S型异质结光催化剂的研究进展
收稿日期: 2023-09-04
网络出版日期: 2024-08-01
基金资助
四川省重点研发项目(2023YFG0247);内江师范学院校级科研项目(2023YB07)
Research progress of S-type heterojunction photocatalysts
Received date: 2023-09-04
Online published: 2024-08-01
光催化技术具有合成过程简便、反应条件易控制、充分利用太阳能且无二次污染等突出优势，在处理环境污染问题和缓解全球能源短缺等方面具有广阔的应用前景。然而，由于光生载流子低的转移和分离效率，实际的光化学转换效率提升受到了限制。新兴的S型异质结光催化剂由于其在空间上实现了光生载流子的有效转移分离并展现出强的氧化还原能力，在太阳燃料制备和环境治理领域受到了广泛关注和研究。综述了异质结光催化剂的发展历程和S型异质结的基本原理及在各领域中的应用。最后，总结了S型异质结光催化剂的突出优势，并提出S型异质结光催化剂的发展前景和面临的挑战，为开发具备高效光催化活性的新型异质结光催化剂提供思路和参考。
刘敏 , 黄秀 , 张理元 . S型异质结光催化剂的研究进展[J]. 无机盐工业, 2024 , 56(7) : 18 -27 . DOI: 10.19964/j.issn.1006-4990.2023-0437
Photocatalytic technology has outstanding advantages such as simple synthesis process，easy control of reaction conditions，full utilization of solar energy，and no secondary pollution.It has broad application prospects in addressing environmental pollution problems and alleviating global energy shortages.However，due to the low transfer and separation efficiency of photo generated carriers，the actual improvement of photochemical conversion efficiency is limited.The emerging S-tpye heterojunction photocatalysts have received widespread attention and research in the fields of solar fuel preparation and environmental governance due to their effective transfer and separation of photo generated carriers in space and their strong redox power.The development history of heterojunction photocatalysts，the basic principles of S-tpye heterojunctions，and their applications in various fields were reviewed.Finally，the outstanding advantages of S-tpye heterojunction photocatalysts were summarized，and the development prospects and challenges faced by S-tpye heterojunction photocatalysts were proposed，providing ideas and references for the development of new heterojunction photocatalysts with high photocatalytic activity.
| 1 | HASIJA V， RAIZADA P， SUDHAIK A，et al.Recent advances in noble metal free doped graphitic carbon nitride based nanohybrids for photocatalysis of organic contaminants in water：A review［J］.Applied Materials Today，2019，15：494-524. |
| 2 | YANG Xi， TIAN Zhen， CHEN Yufang，et al. In situ synthesis of 2D ultrathin cobalt doped g-C3N4 nanosheets enhances photocatalytic performance by accelerating charge transfer［J］.Journal of Alloys and Compounds，2021，859：157754. |
| 3 | LI Kaining， ZHANG Sushu， LI Yuhan，et al.MXenes as noble?metal?alternative co?catalysts in photocatalysis［J］.Chinese Journal of Catalysis，2021，42（1）：3-14. |
| 4 | FUJISHIMA A， HONDA K.Electrochemical photolysis of water at a semiconductor electrode［J］.Nature，1972，238（5358）：37-38. |
| 5 | PEDANEKAR R S， SHAIKH S K， RAJPURE K Y.Thin film photocatalysis for environmental remediation：A status review［J］.Current Applied Physics，2020，20（8）：931-952. |
| 6 | THIMSEN E， BISWAS S， LO C S，et al.Predicting the band structure of mixed transition metal oxides：Theory and experiment［J］.The Journal of Physical Chemistry C，2009，113（5）：2014-2021. |
| 7 | ZAREZADEH S， HABIBI-YANGJEH A， MOUSAVI M.Fabrication of novel ZnO/BiOBr/C-Dots nanocomposites with considerable photocatalytic performances in removal of organic pollutants under visible light［J］.Advanced Powder Technology，2019，30（6）：1197-1209. |
| 8 | KANAKARAJU D， YAHYA M S， WONG S P.Removal of chemical oxygen demand from agro effluent by ZnO photocatalysis and photo-Fenton［J］.SN Applied Sciences，2019，1（7）：738. |
| 9 | ZHU Bangyao， ZHANG Qi， LI Xiuyan，et al.Facile synthesis of ZnS/ZnO nanosheets with enhanced photocatalytic activity［J］.Phy? sica Status Solidi （a），2018，215（23）：1800359. |
| 10 | DAFARE S， DESHPANDE P S， BHAVSAR R S.Photocatalytic degradation of Congo red dye on combustion synthesised Fe2O3 ［J］.Indian Journal of Chemical Technology，2013，20（6）：406-410. |
| 11 | WANG Qizhao， LIAN Juhong， MA Qiong，et al.Photodegradation of Rhodamine B over a novel photocatalyst of feather keratin decorated CdS under visible light irradiation［J］.New Journal of Chemistry，2015，39（9）：7112-7119. |
| 12 | ZHANG Xian， JIA Feifei， YANG Bingqiao，et al.Oxidation of molybdenum disulfide sheet in water under in situ atomic force microscopy observation［J］.The Journal of Physical Chemistry C，2017，121（18）：9938-9943. |
| 13 | WANG Xinchen， MAEDA K， THOMAS A，et al.A metal?free polymeric photocatalyst for hydrogen production from water under visiblelight［J］.Nature Materials，2009，8：76-80. |
| 14 | ZHAO Chen， WANG Jiasheng， CHEN Xi，et al.Bifunctional Bi12O17Cl2/MIL-100（Fe） composites toward photocatalytic Cr（Ⅵ） sequestration and activation of persulfate for bisphenol A degradation［J］.The Science of the Total Environment，2021，752：141901. |
| 15 | YU Jun， CAO Jiao， YANG Zhaohui，et al.One?step synthesis of Mn-doped MIL-53（Fe） for synergistically enhanced generation of sulfate radicals towards tetracycline degradation［J］.Journal of Colloid and Interface Science，2020，580：470-479. |
| 16 | CHEN Shifu， YANG Yunguang， LIU Wei.Preparation，characterization and activity evaluation of TiN/F-TiO2 photocatalyst［J］.Journal of Hazardous Materials，2011，186（2/3）：1560-1567. |
| 17 | RESZCZYNSKA J， GRZYB T， SOBCZAK J W，et al.Visible light activity of rare earth metal doped（Er3+，Yb3+or Er3+/Yb3+）titania photocatalysts［J］.Applied Catalysis B：Environmental，2015，163：40-49. |
| 18 | STUCCHI M， BIANCHI C L， ARGIRUSIS C，et al.Ultrasound assisted synthesis of Ag-decorated TiO2 active in visible light［J］.Ultrasonics Sonochemistry，2018，40（Pt A）：282-288. |
| 19 | QI Lifang， CHENG Bei， YU Jiaguo，et al.High?surface area mesoporous Pt/TiO? hollow chains for efficient formaldehyde decomposition at ambient temperature［J］.Journal of Hazardous Materials，2016，301：522-530. |
| 20 | OHNO T.Development of visible light sensitive TiO2 photocatalysts and their sensitization using Fe3+ ions［J］.Journal of the Japan Petroleum Institute，2006，49（4）：168-176. |
| 21 | BENTO R T， CORREA O V， PILLIS M F.On the surface chemistry and the reuse of sulfur?doped TiO2 films as photocatalysts［J］.Materials Chemistry and Physics，2021，261：124231. |
| 22 | WU Ling， YU J C， FU Xianzhi.Characterization and photocatalytic mechanism of nanosized CdS coupled TiO2 nanocrystals under visible light irradiation［J］.Journal of Molecular Catalysis A：Chemical，2006，244（1/2）：25-32. ′ |
| 23 | ENESCA A， ANDRONIC L.Photocatalytic activity of S-scheme heterostructure for hydrogen production and organic pollutant removal：A mini?review［J］.Nanomaterials，2021，11（4）：871. |
| 24 | SERPONE N， BORGARELLO E， GR?TZEL M.Visible light induced generation of hydrogen from H2S in mixed semiconductor dispersions；improved efficiency through inter?particle electron transfer［J］.Journal of the Chemical Society，Chemical Communications，1984（6）：342-344. |
| 25 | DANISH M， MUNEER M.Excellent visible?light?driven Ni-ZnS/g-C3N4 photocatalyst for enhanced pollutants degradation performance：Insight into the photocatalytic mechanism and adsorption isotherm［J］.Applied Surface Science，2021，563：150262. |
| 26 | BEDJA I， KAMAT P V.Capped semiconductor colloids.Synthesis and photoelectrochemical behavior of TiO2-capped SnO2 nanocrystallites［J］.The Journal of Physical Chemistry，1995，99（22）：9182-9188. |
| 27 | BARD A J.Photoelectrochemistry and heterogeneous photo?catalysis at semiconductors［J］.Journal of Photochemistry，1979，10（1）：59-75. |
| 28 | XU Quanlong， ZHANG Liuyang， CHENG Bei，et al.S-scheme heterojunction photocatalyst［J］.Chem，2020，6（7）：1543-1559. |
| 29 | TADA H， MITSUI T， KIYONAGA T，et al.All?solid?state Z-scheme in CdS-Au-TiO2 three?component nanojunction syst? em［J］.Nature Materials，2006，5：782-786. |
| 30 | TACHIBANA Y， VAYSSIERES L， DURRANT J R.Artificial photosynthesis for solar water?splitting［J］.Nature Photonics，2012，6：511-518. |
| 31 | LIU Jianjun， CHENG Bei， YU Jiaguo.A new understanding of the photocatalytic mechanism of the direct Z-scheme g-C3N4/TiO2 heterostructure［J］.Physical Chemistry Chemical Physics：PCCP，2016，18（45）：31175-31183. |
| 32 | FU Junwei， XU Quanlong，LOW J，et al.Ultrathin 2D/2D WO3/g-C3N4 step?scheme H2-production photocatalyst［J］.Applied Catalysis B：Environmental，2019，243：556-565. |
| 33 | JIANG Guoping， ZHENG Chaoyue， YAN Teng，et al.Cd0.8Mn0.2S/MoO3 composites with an S-scheme heterojunction for efficient photocatalytic hydrogen evolution［J］.Dalton Transactions，2021，50（15）：5360-5369. |
| 34 | WANG Pengfei， LIU Yao， JIANG Ning，et al.Double S-scheme AgBr heterojunction co?modified with g-C3N4 and black phosphorus nanosheets greatly improves the photocatalytic activity and stability［J］.Journal of Molecular Liquids，2021，329： 115540. |
| 35 | WANG Zhongliao， CHEN Yifan， ZHANG Liuyang，et al.Step?scheme CdS/TiO2 nanocomposite hollow microsphere with enhanced photocatalytic CO2 reduction activity［J］.Journal of Materials Science & Technology，2020，56：143-150. |
| 36 | ZHANG Kailian， ZHOU Man， YU Changlin，et al.Construction of S-scheme g-C3N4/ZrO2 heterostructures for enhancing photocatalytic disposals of pollutants and electrocatalytic hydrogen evolution［J］.Dyes and Pigments，2020，180：108525. |
| 37 | ZHEN Yanzhong， YANG Chunming， SHEN Huidong，et al.Photocatalytic performance and mechanism insights of a S-scheme g-C3N4/Bi2MoO6 heterostructure in phenol degradation and hydrogen evolution reactions under visible light［J］.Physical Chemistry Chemical Physics：PCCP，2020，22（45）：26278-26288. |
| 38 | GE Haonan， XU Feiyan， CHENG Bei，et al.S-scheme heterojunction TiO2/CdS nanocomposite nanofiber as H2-production photocatalyst［J］.ChemCatChem，2019，11（24）：6301-6309. |
| 39 | HE Fei， ZHU Bicheng， CHENG Bei，et al.2D/2D/0D TiO2/C3N4/Ti3C2 MXene composite S-scheme photocatalyst with enhanced CO2 reduction activity［J］.Applied Catalysis B：Environmental，2020，272：119006. |
| 40 | HUO Yao， ZHANG Jinfeng， WANG Zhongliao，et al.Efficient interfacial charge transfer of 2D/2D porous carbon nitride/bismuth oxychloride step?scheme heterojunction for boosted solar?driven CO2 reduction［J］.Journal of Colloid and Interface Science，2021， 585：684-693. |
| 41 | HUO Yao， ZHANG Jinfeng， DAI Kai，et al.Amine?modified S-scheme porous g-C3N4/CdSe?diethylenetriamine composite with enhanced photocatalytic CO2 reduction activity［J］.ACS Applied Energy Materials，2021，4（1）：956-968. |
| 42 | MEI Zihui， WANG Guohong， YAN Suding，et al.Rapid microwave?assisted synthesis of 2D/1D ZnIn2S4/TiO2 S-scheme heterojunction for catalyzing photocatalytic hydrogen evolution［J］.Acta Physico Chimica Sinica，2021，37（6）：2009097. |
| 43 | CHEN Yanli， SU Fengyun， XIE Haiquan，et al.One?step construction of S-scheme heterojunctions of N-doped MoS2 and S-doped g-C3N4 for enhanced photocatalytic hydrogen evolution［J］.Chemical Engineering Journal，2021，404：126498. |
| 44 | XU Feiyan， MENG Kai， CHENG Bei，et al.Unique S-scheme heterojunctions in self?assembled TiO2/CsPbBr3 hybrids for CO2 photoreduction［J］.Nature Communications，2020，11：4613. |
| 45 | WANG Libo， CHENG Bei， ZHANG Liuyang，et al. In situ irradiated XPS investigation on S-scheme TiO2@ZnIn2S4 photocatalyst for efficient photocatalytic CO2 reduction［J］.Small，2021，17（41）：2103447. |
| 46 | CHENG Chang， HE Bowen， FAN Jiajie，et al.An inorganic/organic S-scheme heterojunction H2-production photocatalyst and its charge transfer mechanism［J］.Advanced Materials，2021，33（22）：2100317. |
| 47 | CAO Shuang， ZHONG Bo， BIE Chuanbiao，et al.Insights into photocatalytic mechanism of H2 production integrated with organic transformation over WO3/Zn0.5Cd0.5S S-scheme heterojunction［J］.Acta Physico Chimica Sinica，2024，40：2307016. |
| 48 | WEI Renbin， HUANG Zanling， GU Guanghui，et al.Dual?cocatalysts decorated rimous CdS spheres advancing highly?efficient visible?light photocatalytic hydrogen production［J］.Applied Catalysis B：Environmental，2018，231：101-107. |
| 49 | LI Jinmao， WU Congcong， LI Jin，et al.1D/2D TiO2/ZnIn2S4 S-scheme heterojunction photocatalyst for efficient hydrogen evolution［J］.Chinese Journal of Catalysis，2022，43（2）：339-349. |
| 50 | ZHANG Bin， SHI Huanxian， HU Xiaoyun，et al.A novel S-scheme MoS2/CdIn2S4 flower?like heterojunctions with enhanced photocatalytic degradation and H2 evolution activity［J］.Journal of Physics D：Applied Physics，2020，53（20）：205101. |
| 51 | 薛晋波，高国翔，申倩倩，等.新型S型CdS-BiVO4异质结光电极的构筑及产氢性能研究［J］.高等学校化学学报，2021，42（8）：2493-2499. |
| XUE Jinbo， GAO Guoxiang， SHEN Qianqian，et al.Construction of a novel S-scheme CdS-BiVO4 heterojunction photoelectrodes and research on hydrogen production［J］.Chemical Journal of Chinese Universities，2021，42（8）：2493-2499. | |
| 52 | LI Teng， GUO Xin， ZHANG Lijun，et al.2D CoP supported 0D WO3 constructed S-scheme for efficient photocatalytic hydrogen evolution［J］.International Journal of Hydrogen Energy，2021，46（39）：20560-20572. |
| 53 | ZHANG Qiqi， BAI Xue， HU Xiaoyun，et al.Efficient photocatalytic H2 evolution over 2D/2D S-scheme NiTe2/g-C3N4 heterojunction with superhydrophilic surface［J］.Applied Surface Science，2022，579：152224. |
| 54 | SUN Haoran， SHI Yuxing， SHI Weilong，et al.High?crystalline/amorphous g-C3N4 S-scheme homojunction for boosted photocatalytic H2 production in water/simulated seawater：Interfacial charge transfer and mechanism insight［J］.Applied Surface Science，2022，593：153281. |
| 55 | LIU Qinqin， HE Xudong， PENG Jinjun，et al.Hot?electron?assisted S-scheme heterojunction of tungsten oxide/graphitic carbon nitride for broad?spectrum photocatalytic H2 generation［J］.Chinese Journal of Catalysis，2021，42（9）：1478-1487. |
| 56 | MU Feihu， MIAO Xiaowei， CAO Jihui，et al.Integration of plasmonic effect and S-scheme heterojunction into gold decorated carbon nitride/cuprous oxide catalyst for photocatalysis［J］.Journal of Cleaner Production，2022，360：131948. |
| 57 | XU Zheng， SHI Weilong， SHI Yuxing，et al.Carbon dots as solid?state electron mediator and electron acceptor in S-scheme heterojunction for boosted photocatalytic hydrogen evolution［J］.Applied Surface Science，2022，595：153482. |
| 58 | ZHONG Yueqi， LI Mengyuan， LUAN Xue，et al.Ultrathin ZnIn2S4/ZnSe heteronanosheets with modulated S-scheme enable high efficiency of visible?light?responsive photocatalytic hydrogen evolution［J］.Applied Catalysis B：Environmental，2023，335：122859. |
| 59 | HE Fei， MENG Aiyun， CHENG Bei，et al.Enhanced photocatalytic H2-production activity of WO3/TiO2 step?scheme heterojunction by graphene modification［J］.Chinese Journal of Catalysis，2020，41（1）：9-20. |
| 60 | LI Han， TAO Shanren， WAN S，et al.S-scheme heterojunction of ZnCdS nanospheres and dibenzothiophene modified graphite carbon nitride for enhanced H2 production［J］.Chinese Journal of Catalysis，2023，46：167-176. |
| 61 | MOHAMED R M， SHAWKY A.Visible?light?driven hydrogen production over ZIF-8 derived Co3O4/ZnO S-scheme based p-n heterojunctions［J］.Optical Materials，2022，124：112012. |
| 62 | BAHADORAN A， MASUDY-PANAH S， DE LILE J R，et al.Novel 0D/1D ZnBi2O4/ZnO S-scheme photocatalyst for hydrogen production and BPA removal［J］.International Journal of Hydrogen Energy，2021，46（47）：24094-24106. |
| 63 | WANG Zhuanhu， BAI Yuexia， LI Yunpeng，et al.Bi2O2CO3/red phosphorus S-scheme heterojunction for H2 evolution and Cr（Ⅵ） reduction［J］.Journal of Colloid and Interface Science，2022，609：320-329. |
| 64 | ZHAO Xiaoxue， XU Mengyang， SONG Xianghai，et al.3D Fe-MOF embedded into 2D thin layer carbon nitride to construct 3D/2D S-scheme heterojunction for enhanced photoreduction ofCO2［J］.Chinese Journal of Catalysis，2022，43（10）：2625-2636. |
| 65 | DONG Zhongliang， ZHOU Jiaxin， ZHANG Zhijie，et al.Construction of a p-n type S-scheme heterojunction by incorporating CsPbBr3 nanocrystals into mesoporous Cu2O microspheres for efficient CO2 photoreduction［J］.ACS Applied Energy Materials，2022，5（8）：10076-10085. |
| 66 | HE J， SHAO D W， ZHENG L C，et al.Construction of Z-scheme Cu2O/Cu/AgBr/Ag photocatalyst with enhanced photocatalytic activity and stability under visible light［J］.Applied Catalysis B：Environmental，2017，203：917-926. |
| 67 | MALEFANE M E.Co3O4/Bi4O5I2/Bi5O7I C-scheme heterojunction for degradation of organic pollutants by light?emitting diode irradiation［J］.ACS Omega，2020，5（41）：26829-26844. |
| 68 | 马润东，郭雄，施凯旋，等.MoS2/g-C3N4 S型异质结的构建及光催化性能研究［J］.无机材料学报，2023，38（10）：1176-1182. |
| MA Rundong， GUO Xiong， SHI Kaixuan，et al.S-type heterojunction of MOS2/g-C3N4：Construction and photocatalysis［J］.Journal of Inorganic Materials，2023，38（10）：1176-1182. | |
| 69 | 徐凯旋，亢玉龙，高晓明，等.内电场增强S型异质结N-C3N4/BiOCl x I1- x 的制备及其光催化性能［J］.复合材料学报，2023， 40（9）：5134-5144. |
| XU Kaixuan， KANG Yulong， GAO Xiaoming，et al.Preparation of S-type heterojunction N-C3N4/BiOCl x I1- x with internal electric field and enhanced photocatalytic properties［J］.Acta Materiae Compositae Sinica，2023，40（9）：5134-5144. | |
| 70 | HU Xuecheng， WANG Guohong， WANG Juan，et al.Step?scheme NiO/BiOI heterojunction photocatalyst for rhodamine photodegradation［J］.Applied Surface Science，2020，511：145499. |
| 71 | CHEN Zijun， GUO Hai， LIU Huiyun，et al.Construction of dual S-scheme Ag2CO3/Bi4O5I2/g-C3N4 heterostructure photocatalyst with enhanced visible?light photocatalytic degradation for tetracycline［J］.Chemical Engineering Journal，2022，438：135471. |
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