不同APP添加量对复合肥料造粒性能的影响
收稿日期: 2023-10-18
网络出版日期: 2024-09-26
基金资助
国家重点研发计划项目(2022YFD1901500);云南省重大专项科技计划项目(202102AE090053);云南(昆明)院士专家工作站项目(YSZJGZZ-2022034);科技人才与平台计划项目(202305AF150055)
Effect of different addition amount of ammonium polyphosphate on granulation performance of compound fertilizer
Received date: 2023-10-18
Online published: 2024-09-26
聚磷酸铵(APP)作为近几年备受关注的新型肥料,在农业应用中研究较多且效果显著,但作为原料在复合肥料生产中的研究报道较少。为探究APP与其他肥料的复配和造粒性能,采用APP、磷酸一铵(MAP)、磷酸二铵(DAP)等原料通过复配再造粒制备复合肥料。肥料制备共设计两个方案,其中方案I以APP、MAP、尿素和K2SO4为原料,方案II以APP、DAP、尿素和K2SO4为原料,同时两个方案又分别设定不同的APP添加量作为变量,且对原料配伍性能、造粒过程现象、加水量、成粒率、肥料pH、颗粒强度、颗粒分散性及肥料吸湿性等造粒性能进行了评价。结果表明:APP与其他原料复配再造粒能够制备2~4.75 mm的颗粒产品;当聚合磷质量分数≥40%时,复配性能良好;不同磷源配伍对复合肥料造粒性能有明显影响,方案II的产品成粒率、颗粒强度和分散性均优于方案I,但方案II的吸湿性较强;适宜的APP添加量有利于复合肥料造粒,两个方案均显示在聚合磷质量分数为20%~40%时,肥料产品的成粒率较高,方案I>67%,方案II>77%。
赵蕾蕾 , 舒艺周 , 漆增连 , 刘丹丹 , 匡家灵 , 黄成东 , 吴加香 , 普正仙 . 不同APP添加量对复合肥料造粒性能的影响[J]. 无机盐工业, 2024 , 56(8) : 74 -82 . DOI: 10.19964/j.issn.1006-4990.2023-0501
Ammonium polyphosphate(APP),as a new type of fertilizer that has attracted much attention in recent years,has been studied more in agricultural applications with remarkable effects,but less research has been reported as a raw material in the production of compound fertilizers.In order to investigate the compounding and granulation performance of APP with other fertilizers,the APP,monoammonium phosphate(MAP),diammonium phosphate(DAP) and other raw materials were used to prepare compound fertilizers by compounding and then granulation.Two schemes were designed for the preparation of fertilizers,in which Scheme I was based on APP,MAP,urea and K2SO4 as raw materials,and Scheme II was based on APP,DAP,urea and K2SO4 as raw materials,and the two schemes were set with different APP additions as variables,and the compositions of the raw materials,the phenomenon of the granulation process,the amount of water added,the rate of granulation,the pH of the fertilizer,the strength of the particles,particle dispersion,and the moisture absorption of the fertilizer,etc.,were investigated.Fertilizer hygroscopicity and other granulation properties were evaluated.The results showed that APP compounded with other raw materials and then granulated could prepare granular products of 2~4.75 mm.The compounding performance was good when the proportion of polymerized phosphorus was ≥40%.Different phosphorus sources had obvious effects on the granulation performance of composite fertilizers,and the granulation rate,particle strength and dispersibility of the products of Scheme II were better than that of Scheme I,but the hygroscopicity of Scheme II was stronger.The appropriate addition amount of APP was conducive to the granulation of composite fertilizers.Both schemes showed that the granulation performance of APP was better than that of Scheme I,but the moisture absorption of Scheme II was more serious than that of Scheme I.The appropriate amount of APP addition is conducive to the granulation of compound fertilizer,and both schemes showed that when the proportion of polymerized phosphorus was 20%~40%,the granulation rate of fertilizer products was higher,with Scheme I>67% and Scheme II>77%.
| 1 | 何福多,原一帆,周小厚,等.湿法磷酸原位酸解废弃羽毛制备含氨基酸磷酸一铵[J].无机盐工业,2023,55(10):100-105. |
| HE Fuduo, YUAN Yifan, ZHOU Xiaohou,et al.Preparation of monoammonium phosphate containing amino acid from waste feat? | |
| hers by in situ acid hydrolysis of wet process of phosphoric | |
| acid[J].Inorganic Chemicals Industry,2023,55(10):100-105. | |
| 2 | 汪家铭.新型肥料聚磷酸铵的发展与应用[J].杭州化工,2009,39(4):1-4,11. |
| WANG Jiaming.Development and application of new fertilizer ammonium polyphosphate[J].Hangzhou Chemical Industry,2009,39(4):1-4,11. | |
| 3 | MCBEATH T M, LOMBI E, MCLAUGHLIN M J,et al.Polyphosphate?fertilizer solution stability with time,temperature,and |
| pH[J].Journal of Plant Nutrition and Soil Science,2007,170(3):387-391. | |
| 4 | 熊子怡,邱烨,郭琳钰,等.聚磷酸铵在土壤中有效性的变化及其影响因素[J].植物营养与肥料学报,2020,26(8):1473-1480. |
| XIONG Ziyi, QIU Ye, GUO Linyu,et al.The availability of ammonium polyphosphate in soil and the impacting factors[J].Journal of Plant Nutrition and Fertilizers,2020,26(8):1473-1480. | |
| 5 | 张汉卿,付学伟,余赟,等.聚磷酸铵复合肥对包菜生长发育及产量的影响[J].磷肥与复肥,2023,38(2):48-51. |
| ZHANG Hanqing, FU Xuewei, YU Yun,et al.Effects of APP compound fertilizer on growth and yield of cabbage[J].Phosphate & Compound Fertilizer,2023,38(2):48-51. | |
| 6 | 战威名.聚磷酸铵配施改良材料对滨海盐渍土磷形态及大豆生长的影响[D].泰安:山东农业大学,2023. |
| ZHAN Weiming.The effects of ammonium polyphosphate combined with improved materials on phosphorus form and soybean growth in coastal saline soil[D].Tai′an:Shandong Agricultural University,2023. | |
| 7 | 王箫璇.不同磷肥施用对砂姜黑土和红壤磷库转化及作物磷素吸收利用的影响[D].合肥:安徽农业大学,2022. |
| WANG Xiaoxuan.Effects of different varieties of phosphate fertilizers application on soil phosphorus pool transformation and phosphorus uptake and utilization of cereal crops[D].Hefei:Anhui Agricultural University,2022. | |
| 8 | 普正仙,宗世荣,陈泽新,等.聚磷酸盐替代部分正磷酸盐增产作用研究[J].磷肥与复肥,2023,38(1):48-51. |
| PU Zhengxian, ZONG Shirong, CHEN Zexin,et al.Effect of polyphosphate replacing partial orthophosphate on increasing production[J].Phosphate & Compound Fertilizer,2023,38(1):48-51. | |
| 9 | 甘浩天,廖欢,郝海波,等.不同滴灌磷肥对棉田土壤磷含量及磷肥利用率的影响[J].中国土壤与肥料,2022(11):24-32. |
| GAN Haotian, LIAO Huan, HAO Haibo,et al.Effects of different drip irrigation phosphorus fertilizer on soil phosphorus content and phosphorus utilization rate in cotton field[J].Soil and Fertilizer Sciences in China,2022(11):24-32. | |
| 10 | ZHAO Yanan, LI Ruike, HUANG Yufang,et al.Effects of various phosphorus fertilizers on maize yield and phosphorus uptake in soils with different pH values[J].Archives of Agronomy and Soil Science,2022,68(12):1746-1754. |
| 11 | 赵文,高进华,解学仕,等.聚磷酸铵合成工艺评述及产品农用研究进展[J].磷肥与复肥,2019,34(10):25-27,31. |
| ZHAO Wen, GAO Jinhua, XIE Xueshi,et al.Review of ammonium polyphosphate production process and research progress in agricultural application of product[J].Phosphate & Compound Fertilizer,2019,34(10):25-27,31. | |
| 12 | 袁太艳,严正娟,黄成东,等.聚磷酸铵在紫色土壤中的吸附-解吸特征[J].浙江农业学报,2023,35(2):403-416. |
| YUAN Taiyan, YAN Zhengjuan, HUANG Chengdong,et al.Adsorption?desorption characteristics of ammonium polyphosphate in purple soils[J].Acta Agriculturae Zhejiangensis,2023,35(2):403-416. | |
| 13 | 王雅洁,张兵兵,袁盼,等.黄棕壤和酸紫砂土施用不同磷肥对油菜产量的影响[J].中国油料作物学报,2022,44(1):147-157. |
| WANG Yajie, ZHANG Bingbing, YUAN Pan,et al.Effects of different phosphate fertilizer on Brassica napus cultivars grown with yellow?brown earth and acid purplish sandy soil[J].Chinese Journal of Oil Crop Sciences,2022,44(1):147-157. | |
| 14 | 陶金铭,刘烁然,司艳玲,等.聚磷酸铵溶液在春玉米上的施用效果研究[J].玉米科学,2021,29(1):146-153. |
| TAO Jinming, LIU Shuoran, SI Yanling,et al.Study on the application effect of ammonium polyphosphate on spring corn[J].Journal of Maize Sciences,2021,29(1):146-153. | |
| 15 | 亢龙飞,王静,朱丽娜,等.不同形态磷酸盐及施用方式对石灰性土壤磷移动性和有效性的影响[J].植物营养与肥料学报,2020,26(7):1179-1187. |
| KANG Longfei, WANG Jing, ZHU Lina,et al.Mobility and availability of phosphate under different phosphate sources and application methods in calcareous soils[J].Journal of Plant Nutrition and Fertilizers,2020,26(7):1179-1187. | |
| 16 | 柴冠群,刘桂华,罗沐欣键,等.叶面喷施聚磷酸铵对辣椒产量、品质及吸收转运Cd的影响[J].河南农业科学,2022,51(8):107-116. |
| CHAI Guanqun, LIU Guihua, LUO Muxinjian,et al.Effects of spraying ammonium polyphosphate on yield,quality,absorption and transport of Cd in pepper[J].Journal of Henan Agricultural Sciences,2022,51(8):107-116. | |
| 17 | 燕子红,范东升,赵彦梁,等.全水溶聚磷酸铵-稀土缓释肥的研制及其对蔬菜的施用效果[J].中国农业科技导报,2022,24(1):157-163. |
| YAN Zihong, FAN Dongsheng, ZHAO Yanliang,et al.Development of fully water?soluble ammonium polyphosphate?rare earth slow?release fertilizer and its application effect to vegetables[J].Journal of Agricultural Science and Technology,2022,24(1):157-163. | |
| 18 | 王婷婷,杨恒哲,李元峰,等.聚磷酸铵复合肥对设施番茄的肥效研究[J].农学学报,2020,10(9):33-37. |
| WANG Tingting, YANG Hengzhe, LI Yuanfeng,et al.The fertilizer efficiency of ammonium polyphosphate compound fertilizer on tomato in greenhouse[J].Journal of Agriculture,2020,10(9):33-37. | |
| 19 | 范东升.聚磷酸铵稀土肥生产工艺及阿托伐醌和膦配体合成研究[D].喀什:喀什大学,2022. |
| FAN Dongsheng.Study on the production process of ammonium polyphosphates rare earth fertilizer and synthesis of atorvastone and phosphine ligands[D].Kashi:Kashi University,2022. | |
| 20 | 亢龙飞,褚贵新.聚磷酸铵肥料生产工艺及其关键性状表征[J].磷肥与复肥,2018,33(9):13-18. |
| KANG Longfei, CHU Guixin.Manufacturing process of APP fertilizer and its key properties characterization[J].Phosphate & Compound Fertilizer,2018,33(9):13-18. | |
| 21 | 郝青.复合肥料的造粒技术及颗粒特性研究[D].临汾:山西师范大学,2012. |
| HAO Qing.Resarch on compound fertilizer granulation technology and particles′ morphological characters[D].Linfen:Shanxi Normal University,2012. | |
| 22 | 舒艺周,马航,匡家灵,等.含聚合磷水溶肥料微粒化造粒试验研究[J].肥料与健康,2023,50(3):35-38. |
| SHU Yizhou, MA Hang, KUANG Jialing,et al.Experimental study on micronized granulation of water?soluble fertilizer containing polyphosphates[J].Fertilizer & Health,2023,50(3):35-38. | |
| 23 | 张春艾.水分对磷酸二铵产品的影响探微[J].化工管理,2015(36):23. |
| ZHANG Chun′ai.Discussion on the influence of moisture on diammonium phosphate products[J].Chemical Enterprise Management,2015(36):23. | |
| 24 | 韩林沛.电解锰渣基缓释肥的制备及其性能研究[D].绵阳:西南科技大学,2023. |
| HAN Linpei.Study on preparation and properties of electrolytic manganese residue?based slow?release fertilizers[D].Mianyang:Southwest University of Science and Technology,2023. | |
| 25 | 吴玉坤.中低品位磷矿酸解法制备复混肥工艺开发[D].郑州:郑州大学,2021. |
| WU Yukun.Technological development of preparing compound fertilizer by acid hydrolysis of middle and low grade phosphate rock[D].Zhengzhou:Zhengzhou University,2021. | |
| 26 | 郎江华.磷酸一铵制备聚磷酸铵新工艺开发[D].武汉:武汉工程大学,2019. |
| LANG Jianghua.A novel process for synthesis of ammonium polyphosphate by ammonium phosphate[D].Wuhan:Wuhan Institute of Technology,2019. | |
| 27 | 张伟.复合肥料吸湿和结块性能及防止研究[D].上海:华东理工大学,2012. |
| ZHANG Wei.Study on moisture absorption and caking and their prevention of compound fertilizer[D].Shanghai:East China University of Science and Technology,2012. | |
| 28 | 茹铁军,王金铭,乔荣广.复合肥料的吸湿性及其影响因素[J].磷肥与复肥,2010,25(4):50-51. |
| RU Tiejun, WANG Jinming, QIAO Rongguang.Study on the hygroscopicity of compound fertilizer and its influence factors[J].Phosphate & Compound Fertilizer,2010,25(4):50-51. | |
| 29 | 许洪兴.从生产角度谈复混肥配方技术[J].磷肥与复肥,2004,19(2):47-49. |
| XU Hongxing.Discussion on formulation technique for compound fertilizer from viewpoint of production[J].Phosphate & Compound Fertilizer,2004,19(2):47-49. | |
| 30 | 刘续.聚磷酸铵微波合成工艺及其水溶特性研究[D].郑州:郑州大学,2021. |
| LIU Xu.Study on the microwave synthesis technology and water solubility characteristics of ammonium polyphosphate[D].Zhengzhou:Zhengzhou University,2021. | |
| 31 | 徐思思.水溶性聚磷酸铵及淀粉聚磷酸酯的制备研究[D].武汉:湖北工业大学,2018. |
| XU Sisi.Preparation of water?soluble ammonium polyphosphate and starch polyphosphate[D].Wuhan:Hubei University of Technology,2018. | |
| 32 | 宋洁,朱晓斌,牛育华,等.KHA/PPA缓释控肥料的制备及性能[J].应用化工,2021,50(1):117-121. |
| SONG Jie, ZHU Xiaobin, NIU Yuhua,et al.Preparation and properties of KHA/PPA slow release controlled fertilizer[J].Applied Chemical Industry,2021,50(1):117-121. |
/
| 〈 |
|
〉 |