无机盐工业
主管:中海油天津化工研究设计院有限公司
主办:中海油天津化工研究设计院有限公司
   中海油炼油化工科学研究院(北京)有限公司
   中国化工学会无机酸碱盐专业委员会
ISSN 1006-4990 CN 12-1069/TQ
综述与专论

熔盐改性的金属氧化物捕获二氧化碳研究进展

  • 许春辉 ,
  • 王峰 ,
  • 凌长见 ,
  • 王子睿 ,
  • 唐忠锋
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  • 1.内蒙古工业大学能源与动力工程学院, 内蒙古呼和浩特 010051
    2.中国科学院上海应用物理研究所, 上海 201800
    3.中国科学院青海盐湖研究所, 青海西宁 810008
许春辉(1996— ),男,硕士研究生,主要研究方向为碳捕集及熔盐储能;E-mail:xuchunhui430@163.com
王峰(1981— ),女,博士,副教授,主要研究方向为碳捕集技术、储热材料和微纳尺度传热传质等;E-mail:wangfeng@imut.edu.cn;
唐忠锋(1976— ),男,博士,研究员,主要研究方向为能源材料化学、碳捕集和熔盐储能等;E-mail:tangzhongfeng@sinap.ac.cn

收稿日期: 2022-07-26

  网络出版日期: 2023-05-15

基金资助

国家自然科学基金区域创新发展联合基金(U22A20434);青海省基础研究计划(2022-ZJ-706);内蒙古自治区自然科学基金资助项目(2019MS05071)

Research progress of CO2 capture by metal oxides modified by molten salts

  • XU Chunhui ,
  • WANG Feng ,
  • LING Changjian ,
  • WANG Zirui ,
  • TANG Zhongfeng
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  • 1. College of Energy and Power Engineering, Inner Mongolia University of Technology, Hohhot 010051, China
    2. Shanghai Institute of Applied Physics, Chinese Academy of Science, Shanghai 201800, China
    3. Qinghai Institute of Salt Lakes, Chinese Academy of Sciences, Xining 810008, China

Received date: 2022-07-26

  Online published: 2023-05-15

摘要

金属氧化物捕获二氧化碳(CO2)技术是减少碳排放的有效手段,然而其在捕获CO2方面存在吸附容量低和易板结等问题。目前,熔盐改性金属氧化物可有效解决以上问题。以水滑石类衍生镁铝氧化物、氧化镁和氧化钙为研究对象,综述了掺杂熔盐(如硝酸盐、亚硝酸盐、碳酸盐等)对金属氧化物捕获CO2性能的影响,分析了熔盐的改性机制,归纳了金属氧化物捕获CO2的应用进展。未来应更多关注熔盐掺杂体系设计、低成本高选择性吸附材料研发以及CO2捕获机制研究。同时,在实验中应尽可能模拟实际工况,为后续大规模工业应用提供支持。

本文引用格式

许春辉 , 王峰 , 凌长见 , 王子睿 , 唐忠锋 . 熔盐改性的金属氧化物捕获二氧化碳研究进展[J]. 无机盐工业, 2023 , 55(5) : 1 -7 . DOI: 10.19964/j.issn.1006-4990.2022-0452

Abstract

CO2 capture technology by metal oxide is an effective method for carbon emission reduction.However,metal oxides in CO2 capture have some problems,such as low adsorption capacity and easy hardening.At present,molten salt modification of metal oxide can effectively solve these problems.The hydrotalcite derived magnesium aluminum oxides,MgO and CaO were studied.The effects of doped molten salts(such as nitrate,nitrite,carbonate,etc.) on the CO2 capture performance of metal oxides were reviewed.The modification mechanism was analyzed and the application progress of CO2 capture by metal oxides was summarized.In the future,more attention should be paid to the design of doped molten salt system,the study of low-cost and highly selective adsorption materials and the study of capture mechanism.At the same time,practical working conditions should be simulated as much as possible in the experiment to provide support for subsequent large-scale industrial applications.

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