无机盐工业
主管:中海油天津化工研究设计院有限公司
主办:中海油天津化工研究设计院有限公司
   中海油炼油化工科学研究院(北京)有限公司
   中国化工学会无机酸碱盐专业委员会
ISSN 1006-4990 CN 12-1069/TQ
综述与专论

富锂硫酸盐型盐湖卤水蒸发实验研究进展

  • 杨游胜 ,
  • 姚智豪 ,
  • 赵志星 ,
  • 冯霞 ,
  • 曾英 ,
  • 于旭东
展开
  • 成都理工大学材料与化学化工学院,四川 成都 610059
杨游胜(1998— ),男,硕士,研究方向为相平衡与相图;E-mail:yangyoushengc413@126.com
于旭东(1985— ),男,博士,教授,研究方向为相平衡与分离技术;E-mail:xwdlyxd@126.com

收稿日期: 2023-10-09

  网络出版日期: 2024-04-18

基金资助

四川省科技计划项目(2022YFQ0075)

Research progress of lithium-rich sulfate type salt lake brine evaporation experiment

  • YANG Yousheng ,
  • YAO Zhihao ,
  • ZHAO Zhixing ,
  • FENG Xia ,
  • ZENG Ying ,
  • YU Xudong
Expand
  • College of Materials and Chemistry & Chemical Engineering,Chengdu University of Technology,Chengdu 610059,China

Received date: 2023-10-09

  Online published: 2024-04-18

摘要

随着“双碳”目标的提出,锂在新能源材料领域中的应用受到高度关注,锂的需求呈现爆发式增长。世界锂资源以矿石锂和盐湖锂为主,盐湖锂因其储量大成为未来锂资源开发的重点,因而占比最大的硫酸盐型盐湖成为焦点。因盐湖卤水组成差异较大,叠加硫酸盐型盐湖特殊属性,使得锂在盐田蒸发阶段存在多种结晶形式而造成损失,增加了锂的有效富集难度。总结了前人针对富锂硫酸盐型盐湖的蒸发实验研究结果,结合相图分析总结富锂硫酸盐型盐湖蒸发结晶析盐规律,重点关注锂的浓缩状态及析盐结晶形式,为硫酸盐型盐湖锂资源开发提供参考。

本文引用格式

杨游胜 , 姚智豪 , 赵志星 , 冯霞 , 曾英 , 于旭东 . 富锂硫酸盐型盐湖卤水蒸发实验研究进展[J]. 无机盐工业, 2024 , 56(4) : 1 -7 . DOI: 10.19964/j.issn.1006-4990.2023-0481

Abstract

With the proposal of “dual carbon” goal,the application of lithium in the field of new energy materials has received great attention,and the demand for lithium has shown explosive growth.The world's lithium resources are mainly composed of ore lithium and salt lake lithium.Salt lake lithium has become the focus of future lithium resource development because of its large reserves, and therefore the sulfate type salt lake, which accounts for the largest proportion,has become the focus.Due to the significant difference in the composition of salt lake,and the special properties of sulfate type salt lake,lithium has multiple crystalline forms in the evaporation stage of saltpan and causes losses,which increases the difficulty of effective enrichment of lithium.The results of evaporation experiment of lithium-rich sulfate salt lakes were summarized,the law of crystallization salt evolution during evaporation based on the phase diagram was analyzed and summarized,with a focuses on the concentrated state of lithium and the crystalline form of lithium,providing reference for the development of lithium resources in sulfate salt lakes.

参考文献

1 乜贞, 伍倩, 丁涛, 等. 中国盐湖卤水提锂产业化技术研究进展[J]. 无机盐工业202254(10):1-12.
  NIE Zhen, WU Qian, DING Tao, et al. Research progress on industrialization technology of lithium extraction from salt lake brine in China[J]. Inorganic Chemicals Industry202254(10):1-12.
2 于建国, 孙庆, 裘晟波, 等. 支撑国家新能源战略发展的锂资源开发[J]. 无机盐工业202355(1):1-14.
  YU Jianguo, SUN Qing, QIU Shengbo, et al. Lithium resources development supporting national new energy strategy development[J]. Inorganic Chemicals Industry202355(1):1-14.
3 干勇, 彭苏萍, 毛景文, 等. 我国关键矿产及其材料产业供应链高质量发展战略研究[J]. 中国工程科学202224(3):1-9.
  GAN Yong, PENG Suping, MAO Jingwen, et al. High-quality development strategy for the supply chain of critical minerals and its material industry in China[J]. Strategic Study of CAE202224(3):1-9.
4 Survey U.S.Geological. Mineral commodity summaries 2023[R]. Virginia: U.S.Geological Survey, 2023.
5 苏彤, 郭敏, 刘忠, 等. 全球锂资源综合评述[J]. 盐湖研究201927(3):104-111.
  SU Tong, GUO Min, LIU Zhong, et al. Comprehensive review of global lithium resources[J]. Journal of Salt Lake Research201927(3):104-111.
6 邢凯, 朱清, 任军平, 等. 全球锂资源特征及市场发展态势分析[J]. 地质通报202342(8):1402-1421.
  XING Kai, ZHU Qing, REN Junping, et al. Research on the characteristics and market development trend of global lithium resourc-es[J]. Geological Bulletin of China202342(8):1402-1421.
7 吴静, 任秀莲, 魏琦峰. 盐湖卤水中锂的分离提取研究进展[J]. 无机盐工业202052(12):1-6.
  WU Jing, REN Xiulian, WEI Qifeng. Research progress on separation and extraction of lithium from salt-lake brine[J]. Inorganic Chemicals Industry202052(12):1-6.
8 刘东帆, 孙淑英, 于建国. 盐湖卤水提锂技术研究与发展[J]. 化工学报201869(1):141-155.
  LIU Dongfan, SUN Shuying, YU Jianguo. Research and development on technique of lithium recovery from salt lake brine[J]. CIESC Journal201869(1):141-155.
9 韩佳欢, 乜贞, 方朝合, 等. 中国锂资源供需现状分析[J]. 无机盐工业202153(12):61-66.
  HAN Jiahuan, NIE Zhen, FANG Chaohe, et al. Analysis of existing circumstance of supply and demand on China′s lithium resourc-es[J]. Inorganic Chemicals Industry202153(12):61-66.
10 葛涛, 徐亮, 孟金伟, 等. 盐湖卤水提锂工艺技术研究进展[J]. 有色金属工程202111(2):55-62.
  GE Tao, XU Liang, MENG Jinwei, et al. Research progress of lithium extraction technology from salt lake brine[J]. Nonferrous Metals Engineering202111(2):55-62.
11 余疆江, 郑绵平, 伍倩. 富锂盐湖提锂工艺研究进展[J]. 化工进展201332(1):13-21.
  YU Jiangjiang, ZHENG Mianping, WU Qian. Research progress of lithium extraction process in lithium-containing salt lake[J]. Chemical Industry and Engineering Progress201332(1):13-21.
12 张苏江, 崔立伟, 孔令湖, 等. 国内外锂矿资源及其分布概述[J]. 有色金属工程202010(10):95-104.
  ZHANG Sujiang, CUI Liwei, KONG Linghu, et al. Summarize on the lithium mineral resources and their distribution at home and abroad[J]. Nonferrous Metals Engineering202010(10):95-104.
13 高世扬, 宋彭生, 夏树屏, 等. 盐湖化学:新类型硼锂盐湖[M]. 北京: 科学出版社, 2007.
14 姜旭, 周保华, 乜贞. 中国盐湖卤水蒸发实验研究进展[J]. 无机盐工业201345(6):1-3,32.
  JIANG Xu, ZHOU Baohua, NIE Zhen. Experimental research progress in evaporation of salt lake brine[J]. Inorganic Chemicals Industry201345(6):1-3,32.
15 李武, 董亚萍, 宋彭生, 等. 盐湖卤水资源开发利用[M]. 北京: 化学工业出版社, 2012.
16 柳大纲. 柳大纲科学论著选集[M]. 《柳大纲科学论著选集》编委会,编.北京: 科学出版社, 1997.
17 成怀刚, 程芳琴. 水盐体系相分离[M]. 北京: 冶金工业出版社, 2022.
18 白燕祥, 王松博, 国爽, 等. 青海柴达木盆地盐湖资源元素利用及研究现状[J]. 盐科学与化工202352(3):1-6,19.
  BAI Yanxiang, WANG Songbo, GUO Shuang, et al. Utilization and research status of salt lake resources in Qaidam Basin,Qinghai[J]. Journal of Salt Science and Chemical Industry202352(3):1-6,19.
19 马珍. 盐湖锂资源高效分离提取技术研究进展[J]. 无机盐工业202254(10):22-29.
  MA Zhen. Research progress on efficient separation and extraction technology of lithium resources in salt lakes[J]. Inorganic Chemicals Industry202254(10):22-29.
20 付煜, 邓觅, 黄冬根, 等. 盐湖卤水提锂技术研究进展[J]. 无机盐工业202355(9):9-16,65.
  FU Yu, DENG Mi, HUANG Donggen, et al. Research progress of lithium extraction technology from salt lake brine[J]. Inorganic Chemicals Industry202355(9):9-16,65.
21 张苏江, 张琳, 姜爱玲, 等. 中国盐湖资源开发利用现状与发展建议[J]. 无机盐工业202254(10):13-21.
  ZHANG Sujiang, ZHANG Lin, JIANG Ailing, et al. Current situation and development suggestions of development and utilization of salt lake resources in China[J]. Inorganic Chemicals Industry202254(10):13-21.
22 郑绵平, 张永生, 刘喜方, 等. 中国盐湖科学技术研究的若干进展与展望[J]. 地质学报201690(9):2123-2166.
  ZHENG Mianping, ZHANG Yongsheng, LIU Xifang, et al. Progress and prospects of salt lake research in China[J]. Acta Geologica Sinica201690(9):2123-2166.
23 林钰青, 张以任, 邱宇隆, 等. 膜技术在盐湖提锂中的进展和展望[J]. 无机盐工业202355(1):33-45.
  LIN Yuqing, ZHANG Yiren, QIU Yulong, et al. Progress and prospect of membrane technology in lithium extraction from salt lake brine[J]. Inorganic Chemicals Industry202355(1):33-45.
24 李燕, 王敏, 赵有璟, 等. 盐湖卤水锂资源提取技术及开发现状[J]. 盐湖研究202331(2):71-80.
  LI Yan, WANG Min, ZHAO Youjing, et al. Technology and development of lithium extraction from salt lake brine[J]. Journal of Salt Lake Research202331(2):71-80.
25 张秀峰, 谭秀民, 张利珍. 纳滤膜分离技术应用于盐湖卤水提锂的研究进展[J]. 无机盐工业201749(1):1-5.
  ZHANG Xiufeng, TAN Xiumin, ZHANG Lizhen. Research progress in lithium extraction from salt lake brine by nanofiltration membrane separation technology[J]. Inorganic Chemicals Industry201749(1):1-5.
26 唐发满, 解安福, 昝超, 等. 东、西台吉乃尔盐湖及一里坪盐湖卤水资源开发现状及对策研究[J]. 化工矿物与加工202049(2):48-51,56.
  TANG Faman, XIE Anfu, ZAN Chao, et al. Research on development status and countermeasure of brine resources in East-West Ginair and Yiliping Salt Lake[J]. Industrial Minerals & Processing202049(2):48-51,56.
27 杜海涛, 王珂, 李心萍, 等. 靠实干开创更加美好的未来[N/OL]. 人民日报2023-02-06(1). .
28 高峰, 郑绵平, 乜贞, 等. 盐湖卤水锂资源及其开发进展[J]. 地球学报201132(4):483-492.
  GAO Feng, ZHENG Mianping, NIE Zhen, et al. Brine lithium resource in the salt lake and advances in its exploitation[J]. Acta Geoscientica Sinica201132(4):483-492.
29 GAO Feng, ZHENG Mianping, SONG Pengsheng, et al. The 273.15-K-isothermal evaporation experiment of lithium brine from the Zhabei salt lake,Tibet,and its geochemical significan- ce[J]. Aquatic Geochemistry201218(4):343-356.
30 王云生, 郑绵平, 乜贞, 等. 西藏扎北盐湖秋季卤水(硫酸钠亚型)5 ℃等温蒸发实验研究[J]. 地球学报201132(4):477-482.
  WANG Yunsheng, ZHENG Mianping, NIE Zhen, et al. 5 ℃-isothermal evaporation experiment of autumn brines from the sodium sulfate subtype Zhabei salt lake in Tibet[J]. Acta Geoscientica Sinica201132(4):477-482.
31 高峰, 郑绵平, 乜贞, 等. 西藏扎北盐湖夏季卤水自然蒸发实验研究[J]. 盐湖研究201119(4):21-27.
  GAO Feng, ZHENG Mianping, NIE Zhen, et al. Study on natural evaporation of summer brine of Zabei salt lake in Tibet,China[J]. Journal of Salt Lake Research201119(4):21-27.
32 ZHANG Yongming, LI Wu. Isothermal evaporations of the brine from Tibet′s Laguocuo salt lake at 15 ℃:Experiment and UNIQUAC simulations[J]. Crystals202313(3):496.
33 张宝全, 刘铸唐, 符廷进, 等. 东台吉乃尔盐湖卤水的相化学研究(Ⅱ):冬夏季卤水蒸发实验[J]. 盐湖研究19942(3):27-34.
  ZHANG Baoquan, LIU Zhutang, FU Tingjin, et al. Study of the phase chemistry of Dongtaijinaier salt lake brine(Ⅱ):Solar evaporation in summer and winter[J]. Journal of Salt Lake Research19942(3):27-34.
34 李陇岗, 曾英, 杨建元, 等. 东台吉乃尔盐湖冬季卤水25 ℃等温蒸发实验[J]. 盐业与化工201342(6):21-24.
  LI Longgang, ZENG Ying, YANG Jianyuan, et al. 25 ℃-isothermal evaporation experiment on winter brine from Dongtaijinaier salt lake[J]. Journal of Salt and Chemical Industry201342(6):21-24.
35 余明祥, 谢云荣, 任元成, 等. 西台吉乃尔盐湖卤水等温蒸发实验研究[J]. 盐业与化工201241(8):7-10.
  YU Mingxiang, XIE Yunrong, REN Yuancheng, et al. Experimental study on isothermal evaporation with saline brine in west Taijinar[J]. Journal of Salt and Chemical Industry201241(8):7-10.
36 苏建军, 曾英, 李陇岗, 等. 西台吉乃尔盐湖析钾老卤及冻卤25 ℃等温蒸发实验研究[J]. 无机盐工业202254(5):84-89,95.
  SU Jianjun, ZENG Ying, LI Longgang, et al. Study on isothermal evaporation of potassium-extracted old brine and frozen brine in West Taijinar Salt Lake at 25 ℃[J]. Inorganic Chemicals Industry202254(5):84-89,95.
37 李陇岗. 玻利维亚Uyuni盐湖卤水25 ℃等温蒸发实验[J]. 盐湖研究202129(2):44-49.
  LI Longgang. Study on the isothermal evaporation of Uyuni salt lake brine,Bolivia at 25 ℃[J]. Journal of Salt Lake Research202129(2):44-49.
38 SKARULIS J A, HORAN H A. The system Na2SO4-Li2SO4-H2O at 0°[J]. Journal of the American Chemical Society195577(13):3489-3490.
39 GUO Yafei, LIU Yuanhui, WANG Qin, et al. Phase equilibria and phase diagrams for the aqueous ternary system(Na2SO4+Li2SO4+H2O) at(288 and 308) K[J]. Journal of Chemical & Engineering Data201358(10):2763-2767.
40 YU Xudong, YAO Zhihao, ZHAO Zhixing, et al. Phase equilibria of aqueous ternary systems Li2SO4+Na2SO4+H2O and Na2SO42SO4+H2O at 303.2 K[J]. Journal of Chemical & Engineering Data202368(2):474-482.
41 ZENG Ying, LIN Xiaofeng, YU Xudong. Study on the solubility of the aqueous quaternary system Li2SO4+Na2SO4+K2SO4+H2O at 273.15 K[J]. Journal of Chemical & Engineering Data201257(12):3672-3676.
42 赵志星, 姚智豪, 黄琴, 等. 四元体系Li2SO4+Na2SO4+K2SO4+H2O 298.2 K相平衡研究[J]. 盐湖研究202230(4):41-49.
  ZHAO Zhixing, YAO Zhihao, HUANG Qin, et al. Phase equilibria of aqueous quaternary system Li2SO4+Na2SO4+K2SO4+H2O at 298.2 K[J]. Journal of Salt Lake Research202230(4):41-49.
43 李冰, 孙柏, 房春晖, 等. 五元体系Li+,Na+,K+,Mg2+//SO4 2--H2O 25 ℃相关系的研究[J]. 化学学报199755(6):545-552.
  LI Bing, SUN Bai, FANG Chunhui, et al. Studies on the phase diagram for the quinary system Li+,Na+,K+,Mg2+//SO4 2--H2O at 25 ℃[J]. Acta Chimica Sinica199755(6):545-552.
44 林晓峰, 曾英, 郑志远. Na+,K+//SO4 2--H2O三元体系273 K介稳相平衡研究[J]. 盐湖研究200715(3):24-27.
  LIN Xiaofeng, ZENG Ying, ZHENG Zhiyuan. Study on metastable phase equilibrium of Na+,K+//SO4 2--H2O ternary system at 273 K[J]. Journal of Salt Lake Research200715(3):24-27.
45 牛自得, 程芳琴, 李宝存, 等. 水盐体系相图及其应用[M]. 天津: 天津大学出版社, 2002.
46 陈敬清, 刘子琴, 符廷进. 东台吉乃尔湖间晶卤水25 ℃等温蒸发与天然蒸发试验[J]. 盐湖科技资料1980(Z1):71-82.
  CHEN Jingqing, LIU Ziqin, FU Tingjin. Experiment on isothermal evaporation and natural evaporation of intercrystalline brine at 25 ℃ in Dongtaijinaier salt lake[J]. Journal of Salt Lake Research1980(Z1):71-82.
47 张宝全, 刘铸唐, 符廷进, 等. 东台吉乃尔盐湖卤水的相化学研究(Ⅰ)25 ℃等温蒸发实验[J]. 盐湖研究19942(2):57-61.
  ZHANG Baoquan, LIU Zhutang, FU Tingjin, et al. Study of the phase chemistry of Dongtaijinaier salt lake brine(Ⅰ):Isothermal evaporation at 25 ℃[J]. Journal of Salt Lake Research19942(2):57-61.
48 宋彭生, 李武, 孙柏, 等. 盐湖资源开发利用进展[J]. 无机化学学报201127(5):801-815.
  SONG Pengsheng, LI Wu, SUN Bai, et al. Recent development on comprehensive utilization of salt lake resources[J]. Chinese Journal of Inorganic Chemistry201127(5):801-815.
49 郭爱武, 李吉生, 王菊香, 等. 西台吉乃尔盐湖卤水自然蒸发试验研究[J]. 盐湖研究200917(3):29-31.
  GUO Aiwu, LI Jisheng, WANG Juxiang, et al. Study on natural evaporation of brine in west Taijinar salt lakes[J]. Journal of Salt Lake Research200917(3):29-31.
50 王冀洺, 乜贞, 樊馥, 等. 西台吉乃尔盐湖盐田与模拟蒸发过程卤水钾、锂的损失研究[J]. 无机盐工业202355(5):31-38.
  WANG Jiming, NIE Zhen, FAN Fu, et al. Study on potassium and lithium resource loss in brine of West Taijinar Salt Lake and simulated evaporation process[J]. Inorganic Chemicals Industry202355(5):31-38.
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