甲醇氧化制甲醛工艺及催化剂研究进展
收稿日期: 2023-03-16
网络出版日期: 2023-11-16
Advances in technology and catalyst for methanol oxidized to formaldehyde
Received date: 2023-03-16
Online published: 2023-11-16
李贺 , 张利杰 , 张凯 , 苏晋 , 姚朝阳 , 曾贤君 , 郭春垒 , 孙彦民 . 甲醇氧化制甲醛工艺及催化剂研究进展[J]. 无机盐工业, 2023 , 55(11) : 12 -18 . DOI: 10.19964/j.issn.1006-4990.2023-0146
The silver method and ferro-molybdenum method for producing formaldehyde by air oxidation of methanol were summarized and compared.Silver method was employed as the main technology of formaldehyde production in China for its maturity.Ferro-molybdenum method was more suitable for the planning and development of formaldehyde industry for its low methanol consumption，high formaldehyde yield，long catalyst life and good economic benefit.Nevertheless，domestic technology of ferro-molybdenum method was not mature.The research progresses of silver，ferro-molybdenum and vanadium catalysts were reviewed.Silver catalyst was difficult to be improved greatly.Ferro-molybdenum was researched as a hotspot，and vanadium catalyst was still far away from industrial application.Further study on reaction mechanism for performance improvement of ferro-molybdenum catalyst was proposed as an important subject of methanol oxidation to formaldehyde.The development of ferro-molybdenum catalyst which was more compatible with the existing silver method process was suggested as the main research direction of formaldehyde production technology in the future.
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