石墨化碳修饰碳化稻壳泡沫的制备及光热水蒸发性能
收稿日期: 2022-09-05
网络出版日期: 2023-07-13
Preparation of graphitized carbon modified carbonized rice husk foam and its solar steam generation performance
Received date: 2022-09-05
Online published: 2023-07-13
为了改善生物质碳化稻壳光热转换效率不足的问题,提出利用过渡金属催化技术调控其热解碳结构,优化光热水蒸发性能。首先,制备具有多孔结构的稻壳泡沫,并在此基础上引入硝酸镍作为催化剂前驱体,在高温碳化过程中通过Ni高温催化作用催化稻壳热解碳石墨化制备石墨化碳修饰碳化稻壳泡沫(GC/CRF)光吸收体,系统研究光吸收体结构、光吸收率和光热水蒸发性能。结果表明:制备的GC/CRF光吸收体有效地保留了稻壳泡沫原有的三维多孔结构,孔径在10~100 µm,催化剂Ni均匀分散在泡沫基体中;Ni的高温催化作用使GC/CRF中原位形成大量纳米球,纳米球为典型的核壳结构,核层为纳米Ni颗粒,壳层为薄层石墨化碳;石墨化碳的形成可有效提高光吸收体的石墨化程度,进而改善光吸收率和光热水蒸发性能;碳化温度为1 200 ℃时,制备的GC/CRF光吸收体具有最优的光吸收率和光热转换效率,分别约为94%和70%。
鲁琴 , 方伟 , 赵雷 . 石墨化碳修饰碳化稻壳泡沫的制备及光热水蒸发性能[J]. 无机盐工业, 2023 , 55(7) : 122 -129 . DOI: 10.19964/j.issn.1006-4990.2022-0533
To improve the solar-thermal conversion efficiency of biomass carbonized rice husk,the transition metal catalytic technique was proposed to regulate the pyrolytic carbon structure of carbonized rice husk and optimize the solar steam generation performance.Firstly,a typical porous rice husk foam was constructed with introducing nickel nitrate as a catalyst precursor.And then,the graphitized carbon modified carbonized rice husk foam(GC/CRF) absorber was prepared by employing transition metal Ni as catalyst to in-situ catalyze the pyrolytic carbon of rice husk graphitizing during the carbonation process.The structure,light absorption and solar steam generation performance of GC/CRF were investigated.It was showed that the prepared GC/CRF availably retained the three-dimensional porous structure of original rice husk foam with pore sizes range from 10~100 µm,and Ni catalyst was uniformly dispersed in the foam structure.By the catalysis of Ni,large numbers of core-shell nanospheres were also formed in the absorber,with nano Ni as core and graphitized carbon layer as shell.The formation of graphitized carbon showed positive effect on improving the graphitization degree of GC/CRF,so as to enhance the light absorption and solar steam generation performance.After carbonizing at 1 200 ℃,the GC/CRF absorber achieved maximum absorption and solar-vapor evaporation efficiency with values up to ~94% and ~70%.
| 1 | MIN Xinzhe, ZHU Bin, LI Bo,et al.Interfacial solar vapor generation:Materials and structural design[J].Accounts of Materials Research,2021,2(4):198-209. |
| 2 | MENG Xiangyu, PENG Xiaoli, XUE Jing,et al.A biomass-derived,all-day-round solar evaporation platform for harvesting clean water from microplastic pollution[J].Journal of Materials Chemistry A,2021,9(17):11013-11024. |
| 3 | JIN Haichuan, LIN Guiping, BAI Lizhan,et al.Steam generation in a nanoparticle-based solar receiver[J].Nano Energy,2016,28:397-406. |
| 4 | GUO Ankang, FU Yang, WANG Gang,et al.Diameter effect of gold nanoparticles on photothermal conversion for solar steam generation[J].RSC Advances,2017,7(8):4815-4824. |
| 5 | GHASEMI H, NI G, MARCONNET A M,et al.Solar steam generation by heat localization[J].Nature Communications,2014,5:4449. |
| 6 | ZHOU Lin, TAN Yingling, WANG Jingyang,et al.3D self-assembly of aluminium nanoparticles for plasmon-enhanced solar desalination[J].Nature Photonics,2016,10(6):393-398. |
| 7 | ZHOU Lin, TAN Yingling, JI Dengxin,et al.Self-assembly of highly efficient,broadband plasmonic absorbers for solar steam generation[J].Science Advances,2016,2(4):e1501227. |
| 8 | 王星瑶,顾宇飞,王鹏飞,等.聚吡咯壳聚糖复合气凝胶的制备及光热性能[J].功能高分子学报,2022,35(2):196-202. |
| WANG Xingyao, GU Yufei, WANG Pengfei,et al.Preparation and photothermal properties of polypyrrole chitosan composite aero- | |
| gels[J].Journal of Functional Polymers,2022,35(2):196-202. | |
| 9 | 薛超瑞,李洋森,黄蕊蕊,等.BiOBr/Bi复合光热粉体的制备及其界面光热驱动水蒸发性能[J].复合材料学报,2022,39(7):3271-3280. |
| XUE Chaorui, LI Yangsen, HUANG Ruirui,et al.Preparation of BiOBr/Bi composite photothermal powder and its interfacial photothermal driven water evaporation performance[J].Acta Materiae Compositae Sinica,2022,39(7):3271-3280. | |
| 10 | HU Xiaozhen, XU Weichao, ZHOU Lin,et al.Tailoring graphene oxide-based aerogels for efficient solar steam generation under one Sun[J].Advanced Materials,2017,29(5):1604031. |
| 11 | 李亚玲,杨曙光,王义.石墨烯基复合水凝胶的制备及其在海水脱盐净化中的应用[J].东华大学学报(自然科学版),2021,47(6):1-6,28. |
| LI Yaling, YANG Shuguang, WANG Yi.Preparation of graphene-based composite hydrogels and its application in seawater desalination and purification[J].Journal of Donghua University(Natural Science),2021,47(6):1-6,28. | |
| 12 | YIN Zhe, WANG Huimin, JIAN Muqiang,et al.Extremely black vertically aligned carbon nanotube arrays for solar steam generation[J].ACS Applied Materials & Interfaces,2017,9(34):28596-28603. |
| 13 | FANG Jing, LIU Jie, GU Jiajun,et al.Hierarchical porous carbonized lotus seedpods for highly efficient solar steam generation[J].Chemistry of Materials,2018,30(18):6217-6221. |
| 14 | ZHU Mengmeng, YU Jialiang, MA Cunlin,et al.Carbonized daikon for high efficient solar steam generation[J].Solar Energy Materials and Solar Cells,2019,191:83-90. |
| 15 | XUE Guobin, LIU Kang, CHEN Qian,et al.Robust and low-cost flame-treated wood for high-performance solar steam generati- |
| on[J].ACS Applied Materials & Interfaces,2017,9(17):15052-15057. | |
| 16 | ZHU Mingwei, LI Yiju, CHEN Guang,et al.Tree-inspired design for high-efficiency water extraction[J].Advanced Materials,2017, 29(44):1704107. |
| 17 | XU Ning, HU Xiaozhen, XU Weichao,et al.Mushrooms as efficient solar steam-generation devices[J].Advanced Materials,2017,29(28):1606762. |
| 18 | FANG Wei, ZHAO Lei, HE Xuan,et al.Carbonized rice husk foam constructed by surfactant foaming method for solar steam generation[J].Renewable Energy,2020,151:1067-1075. |
| 19 | NI G, MILJKOVIC N, GHASEMI H,et al.Volumetric solar heating of nanofluids for direct vapor generation[J].Nano Energy,2015,17:290-301. |
| 20 | KANG Shifei, HE Maofen, YIN Chaochuang,et al.Graphitic carbon embedded with Fe/Ni nano-catalysts derived from bacterial precursor for efficient toluene cracking[J].Green Chemistry,2020,22(6):1934-1943. |
| 21 | CHEN Hui, ZHAO Lei, WANG Xitang,et al.Hybrid one-dimensional nanostructure based on biomorphic porous SiO2 through in situ catalytic pyrolysis of rice husk[J].Ceramics International,2015,41(4):6089-6097. |
| 22 | LI Xiuqiang, NI G, COOPER T,et al.Measuring conversion efficiency of solar vapor generation[J].Joule,2019,3(8):1798-1803. |
/
| 〈 |
|
〉 |