无机盐工业
主管:中海油天津化工研究设计院有限公司
主办:中海油天津化工研究设计院有限公司
   中海油炼油化工科学研究院(北京)有限公司
   中国化工学会无机酸碱盐专业委员会
ISSN 1006-4990 CN 12-1069/TQ
环境·健康·安全

牡蛎壳微粉改性水泥基复合材料性能及微观结构研究

  • 钟彬扬 ,
  • 梁玉兰 ,
  • 陈志杰 ,
  • 廖启华 ,
  • 王金贵
展开
  • 1.闽西职业技术学院,福建 龙岩 364021
    2.蒙古国研究大学,蒙古国乌兰巴托 11000
    3.福州大学环境与安全工程学院,福建 福州 350108
钟彬扬(1987— ),男,硕士,讲师,主要研究方向为无机化工材料研发及化学分析;E-mail:3049430056@qq.com

收稿日期: 2024-02-04

  网络出版日期: 2024-11-05

基金资助

国家自然科学基金项目(51604083);福建省龙岩市科技局项目(2019LYF12004)

Study on properties and microstructure of cement⁃based fillers modified by oyster shell powder

  • ZHONG Binyang ,
  • LIANG Yulan ,
  • CHEN Zhijie ,
  • LIAO Qihua ,
  • WANG Jingui
Expand
  • 1.Minxi Vocational & Technical College,Longyan 364021,China
    2.Graduate University of Mongolia,Ulaanbaatar ;11000,Mongolia
    3.College of environment & safety engineering,Fuzhou uninersity,Fuzhou 350108,China

Received date: 2024-02-04

  Online published: 2024-11-05

摘要

以牡蛎壳粉部分替换传统水泥基材料,在实现牡蛎壳废物利用的同时可有效降低建材成本。利用牡蛎壳粉作为普通硅酸盐水泥掺合料,探讨其不同掺杂量及不同粉磨方式对水泥胶砂强度及安定性的影响,确定了牡蛎壳粉的适宜添加量,并用XRD、SEM及EDS等测试分析手段表征不同掺量下胶凝试块的结构及性能变化。实验结果表明,牡蛎壳的球磨方式对水泥胶砂强度有明显影响,掺加湿法球磨牡蛎壳粉的胶凝材料的强度高于相应的掺加干法球磨的样品。牡蛎壳粉的掺加量为5%时,试样的抗压强度和抗折强度分别达到49.2 MPa和7.55 MPa,显著高于未掺加的空白样品。通过安定性实验制得的试样经过预养、沸煮之后,表面均光滑、无裂纹,体积无明显膨胀或收缩,表明掺杂牡蛎壳粉的胶凝材料安定性良好。微观结构表征结果显示牡蛎壳粉在水泥胶凝材料中独立存在,主要起惰性填充作用。利用牡蛎壳微粉部分替代水泥基材料是可行的,既可以改善水泥基材料综合性能,又能节约材料成本、减少环境污染,具有良好的应用前景。

本文引用格式

钟彬扬 , 梁玉兰 , 陈志杰 , 廖启华 , 王金贵 . 牡蛎壳微粉改性水泥基复合材料性能及微观结构研究[J]. 无机盐工业, 2024 , 56(10) : 135 -140 . DOI: 10.19964/j.issn.1006-4990.2024-0073

Abstract

Replacing traditional cement⁃based materials with oyster shell powder can effectively reduce building material costs while achieving the utilization of oyster shell waste.With oyster shell powder as the admixture of ordinary Portland cement,the effects of different doping amount and different grinding methods on the strength and stability of cement mortar were discussed,and the appropriate addition amount of oyster powder was determined.XRD,SEM and EDS analysis methods were used to characterize the changes in the structure and performance of the cementitious test block under different dosage.The results showed that the strength of cement mortar was obviously affected by the ball milling method of oyster shell,and the strength of the cementitious material mixed with wet ball milling oyster shell powder was higher than that of the corresponding sample mixed with dry ball milling.When the addition amount of oyster shell powder was 5%,the compressive strength and flexural strength of the sample reached 49.2 MPa and 7.55 MPa,respectively,which were significantly higher than the blank sample without addition.After pre curing and boiling,the surface of the samples prepared by the stability test was smooth,without cracks,and the volume had no obvious expansion or contraction,indicating that the stability of the gelling material doped with oyster shell powder was good.Microstructure characterization results showed that oyster shell powder existed independently in cement cementitious materials and mainly played an inert filling role.It was feasible to partially replace cement-based materials with oyster shell micro powder,which could improve the comprehensive performance of cement-based materials,save material costs,reduce environmental pollution and have good application prospects.

参考文献

1 刘子阳,耿振,李朝阳.牡蛎壳为原料制备医用CaCO3/HA复合生物材料[J].无机材料学报202035(5):601-607.
  LIU Ziyang, GENG Zhen, LI Chaoyang.Preparation of medical CaCO3/HA composite biomaterials using oyster shells as raw materials[J].Journal of Inorganic Materials202035(5):601-607.
2 CHEN Deke, WAN Peng, CAI Bingna,et al.Trimethylamine adsorption mechanism on activated carbon and removal in water and oyster proteolytic solution[J].Journal of Ocean University of China202120(6):1578-1586.
3 CAI Yun, WU Qiong, FU Cheng,et al.Study on the structures and properties of copper removal adsorbent prepared from sinter?free pulverized oyster shell materials[J].Chinese Journal of Structural Chiemistry20142:263-269.
4 K?SE T E, K?VAN? B.Adsorption of phosphate from aqueous solutions using calcined waste eggshell[J].Chemical Engineering Journal2011178:34-39.
5 姚汉云,徐雷,周晓香,等.柴胡加龙骨牡蛎汤作用难治性癫痫多药转运体的机制研究[J].世界科学技术-中医药现代化20239(1):120-127.
  YAO Hanyun, XU Lei, ZHOU Xiaoxiang,et al.Study on the mechanism of Chaihujia Longgu Muli decoction acting on multidrug transporter in refractory epilepsy[J].Modernization of Traditional Chinese Medicine and Materia Medica?World Science and Technology20239(1):120-127.
6 李旭东,彭吉星,吴海燕,等.牡蛎中营养、呈味及功能成分研究进展[J].水产科学202241(4):682-694.
  LI Xudong, PENG Jixing, WU Haiyan,et al.A review:Nutrition,taste and functional components in oysters[J].Fisheries Science202241(4):682-694.
7 吴梦,张大超,徐师,等.废水除磷工艺技术研究进展[J].有色金属科学与工程201910(2):97-103.
  WU Meng, ZHANG Dachao, XU Shi,et al.Research progress of dephosphorization technology on wastewater[J].Nonferrous Metals Science and Engineering201910(2):97-103.
8 CHEN Wanting, LIN C W, SHIH P K,et al.Adsorption of phosphate into waste oyster shell:Thermodynamic parameters and reaction kinetics[J].Desalination and Water Treatment201247(1/2/3):86-95.
9 张伟,梁哲,汪爱河,等.改性牡蛎壳粉优化制备及其对草甘膦的吸附性能[J].工业水处理202242(3):90-97.
  ZHANG Wei, LIANG Zhe, WANG Aihe,et al.Optimized preparation of modified oyster shell powder and its adsorption performancefor glyphosate[J].Industrial Water Treatment202242(3):90- 97.
10 冯卓意,陈雪梅.贝壳资源的深加工利用[J].材料科学与工程学报202240(1):123-128.
  FENG Zhuoyi, CHEN Xuemei.Research on the processing technology of seashell resource[J].Journal of Materials Science and Engineering202240(1):123-128.
11 许颖,陈锐,韦其颖,等.活化牡蛎壳固化余泥渣土及其机理分析[J].硅酸盐通报202140(3):900-906,935.
  XU Ying, CHEN Rui, WEI Qiying,et al.Activated oyster shell for solidification of residual soil and its mechanism analysis[J].Bulletin of the Chinese Ceramic Society202140(3):900-906, 935.
12 张思雨,于琦,刘桂宾,等.废弃牡蛎壳制备透水混凝土的试验研究[J].新型建筑材料202249(9):48-51.
  ZHANG Siyu, YU Qi, LIU Guibin,et al.Experimental study on permeable concrete prepared from waste oyster shell[J].New Building Materials202249(9):48-51.
13 曹敏杰,丁希月,许玲玲,等.牡蛎壳资源利用研究进展[J].集美大学学报(自然科学版)202126(5):390-397.
  CAO Minjie, DING Xiyue, XU Lingling,et al.Progress of the utilization of oyster shell resource[J].Journal of Jimei University (Natural Science)202126(5):390-397.
14 YANG E I, YI S T, KIM H M,et al.Long?term performance evaluation of concrete utilizing oyster shell in lieu of fine aggregate[J].Journal of the Korea Concrete Institute200315(2):280-287.
15 YANG E I, YI S T, LEEM Y M.Effect of oyster shell substituted for fine aggregate on concrete characteristics:Part I.Fundamental properties[J].Cement and Concrete Research200535(11):2175-2182.
16 黄震,边林林,刘莹,等.牡蛎壳粉改良膨胀土的工程特性及微观机理研究[J].铁道科学与工程学报202320(5):1729-1739.
  HUANG Zhen, BIAN Linlin, LIU Ying,et al.Engineering characteristics and microscopic mechanism of expansive soil improved by oyster shell powder[J].Journal of Railway Science and Engineering202320(5):1729-1739.
17 周璐,范宗青,安生霞,等.矿物掺合料对透水混凝土性能的影响[J].混凝土与水泥制品2018(9):1-5.
  ZHOU Lu, FAN Zongqing, AN Shengxia,et al.Influence of mineral admixtures on properties of permeable concrete[J].China Concrete and Cement Products2018(9):1-5.
18 黄耀英,蔡忍,刘钰,等.不同水灰比混凝土自干燥试验[J].水利水电科技进展201838(5):65-70.
  HUANG Yaoying, CAI Ren, LIU Yu,et al.Discussion on self?drying test of concrete with different water?cement ratios[J].Advances in Science and Technology of Water Resources201838(5):65-70.
19 褚玲妹.水灰比及再生骨料代替率对再生混凝土抗压强度的影响研究[J].河北能源职业技术学院学报202020(3):63-64,69.
  CHU Lingmei.The influence of water cement ratio and replacement ratio of recycled aggregate on compressed strength of recycled concrete[J].Journal of Hebei Energy College of Vocation and Technology202020(3):63-64,69.
20 肖力光,刘晓天.再生混凝土抗渗性能的研究进展[J].应用化工202251(1):216-219,224.
  XIAO Liguang, LIU Xiaotian.Research progress on the impermeability of recycled concrete[J].Applied Chemical Industry202251(1):216-219,224.
21 国家质量监督检验检疫总局,中国国家标准化管理委员会. 通用硅酸盐水泥: [S].北京:中国标准出版社,2008.
文章导航

/