无机盐工业
主管:中海油天津化工研究设计院有限公司
主办:中海油天津化工研究设计院有限公司
   中海油炼油化工科学研究院(北京)有限公司
   中国化工学会无机酸碱盐专业委员会
ISSN 1006-4990 CN 12-1069/TQ
环境·健康·安全

从工业硅渣中回收硅和铝的研究

  • 罗文波 ,
  • 李恒 ,
  • 吕钧 ,
  • 杨林光 ,
  • 赵兴凡 ,
  • 龙潇
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  • 1.贵州理工学院 材料与能源工程学院,贵州 贵阳 550003
    2.芒市永隆铁合金有限公司,云南芒市 678400
    3.云南省 ;龙陵县龙山硅有限责任公司,云南龙陵 678300
    4.龙陵县鹏越科技咨询服务有限责任公司,云南龙陵 678300
罗文波(1983— ),男,博士,副教授,主要研究方向为加压湿法冶金和二次资源综合利用研究;E-mail:luowenbo@126.com
龙潇(1988— ),男,博士,副教授,主要研究方向为金属连铸凝固技术,炼钢和二次精炼新技术;E-mail:609412746@qq.com

收稿日期: 2022-11-09

  网络出版日期: 2023-09-19

Study on recovery of silicon and aluminum from industrial silicon slag

  • LUO Wenbo ,
  • LI Heng ,
  • Lü Jun ,
  • YANG Linguang ,
  • ZHAO Xingfan ,
  • LONG Xiao
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  • 1.Faculty of Materials and Energy Engineering,Guizhou Institute of Technology,Guiyang 550003,China
    2.Mangshi Yonglong Ferroalloy Co. ,Ltd,Mangshi 678400,China
    3.Yunnan Longling Longshan silicon Co. ,Ltd,Longling 678300,China
    4.Longling Pengyue Technology Consulting Service Co. ,Ltd,Longling 678300,China

Received date: 2022-11-09

  Online published: 2023-09-19

摘要

工业硅渣主要成分为硅、铝、钙三元氧化物及少量单质硅,其他杂质含量极少,可以作为制备高品质分子筛的原料。采用“苏打焙烧-碱浸”工艺从工业硅渣中提取硅酸钠和铝酸钠溶液,考察焙烧时间、焙烧温度、碳酸钠加入量对硅、铝浸出率的影响。结果表明:在焙烧温度为800 ℃、焙烧时间为30 min、碳酸钠加入量为理论量1.1倍的优化条件下,硅、铝转换率高,碱浸出时硅、铝的浸出率分别为82.34%和67.10%。该工艺可行,解决了工业硅废渣堆存问题,同时带来可观经济效益。

本文引用格式

罗文波 , 李恒 , 吕钧 , 杨林光 , 赵兴凡 , 龙潇 . 从工业硅渣中回收硅和铝的研究[J]. 无机盐工业, 2023 , 55(9) : 94 -99 . DOI: 10.19964/j.issn.1006-4990.2022-0664

Abstract

The industrial silicon slag is mainly composed of silicon,aluminum,calcium ternary oxides and a small amount of silicon.The content of other impurities is extremely rare.It can be used as the raw material for high-quality molecular sieve.Sodium silicate and sodium aluminate solution were extracted from industrial silicon slag by "baking soda alkali leaching" process.The effects of calcination time,calcination temperature and sodium carbonate addition on the leach rate of silicon and aluminum were investigated.The results showed that under the optimum conditions of calcination temperature of 800 ℃,calcination time of 30 min and 1.1 times of the theoretical amount of sodium carbonate,the conversion rate of silicon and aluminum was high,and the leach rates of silicon and aluminum in alkali leaching were 82.34% and 67.10% respectively.The process was feasible,which solved the problem of industrial silicon waste residue stockpiling and brings considerable economic benefits.

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