in fixed bed hydrogen peroxide production process

  • CHENG Xiaoqiang ,
  • MA Jun ,
  • FENG Bin ,
  • BAI Liguang ,
  • ZHAO Xiaodong
Expand
  • Liming Research and Design Institute of Chemical Industry Co. ,Ltd. ,Luoyang 471000,China

Received date: 2024-04-07

  Online published: 2025-02-20

摘要

针对真空脱水技术和碱塔技术在过氧化氢后处理工序的应用效果,分别从工作液脱水、降解物再生、工作液中过氧化氢的分解和运行成本等方面进行了对比分析和探讨。其中,碱塔脱水量为0.65 g/L,真空脱水量为0.83 g/L。工作液经碱塔处理后,过氧化氢质量浓度由0.25 g/L降至0.03 g/L;真空脱水处理的工作液中过氧化氢含量维持不变。工作液经碱塔处理后,总有效蒽醌增量为1.62~2.12 g/L,蒽醌再生率为1.43%~1.90%;而真空技术采用物理除水,不具备再生作用。真空脱水的运行成本约为碱塔运行成本的1/4。结果表明,真空脱水技术的脱水能力和运行成本优于后者,但碱塔技术具有一定的工作液再生能力和分解工作液中过氧化氢的能力。最后,分别从再生剂改进和再生工艺改进两方面进行了概述。

本文引用格式

成小强 , 马俊 , 冯彬 , 白立光 , 赵晓东 . 固定床过氧化氢生产工艺后处理工序的应用探讨[J]. 无机盐工业, 2025 , 57(2) : 98 -104 . DOI: 10.19964/j.issn.1006-4990.2024-0192

Abstract

In view of the application effect of vacuum dehydration technology and alkali tower technology in hydrogen peroxide post-treatment process,it was analyzed and discussed from four aspects:dehydration of working fluid,degradation regeneration,decomposition of hydrogen peroxide in working fluid and comparison of operating costs.Among them,the removal water of alkali tower was 0.65 g/L,and the removal water of vacuum was 0.83 g/L.The content of hydrogen peroxide was decreased from 0.25 g/L to 0.03 g/L when the working liquid was treated by alkali tower.The hydrogen peroxide content in the working liquid of vacuum dehydration treatment remained unchanged.The increment of total available anthraquinone was 1.62~2.12 g/L and the regeneration rate of anthraquinone was 1.43%~1.90%.The vacuum technology adopted physical water removal without regenerative effect.The operating cost of vacuum dehydration was about 1/4 of the operating cost of alkali towers.The data results showed that the dehydration capacity and operating cost of vacuum dehydration technology were better than the latter,but the alkali tower technology had a certain capacity of working fluid regeneration and decomposition of hydrogen peroxide in the working fluid.Finally,the research progress of the regeneration of biodegradants in working fluids was summarized from two aspects:the improvement of regenerant and the improvement of regeneration process.

参考文献

1 杨盟飞,冯彬,白立光,等.蒽醌法制过氧化氢技术研究进展[J].化学推进剂与高分子材料202422(1):25-32.
  YANG Mengfei, FENG Bin, BAI Liguang,et al.Research progress in technology preparing hydrogen peroxide by anthraquinone process[J].Chemical Propellants & Polymeric Materials202422(1):25-32.
2 成小强,李鹏翔,冯彬,等.蒽醌法制备过氧化氢用钯催化剂的再生及科学使用探讨[J].化学推进剂与高分子材料202220(6):25-30.
  CHENG Xiaoqiang, LI Pengxiang, FENG Bin,et al.Discussion on regeneration and scientific use of palladium catalysts for preparation of hydrogen peroxide by anthraquinone process[J].Chemical Propellants & Polymeric Materials202220(6):25-30.
3 潘智勇,邢定峰.过氧化氢市场现状和技术发展趋势[J].现代化工202141(4):11-16.
  PAN Zhiyong, XING Dingfeng.Market status and technology development trend of hydrogen peroxide[J].Modern Chemical Industry202141(4):11-16.
4 沈冲,庞飞,柴春玲,等.磷酸三辛酯的合成工艺概况[J].化学推进剂与高分子材料202119(6):1-7.
  SHEN Chong, PANG Fei, CHAI Chunling,et al.Overview of synthesis process of trioctyl phosphate[J].Chemical Propellants & Polymeric Materials202119(6):1-7.
5 刘向来.真空脱水在双氧水生产中的应用[J].无机盐工业201446(7):47-50.
  LIU Xianglai.Application of vacuum dehydration in hydrogen peroxide production[J].Inorganic Chemicals Industry201446(7):47-50.
6 陈四海,蔡志伟,龚凌,等.四丁基脲代替磷酸三辛酯用于过氧化氢生产[J].石油化工200332(6):470-473.
  CHEN Sihai, CAI Zhiwei, GONG Ling,et al.Tetra-n-butyl urea substituted for tri-iso-octyl phosphate to manufacture H2O2 [J].Petrochemical Technology200332(6):470-473.
7 许颖睿,庞飞,申敬敬,等.一种过氧化氢生产用萃取塔:中国,116236813A[P].2023-06-09.
8 初铭玥,吴美岩,唐春,等.过氧化氢工作液中蒽醌降解物再生剂研究现状[J].无机盐工业201850(11):7-10.
  CHU Mingyue, WU Meiyan, TANG Chun,et al.Recent advances in regenerant of anthraquinone degradation products in working solution of hydrogen peroxide[J].Inorganic Chemicals Industry201850(11):7-10.
9 邓明杨,张晓昕,宗保宁.蒽醌加氢法生产过氧化氢工业催化剂中的科学问题[J].中国科学:化学202151(7):896-904.
  DENG Mingyang, ZHANG Xiaoxin, ZONG Baoning.Scientific issues in industrial catalysts for anthraquinone hydrogenation to produce hydrogen peroxides[J].Scientia Sinica Chimica202151(7):896-904.
10 庞飞,许颖睿,柴春玲,等.蒽醌法过氧化氢生产工艺中废弃活性氧化铝的回收利用研究概况[J].无机盐工业202355(6):1-7,49.
  PANG Fei, XU Yingrui, CHAI Chunling,et al.Overview on recycling of waste activated alumina in production of hydrogen peroxide by anthraquinone process[J].Inorganic Chemicals Industry202355(6):1-7,49.
11 周伟,王红琴,安霓虹,等.过氧化氢生产中新型氧化铝再生剂工业应用实验[J].无机盐工业201850(12):44-46.
  ZHOU Wei, WANG Hongqin, AN Nihong,et al.Industrial application of new alumina regenerant for hydrogen peroxide working solution[J].Inorganic Chemicals Industry201850(12):44-46.
12 庞飞,许颖睿,柴春玲,等.蒽醌法过氧化氢生产工艺中废弃活性氧化铝的回收利用研究概况[J].无机盐工业202355(6):1-7,49.
  PANG Fei, XU Yingrui, CHAI Chunling,et al.Overview on recycling of waste activated alumina in production of hydrogen peroxide by anthraquinone process[J].Inorganic Chemicals Industry202355(6):1-7,49.
13 赵珒,袁恩先,王莅.氧化镁/γ-氧化铝催化蒽醌法工艺降解物再生过程研究[J].无机盐工业201547(6):70-73.
  ZHAO Jin, YUAN Enxian, WANG Li.Regenerations of degradation products in anthraquinone process of hydrogen peroxide production over MgO/γ-Al2O3 catalysts[J].Inorganic Chemicals Industry201547(6):70-73.
14 陈振.蒽醌降解物再生固体碱催化剂制备及性能研究[D].北京:北京化工大学,2019.
15 程义,梁希慧,朱朝莹,等.CaO和MnO2双修饰的γ-Al2O3催化再生乙基蒽醌工作液[J].化学反应工程与工艺201834(5):431-439.
  CHENG Yi, LIANG Xihui, ZHU Chaoying,et al.CaO and MnO2-modified γ-Al2O3 catalyzed the regeneration of ethyl anthraquinone working solution[J].Chemical Reaction Engineering and Technology201834(05):431-439.
16 李亚北.新型固体镁基催化剂的构筑及其蒽醌降解物再生催化性能研究[D].北京:北京化工大学,2021.
17 史振宇,孙小惠,张旭旺,等.一种用于蒽醌法制备双氧水工作液的再生剂及其应用:中国,112551541B[P].2022.10.11.
18 H·堺谷,井浦克弘,萩原猪佐夫,等.过含工作液再生工序的过氧化氢制造方法:中国,101421184B[P].2011-04-13.
19 庞飞,许颖睿,马俊,等.一种蒽醌法生产过氧化氢用工作液的后处理新工艺:中国,114180773A[P].2022-03-15.
20 卿光宗,杨华,刘光昌,等.蒽醌法全酸性工作液体系制备双氧水的方法:中国,103496674B[P].2015-02-18.
21 张永泽,王珂.高效2-乙基蒽醌催化再生系统:中国,113045396A[P].2021-06-29.
文章导航

/