农林业废弃物改性硫氧镁生态板的制备及性能研究
收稿日期: 2024-08-01
网络出版日期: 2024-09-09
基金资助
教育部产学合作协同育人项目(231104429103410);成都理工大学“四新项目式”课程教学改革项目(11100-000114-22155);青海省高原绿色建筑与生态社区重点实验室开放基金计划项目(KLKF-2021-009)
Study on preparation and properties of agriculture and forestry waste modified magnesium oxysulfide ecological board
Received date: 2024-08-01
Online published: 2024-09-09
复合生态板是一种新型环保材料,广泛应用于整体橱柜、室内装修、室内地板等领域。为了制备综合性能更优、环保价值更高的新型板材,以硫氧镁生态板为研究对象,通过扫描电子显微镜(SEM)、X射线衍射(XRD)、表观密度测试、抗压强度测试等表征手段,探究了农林业废弃物的种类及其掺量对生态板结构和性能的影响。研究结果表明:小麦秸秆、砂光粉、木屑的掺入对硫氧镁生态板的物相结构均无显著影响,各样品的主结晶相均为MgO、MgCO3、Mg(OH)2、5Mg(OH)2·MgSO4·7H2O,且峰强差异不明显;与砂光粉和小麦秸秆相比,掺入木屑的硫氧镁试块性能最佳,当木屑掺量(木屑与氧化镁的质量比,下同)为0.3时,硫氧镁生态板养护28 d后具有最大的表观密度(1 100 kg/m3)和较高的抗压强度(16.6 MPa);小麦秸秆的掺入能有效降低生态板的表观密度;当其掺量为0.8时,表观密度降至402 kg/m3,且28 d抗压强度仍保持在3.7 MPa。这一结论为轻质硫氧镁生态板材料的研究提供了依据,对环保化菱镁建材的开发具有启示意义。
许琪 , 颜学睿 , 付立 , 张儒 , 董生德 , 孙艳霞 , 马路祥 , 贺欣 , 海春喜 , 周园 . 农林业废弃物改性硫氧镁生态板的制备及性能研究[J]. 无机盐工业, 2025 , 57(5) : 11 -17 . DOI: 10.19964/j.issn.1006-4990.2024-0432
Composite ecological board is a new type of environmental⁃friendly material,which is widely used in the fields of integrated kitchen cabinets,indoor decoration,and indoor flooring.To fabricate an innovative board with enhanced comprehensive performance and higher environmental value,the magnesium oxysulfide ecological board was investigated.By utilizing characterization techniques such as scanning electron microscopy(SEM),X-ray diffraction(XRD),apparent density testing,compressive strength testing,etc.,the impact of agricultural and forestry waste types and addition amounts on the structure and properties of the ecological board was explored.The results showed that the addition of wheat straw,sanding powder,and wood chips had no effect on the crystal structure of the magnesium oxysulfide⁃cement ecological board,and the main crystalline phase of all samples was MgO,MgCO3,Mg(OH)2,5Mg(OH)2·MgSO4·7H2O,with peak intensity differences not obvious.Compared with sanding powder and wheat straw,the magnesium oxysulfide blocks with wood chips performed best.When the wood chips content was 0.3,the magnesium oxysulfide cement ecological board had the highest apparent density of 1 100 kg/m3 and the highest compressive strength of 16.6 MPa after curing for 28 days.The addition of wheat straw could effectively reduce the apparent density of the ecological board.When the content was 0.8,the apparent density was reduced to 402 kg/m3,and the compressive strength was maintained at 3.7 MPa after 28 days.This conclusion provided important basis for the research of lightweight magnesium oxysulfide cement ecological board materials,and had certain enlightening significance for the development of environmental⁃friendly magnesium cement building materials.
| 1 | 周腰华,王亚静.我国秸秆综合利用政策演变、特征与展望[J].辽宁农业科学,2023(1):48-55. |
| ZHOU Yaohua, WANG Yajing.Review and prospect of China′s straw comprehensive utilization policy[J].Liaoning Agricultural Sciences,2023(1):48-55. | |
| 2 | 吴长,陈星宏,刘家乐.轻钢龙骨-黄麻纤维生物基面板组合墙体抗震性能分析[J].兰州理工大学学报,2022,48(5):126- 133. |
| WU Chang, CHEN Xinghong, LIU Jiale.Analysis of seismic performance of the light?gauge steel and jute fiber bio?based panel composite wall[J].Journal of Lanzhou University of Technology,2022,48(5):126-133. | |
| 3 | 周俊峰,陈啸洋,陈兵,等.煅烧沸石粉对硫氧镁水泥耐水性的影响[J].建筑材料学报,2024,27(3):197-205. |
| ZHOU Junfeng, CHEN Xiaoyang, CHEN Bing,et al.Effect of calcined zeolite powder on water resistance of magnesium oxysulfate cement[J].Journal of Building Materials,2024,27(3):197-205. | |
| 4 | BARBIERI V, LASSINANTTI GUALTIERI M, MANFREDINI T,et al.Hydration kinetics and microstructural development of a magnesium oxysulfate cement modified by macromolecules[J].Construction and Building Materials,2020,248:118624. |
| 5 | 朱效甲,朱倩倩,朱芸馨,等.生土基硫氧镁水泥生态防火板的性能研究与应用[J].上海建材,2022(1):37-43. |
| ZHU Xiaojia, ZHU Qianqian, ZHU Yunxin,et al.Performance research and application of magnesium oxysulfide cement ecological fireproof board based raw soil material[J].Shanghai Building Materials,2022(1):37-43. | |
| 6 | 谌萌,齐俊杰,席凯原.镁水泥胶合秸秆板生产工艺和经济技术分析[J].中国人造板,2018,25(4):16-21. |
| CHEN Meng, QI Junjie, XI Kaiyuan.Production technology and economic analysis of magnesium cement glued straw board[J].China Wood-Based Panels,2018,25(4):16-21. | |
| 7 | 李淑艳.秸秆镁质水泥轻质条板(SMC板)在高层建筑中的应用与施工[J].砖瓦,2006(9):55-56. |
| LI Shuyan.The utilization and construction of lightweight straw magnesium cement slab(SMC Panels) in high?rise buildings[J].Brick-Tile,2006(9):55-56. | |
| 8 | YOU Junjie, SONG Qianyi, TAN Da,et al.Mechanical properties and microstructure of basalt fiber?biobased?basic magnesium sulfate cement[J].Cement and Concrete Composites,2023,137:104934. |
| 9 | 许兴.秸秆-硫氧镁水泥复合材料关键技术的研究[D].镇江:江苏大学,2021. |
| XU Xing.Research on the key technology of straw?magnesium oxysulfate cement composite material[D].Zhenjiang:Jiangsu University,2021. | |
| 10 | 巴明芳,马哲洋,纪璐鑫,等.不同摩尔比对改性硫氧镁水泥基材料力学性能、变形行为的影响及机理研究[J/OL].建筑材料学报,2024:1-14.(2024-01-16). |
| 11 | WEI Zhiming, GU Kang, CHEN Bing,et al.Comparison of sawdust bio?composites based on magnesium oxysulfate cement and ordinary Portland cement[J].Journal of Building Engineering,2023,63:105514. |
| 12 | 国家质量监督检验检疫总局,中国国家标准化管理委员会. 无机硬质绝热制品试验方法: [S].北京:中国标准出版社,2008. |
| 13 | 国家市场监督管理总局,国家标准化管理委员会. 实木复合地板: [S].北京:中国标准出版社,2022. |
| 14 | 国家市场监督管理总局,国家标准化管理委员会. 水泥胶砂强度检验方法: [S].北京:中国标准出版社,2021. |
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