无机盐工业
主管:中海油天津化工研究设计院有限公司
主办:中海油天津化工研究设计院有限公司
   中海油炼油化工科学研究院(北京)有限公司
   中国化工学会无机酸碱盐专业委员会
ISSN 1006-4990 CN 12-1069/TQ
催化材料

石墨化碳修饰碳化稻壳泡沫的制备及光热水蒸发性能

  • 鲁琴 ,
  • 方伟 ,
  • 赵雷
展开
  • 1.武汉华工图像技术开发有限公司,湖北 武汉 430223
    2.武汉科技大学省部共建 耐火材料与冶金国家重点实验室,湖北 武汉 430081
鲁琴(1973— ),女,硕士,工程师,主要研究方向为多孔碳功能材料;E-mail:luqin@hgimage.com
赵雷(1969— ),男,博士,教授,主要研究方向为光能转换与应用;E-mail:zhaolei@wust.edu.cn

收稿日期: 2022-09-05

  网络出版日期: 2023-07-13

Preparation of graphitized carbon modified carbonized rice husk foam and its solar steam generation performance

  • LU Qin ,
  • FANG Wei ,
  • ZHAO Lei
Expand
  • 1. Wuhan Huagong Image Technology & Development Co. ,Ltd,Wuhan 430223,China
    2. The State Key Laboratory of Refractories and Metallurgy,Wuhan University of Science & Technology,Wuhan 430081,China

Received date: 2022-09-05

  Online published: 2023-07-13

摘要

为了改善生物质碳化稻壳光热转换效率不足的问题,提出利用过渡金属催化技术调控其热解碳结构,优化光热水蒸发性能。首先,制备具有多孔结构的稻壳泡沫,并在此基础上引入硝酸镍作为催化剂前驱体,在高温碳化过程中通过Ni高温催化作用催化稻壳热解碳石墨化制备石墨化碳修饰碳化稻壳泡沫(GC/CRF)光吸收体,系统研究光吸收体结构、光吸收率和光热水蒸发性能。结果表明:制备的GC/CRF光吸收体有效地保留了稻壳泡沫原有的三维多孔结构,孔径在10~100 µm,催化剂Ni均匀分散在泡沫基体中;Ni的高温催化作用使GC/CRF中原位形成大量纳米球,纳米球为典型的核壳结构,核层为纳米Ni颗粒,壳层为薄层石墨化碳;石墨化碳的形成可有效提高光吸收体的石墨化程度,进而改善光吸收率和光热水蒸发性能;碳化温度为1 200 ℃时,制备的GC/CRF光吸收体具有最优的光吸收率和光热转换效率,分别约为94%和70%。

本文引用格式

鲁琴 , 方伟 , 赵雷 . 石墨化碳修饰碳化稻壳泡沫的制备及光热水蒸发性能[J]. 无机盐工业, 2023 , 55(7) : 122 -129 . DOI: 10.19964/j.issn.1006-4990.2022-0533

Abstract

To improve the solar-thermal conversion efficiency of biomass carbonized rice husk,the transition metal catalytic technique was proposed to regulate the pyrolytic carbon structure of carbonized rice husk and optimize the solar steam generation performance.Firstly,a typical porous rice husk foam was constructed with introducing nickel nitrate as a catalyst precursor.And then,the graphitized carbon modified carbonized rice husk foam(GC/CRF) absorber was prepared by employing transition metal Ni as catalyst to in-situ catalyze the pyrolytic carbon of rice husk graphitizing during the carbonation process.The structure,light absorption and solar steam generation performance of GC/CRF were investigated.It was showed that the prepared GC/CRF availably retained the three-dimensional porous structure of original rice husk foam with pore sizes range from 10~100 µm,and Ni catalyst was uniformly dispersed in the foam structure.By the catalysis of Ni,large numbers of core-shell nanospheres were also formed in the absorber,with nano Ni as core and graphitized carbon layer as shell.The formation of graphitized carbon showed positive effect on improving the graphitization degree of GC/CRF,so as to enhance the light absorption and solar steam generation performance.After carbonizing at 1 200 ℃,the GC/CRF absorber achieved maximum absorption and solar-vapor evaporation efficiency with values up to ~94% and ~70%.

参考文献

1 MIN Xinzhe, ZHU Bin, LI Bo,et al.Interfacial solar vapor generation:Materials and structural design[J].Accounts of Materials Research20212(4):198-209.
2 MENG Xiangyu, PENG Xiaoli, XUE Jing,et al.A biomass-derived,all-day-round solar evaporation platform for harvesting clean water from microplastic pollution[J].Journal of Materials Chemistry A20219(17):11013-11024.
3 JIN Haichuan, LIN Guiping, BAI Lizhan,et al.Steam generation in a nanoparticle-based solar receiver[J].Nano Energy201628:397-406.
4 GUO Ankang, FU Yang, WANG Gang,et al.Diameter effect of gold nanoparticles on photothermal conversion for solar steam generation[J].RSC Advances20177(8):4815-4824.
5 GHASEMI H, NI G, MARCONNET A M,et al.Solar steam generation by heat localization[J].Nature Communications20145:4449.
6 ZHOU Lin, TAN Yingling, WANG Jingyang,et al.3D self-assembly of aluminium nanoparticles for plasmon-enhanced solar desalination[J].Nature Photonics201610(6):393-398.
7 ZHOU Lin, TAN Yingling, JI Dengxin,et al.Self-assembly of highly efficient,broadband plasmonic absorbers for solar steam generation[J].Science Advances20162(4):e1501227.
8 王星瑶,顾宇飞,王鹏飞,等.聚吡咯壳聚糖复合气凝胶的制备及光热性能[J].功能高分子学报202235(2):196-202.
  WANG Xingyao, GU Yufei, WANG Pengfei,et al.Preparation and photothermal properties of polypyrrole chitosan composite aero-
  gels[J].Journal of Functional Polymers202235(2):196-202.
9 薛超瑞,李洋森,黄蕊蕊,等.BiOBr/Bi复合光热粉体的制备及其界面光热驱动水蒸发性能[J].复合材料学报202239(7):3271-3280.
  XUE Chaorui, LI Yangsen, HUANG Ruirui,et al.Preparation of BiOBr/Bi composite photothermal powder and its interfacial photothermal driven water evaporation performance[J].Acta Materiae Compositae Sinica202239(7):3271-3280.
10 HU Xiaozhen, XU Weichao, ZHOU Lin,et al.Tailoring graphene oxide-based aerogels for efficient solar steam generation under one Sun[J].Advanced Materials201729(5):1604031.
11 李亚玲,杨曙光,王义.石墨烯基复合水凝胶的制备及其在海水脱盐净化中的应用[J].东华大学学报(自然科学版)202147(6):1-6,28.
  LI Yaling, YANG Shuguang, WANG Yi.Preparation of graphene-based composite hydrogels and its application in seawater desalination and purification[J].Journal of Donghua University(Natural Science)202147(6):1-6,28.
12 YIN Zhe, WANG Huimin, JIAN Muqiang,et al.Extremely black vertically aligned carbon nanotube arrays for solar steam generation[J].ACS Applied Materials & Interfaces20179(34):28596-28603.
13 FANG Jing, LIU Jie, GU Jiajun,et al.Hierarchical porous carbonized lotus seedpods for highly efficient solar steam generation[J].Chemistry of Materials201830(18):6217-6221.
14 ZHU Mengmeng, YU Jialiang, MA Cunlin,et al.Carbonized daikon for high efficient solar steam generation[J].Solar Energy Materials and Solar Cells2019191:83-90.
15 XUE Guobin, LIU Kang, CHEN Qian,et al.Robust and low-cost flame-treated wood for high-performance solar steam generati-
  on[J].ACS Applied Materials & Interfaces20179(17):15052-15057.
16 ZHU Mingwei, LI Yiju, CHEN Guang,et al.Tree-inspired design for high-efficiency water extraction[J].Advanced Materials201729(44):1704107.
17 XU Ning, HU Xiaozhen, XU Weichao,et al.Mushrooms as efficient solar steam-generation devices[J].Advanced Materials201729(28):1606762.
18 FANG Wei, ZHAO Lei, HE Xuan,et al.Carbonized rice husk foam constructed by surfactant foaming method for solar steam generation[J].Renewable Energy2020151:1067-1075.
19 NI G, MILJKOVIC N, GHASEMI H,et al.Volumetric solar heating of nanofluids for direct vapor generation[J].Nano Energy201517:290-301.
20 KANG Shifei, HE Maofen, YIN Chaochuang,et al.Graphitic carbon embedded with Fe/Ni nano-catalysts derived from bacterial precursor for efficient toluene cracking[J].Green Chemistry202022(6):1934-1943.
21 CHEN Hui, ZHAO Lei, WANG Xitang,et al.Hybrid one-dimensional nanostructure based on biomorphic porous SiO2 through in situ catalytic pyrolysis of rice husk[J].Ceramics International201541(4):6089-6097.
22 LI Xiuqiang, NI G, COOPER T,et al.Measuring conversion efficiency of solar vapor generation[J].Joule20193(8):1798-1803.
文章导航

/