无机盐工业
主管:中海油天津化工研究设计院有限公司
主办:中海油天津化工研究设计院有限公司
   中海油炼油化工科学研究院(北京)有限公司
   中国化工学会无机酸碱盐专业委员会
ISSN 1006-4990 CN 12-1069/TQ
综述与专论

新型无机磷基阻燃剂的研究进展

  • 刘畅 ,
  • 段尊斌 ,
  • 汪建南 ,
  • 马会娟 ,
  • 王佳宏 ,
  • 喻学锋
展开
  • 1.湖北三峡实验室,湖北 宜昌 443007
    2.湖北兴发化工集团股份有限公司
    3.中国科学院深圳先进技术研究院
刘畅(1978— ),女,工程师,研究方向为磷硅化工及磷硅材料项目的开发和产业化;E-mail:466578168@qq.com

收稿日期: 2022-01-24

  网络出版日期: 2022-11-23

基金资助

国家自然科学基金(21975280);湖北三峡实验室开放/创新基金项目(SC213003)

Research progress on new inorganic phosphorus-based flame retardants

  • Chang LIU ,
  • Zunbin DUAN ,
  • Jiannan WANG ,
  • Huijuan MA ,
  • Jiahong WANG ,
  • Xuefeng YU
Expand
  • 1. Hubei Three Gorges Laboratory, Yichang 443007, China
    2. Hubei Xingfa Chemicals Group Co. Ltd.
    3. Shenzhen Institute of Advanced Technology, Chinese Academy of Sciences

Received date: 2022-01-24

  Online published: 2022-11-23

摘要

以黑磷基阻燃剂为代表的纳米级新型无机磷基阻燃剂,在极低的添加量下即可实现高分子材料的阻燃性能和机械性能的同步提高,表现出良好的应用前景。综述了新型无机磷基阻燃剂的研究进展,重点介绍了黑磷基阻燃剂的功能化策略、制备工艺、阻燃机理和应用进展,最后对发展趋势进行了展望。总结并评述了黑磷制备所用的超声剥离、球磨剥离、电化学插层剥离等纳米化工艺和利用阻燃有机/无机物质对黑磷进行共价或非共价的修饰策略,对比分析了溶液共混、熔融共混、原位聚合、涂层等复合制备工艺的利弊,归纳了黑磷基阻燃剂的结构与性能之间的基本规律,提出了今后在科学创新和工程突破两方面的研究重点。

本文引用格式

刘畅 , 段尊斌 , 汪建南 , 马会娟 , 王佳宏 , 喻学锋 . 新型无机磷基阻燃剂的研究进展[J]. 无机盐工业, 2022 , 54(11) : 8 -17 . DOI: 10.19964/j.issn.1006-4990.2022-0047

Abstract

Black phosphorus-based flame retardants,the representative of new nano inorganic phosphorus-based flame retardants,can achieve simultaneous improvement of the flame retardancy and mechanical properties of polymers at a low addition amount,showing good application prospects.The research progress on new inorganic phosphorus-based flame retardants was reviewed.The functional strategy,preparation process,flame retardant mechanism and application progress of black phosphorus-based flame retardants were mainly introduced.Finally,the development trend was prospected.The preparation of black phosphorus by nanoscale processes such as ultrasonic exfoliation,ball-milling exfoliation,electrochemical intercalation exfoliation,and targeted covalent or non-covalent modification strategies using flame-retardant organic/inorganic substances were reviewed.The advantages and disadvantages of composite preparation processes including solution blending,melt blending,in-situ polymerization and coating were analyzed.The rules between the structure and properties of black phosphorus-based flame retardants were summarized.Future research priorities in both scientific innovation and engineering breakthroughs were proposed.

参考文献

1 LAOUTID F, BONNAUD L, ALEXANDRE M, et al.New prospects in flame retardant polymer materials:From fundamentals to nanocomposites[J].Materials Science and Engineering:R:Reports,2009,63(3):100-125.
2 LAZAR S T, KOLIBABA T J, GRUNLAN J C.Flame-retardant surface treatments[J].Nature Reviews Materials,2020,5(4):259-275.
3 QU Guangbo, SHI Jianbo, WANG T, et al.Identification of tetrabromobisphenol A diallyl ether as an emerging neurotoxicant in environmental samples by bioassay-directed fractionation and HPLC-APCI-MS/MS[J].Environmental Science & Technology,2011,45(11):5009-5016.
4 蒋运才,付姣,李雪梅,等.纳米黑磷应用在阻燃领域的研究进展[J].磷肥与复肥,2021,36(12):20-26.
4 JIANG Yuncai, FU Jiao, LI Xuemei, et al.Recent advances of nano black phosphorus in flame retardant[J].Phosphate & Compound Fertilizer,2021,36(12):20-26.
5 HUO Siqi, SONG Pingan, YU Bin, et al.Phosphorus-containing flame retardant epoxy thermosets:Recent advances and future perspectives[J].Progress in Polymer Science,2021,114.Doi:10.1016/j.progpolymsci.2021.101366.
6 俞森龙,胡香凝,唐飞宇,等.聚乳酸阻燃改性研究进展[J].化工进展,2020,39(9):3421-3432.
6 YU Senlong, HU Xiangning, TANG Feiyu, et al.Flame-retardant poly(lactic acid):An overview and outlook[J].Chemical Industry and Engineering Progress,2020,39(9):3421-3432.
7 陈志,杜建新,李向梅,等.红磷阻燃剂的进展及市场概况[J].石化技术,2019,26(1):6-7,29.
7 CHEN Zhi, DU Jianxin, LI Xiangmei, et al.Review and market profile on red phosphorus flame retardant[J].Petrochemical Industry Technology,2019,26(1):6-7,29.
8 QU Guangbo, XIA Tian, ZHOU Wenhua, et al.Property-activity relationship of black phosphorus at the nano-bio interface:From mo- lecules to organisms[J].Chemical Reviews,2020,120(4):2288-2346.
9 REN Xinlin, MEI Yi, LIAN Peichao, et al.A novel application of phosphorene as a flame retardant[J].Polymers,2018,10(3).Doi:10.3390/polym10030227.
10 任新林.黑磷烯基复合材料的制备及阻燃性能研究[D].昆明:昆明理工大学,2019.
10 REN Xinlin.Preparation and flame-retardant properties of black phosphorene-based composites.Kunming:Kunming University of Science and Technology,2019.
11 任细运.阻燃环氧树脂的燃烧特性及其潜在火灾危险性评价的研究[D].合肥:中国科学技术大学,2021.
11 REN Xiyun.Study on combustion behaviors and potential fire hazards assessment of flame retardant epoxy resins[D].Hefei:University of Science and Technology of China,2021.
12 SALMEIA K A, GAAN S, MALUCELLI G.Recent advances for flame retardancy of textiles based on phosphorus chemistry[J].Polymers,2016,8(9).Doi:10.3390/polym8090319.
13 QIU Shuilai.Functionalized two-dimensional black phosphorus and polymer nanocomposites as flame retardant[M].Singapore:Springer Singapore,2021.
14 GREEN J.Mechanisms for flame retardancy and smoke suppressi- on-A review[J].Journal of Fire Sciences,1996,14(6):426-442.
15 李策.黑磷(烯)聚合物复合材料制备及性能研究[D].北京:北京化工大学,2020.
15 LI Ce.Preparation andproperties of blakephosphorene polymer composites[D].Beijing:Beijing University of Chemical Technology,2020.
16 SCHARTEL B.Phosphorus-based flame retardancy mechanisms-old hat or a starting point for future development?[J].Materials,2010,3(10):4710-4745.
17 SALMEIA K, FAGE J, LIANG Shuyu, et al.An overview of mode of action and analytical methods for evaluation of gas phase activities of flame retardants[J].Polymers,2015,7(3):504-526.
18 SCHARTEL B, PERRET B, DITTRICH B, et al.Flame retardancyof polymers:The role of specific reactions in the condensed pha-se[J].Macromolecular Materials and Engineering,2016,301(1):9-35.
19 VAHABI H, LAOUTID F, MEHRPOUYA M, et al.Flame retardant polymer materials:An update and the future for 3D printing developments[J].Materials Science and Engineering:R:Repor- ts,2021,144.Doi:10.1016/j.mser.2020.100604.
20 MOURITZ A P, GIBSON A G.Fire properties of polymer composite materials[M].Dordrecht:Springer Netherlands,2006.
21 邱水来.功能化二维黑磷/聚合物纳米复合材料的阻燃性能研究[D].合肥:中国科学技术大学,2019.
21 QIU Shuilai.Study on flame retardant properties of functionalized two-dimensional black phosphorus/polymer nanocomposites[D].Hefei:University of Science and Technology of China,2019.
22 何灵欣.水性聚氨酯/二维黑磷复合材料设计及其阻燃和电磁屏蔽性能研究[D].合肥:中国科学技术大学,2021.
22 HE Lingxin.Fabrication of waterborne polyurethane/black phosphorus nanocomposites:Investigation on flame retardancy and electromagnetic interfere shielding performance[D].Hefei:University of Science and Technology of China,2021.
23 LIU Quanyi, WANG Donghui, LI Zekun, et al.Recent developments in the flame-retardant system of epoxy resin[J].Materials,2020,13(9).Doi:10.3390/ma13092145.
24 GIBERTINI E, CAROSIO F, AYKANAT K, et al.Silica-encapsulated red phosphorus for flame retardant treatment on textile[J].Surfaces and Interfaces,2021,25.Doi:10.1016/j.surfin.2021.101252.
25 SAVAS L A, DENIZ T K, TAYFUN U, et al.Effect of microcapsulated red phosphorus on flame retardant,thermal and mechanical properties of thermoplastic polyurethane composites filled with huntite&hydromagnesite mineral[J].Polymer Degradation and Stability,2017,135: 121-129.
26 KARAER ?ZMEN F, üREYEN M E, KOPARAL A S.Cleaner production of flame-retardant-glass reinforced epoxy resin composite for aviation and reducing smoke toxicity[J].Journal of Cle- Production aner,2020,276.Doi:10.1016/j.jclepro.2020.124065.
27 ZHAO Bin, HU Zhi, CHEN Li, et al.A phosphorus-containing inorganic compound as an effective flame retardant for glass-fiber-reinforced polyamide 6[J].Journal of Applied Polymer Science,2011,119(4):2379-2385.
28 ZHANG Ye, MA Chunyang, XIE Jianlei, et al.Black phosphorus/polymers:Status and challenges[J].Advanced Materials,2021,33(37).Doi:10.1002/adma.202100113.
29 CHENG Chen, LU Yanling, MA Weining, et al.Preparation and characterization of polydopamine/melamine microencapsulated red phosphorus and its flame retardance in epoxy resin[J].RSC Advances,2021,11(33):20391-20402.
30 TRAN V, SOKLASKI R, LIANG Yufeng, et al.Layer-controlled band gap and anisotropic excitons in few-layer black phosphor-us[J].Physical Review B,2014,89(23).Doi:10.1103/physrevb.89.235319.
31 LI Likai, YU Yijun, YE Guojun, et al.Black phosphorus field-effect transistors[J].Nature Nanotechnology,2014,9(5):372-377.
32 WU Peng, AMEEN T, ZHANG Huairuo, et al.Complementary black phosphorus tunneling field-effect transistors[J].ACS Nano,2019,13(1):377-385.
33 WANG Xin, BAI Licheng, LU Jiang, et al.Rapid activation of pla- tinum with black phosphorus for efficient hydrogen evolution[J].Angewandte Chemie International Edition,2019,58(52):19060-19066.
34 WANG Jiahong, LIU Danni, HUANG Hao, et al.In-plane black phosphorus/dicobalt phosphide heterostructure for efficient electrocatalysis[J].Angewandte Chemie International Edition,2018,57(10):2600-2604.
35 BAI Licheng, WANG Xin, TANG Shaobin, et al.Black phosphorus/platinum heterostructure:A highly efficient photocatalyst for solar-driven chemical reactions[J].Advanced Materials,2018,30(40).Doi:10.1002/adma.201803641.
36 TIAN Bin, TIAN Bining, SMITH B, et al.Facile bottom-up synthesis of partially oxidized black phosphorus nanosheets as metal-free photocatalyst for hydrogen evolution[J].Proceedings of the National Academy of Sciences of the United States of America,2018,115(17):4345-4350.
37 SHAO Ximing, DING Zhihao, ZHOU Wenhua, et al.Intrinsic bioactivity of black phosphorus nanomaterials on mitotic centrosome destabilization through suppression of PLK1 kinase[J].Nature Nanotechnology,2021,16(10):1150-1160.
38 BRIDGMAN P W.Two new modifications of phosphorus[J].Journal of the American Chemical Society,1914,36(7):1344-1363.
39 NAGAO M, HAYASHI A, TATSUMISAGO M.All-solid-state lithium secondary batteries with high capacity using black phosphorus negative electrode[J].Journal of Power Sources,2011,196(16):6902-6905.
40 LANGE S, SCHMIDT P, NILGES T.Au3SnP7@Black phosphorus:An easy access to black phosphorus[J].ChemInform,2007,38(30).Doi:10.1002/chin.200730015.
41 ZHOU Yifan, HUANG Jiali, WANG Junling, et al.Rationally designed functionalized black phosphorus nanosheets as new fire hazard suppression material for polylactic acid[J].Polymer Degradation and Stability,2020,178.Doi:10.1016/j.polymdegradstab.2020.109194.
42 林绍铃,黄初,赵小敏,等.石墨烯/黑磷纳米复合粒子对环氧树脂阻燃与热稳定性能的影响[J].材料导报,2021,35(10):10184-10188.
42 LIN Shaoling, HUANG Chu, ZHAO Xiaomin, et al.Effects of graphene/black phosphorus nanocomposites on flame retardancy and thermal stability of epoxy resin[J].Materials Reports,2021,35(10):10184-10188.
43 QIU Shuilai, ZOU Bin, ZHANG Tao, et al.Integrated effect of NH2-functionalized/triazine based covalent organic framework black phosphorus on reducing fire hazards of epoxy nanocomposites[J].Chemical Engineering Journal,2020,401.Doi:10.1016/j.cej.2020.126058.
44 QIU Shuilai, ZOU Bin, SHENG Haibo, et al.Electrochemically exfoliated functionalized black phosphorene and its polyurethane acrylate nanocomposites:Synthesis and applications[J].ACS Applied Materials & Interfaces,2019,11(14):13652-13664.
45 LI Xuesong, DENG Bingchen, WANG Xiaomu, et al.Synthesis of thin-film black phosphorus on a flexible substrate[J].2D Materials,2015,2(3).Doi:10.1088/2053-1583/2/3/031002.
46 BRENT J R, SAVJANI N, LEWIS E A, et al.Production of few-layer phosphorene by liquid exfoliation of black phosphorus[J].Chemical Communications,2014,50(87):13338-13341.
47 GUO Zhinan, ZHANG Han, LU Shunbin, et al.From black phosphorus to phosphorene:Basic solvent exfoliation,evolution of Raman scattering,and applications to ultrafast photonics[J].Advanced Functional Materials,2015,25(45):6996-7002.
48 FAVRON A, GAUFRèS E, FOSSARD F, et al.Photooxidation and quantum confinement effects in exfoliated black phosphorus[J].Nature Materials,2015,14(8):826-832.
49 REN Xinlin, MEI Yi, LIAN Peichao, et al.Fabrication and application of black phosphorene/graphene composite material as a flame retardant[J].Polymers,2019,11(2).Doi:10.3390/polyml1020193
50 QIU Shuilai, ZHOU Yifan, ZHOU Xia, et al.Air-stable polyphosphazene-functionalized few-layer black phosphorene for flame retardancy of epoxy resins[J].Small,2019,15(10).Doi:10.1002/smll.201805175.
51 QU Zhencai, WANG Kunxin, XU Changan, et al.Simultaneous enhancement in thermal conductivity and flame retardancy of flexible film by introducing covalent bond connection[J].Chemical Engineering Journal,2021,421.Doi:10.1016/j.cej.2022.129729.
52 QU Zhencai, WU Kun, JIAO Enxiang, et al.Surface functionalization of few-layer black phosphorene and its flame retardancy in epoxy resin[J].Chemical Engineering Journal,2020,382.Doi:10.1016/j.cej.2019.122991.
53 CAI Wei, HU Yixin, PAN Ying, et al.Self-assembly followed by radical polymerization of ionic liquid for interfacial engineering of black phosphorus nanosheets:Enhancing flame retardancy,toxic gas suppression and mechanical performance of polyurethane[J].Journal of Colloid and Interface Science,2020,561: 32-45.
54 ZHOU Yifan, CHU Fukai, QIU Shuilai, et al.Construction of graphite oxide modified black phosphorus through covalent linkage:An efficient strategy for smoke toxicity and fire hazard suppression of epoxy resin[J].Journal of Hazardous Materials,2020,399.Doi:10.1016/j.jhazmat.2020.123015.
55 QU Zhencai, XU Changan, LI Xiaobin, et al.Facile preparation of BP-MoS2/GO composite films with excellent flame retardancy and ultrasensitive response for smart fire alarm[J].Chemical Engineering Journal,2021,426.Doi:10.1016/j.cej.2021.130717.
56 REN Xiyun, ZOU Bin, ZHOU Yifan, et al.Construction of few-layered black phosphorus/graphite-like carbon nitride binary hybrid nanostructure for reducing the fire hazards of epoxy resin[J].Journal of Colloid and Interface Science,2021,586: 692-707.
57 YIN Sihao, REN Xinlin, LIAN Peichao, et al.Synergistic effects of black phosphorus/boron nitride nanosheets on enhancing the flame-retardant properties of waterborne polyurethane and its flame-retardant mechanism[J].Polymers,2020,12(7).Doi:10.3390/polym1207148.
58 李永翔,尹思浩,谢于辉,等.纳米黑磷阻燃聚丙烯及对力学性能的影响[J].复合材料学报,2022,39(7):3178-3190.
58 LI Yongxiang, YIN Sihao, XIE Yuhui, et al.Effect of black phosphorous nanosheet on the flame retardance and mechanical property of polypropylene[J].Acta Materiae Compositae Sinica,2022,39(7):3178-3190.
59 CAI Wei, CAI Tongmin, HE Lingxin, et al.Natural antioxidant functionalization for fabricating ambient-stable black phosphorus nanosheets toward enhancing flame retardancy and toxic gases suppression of polyurethane[J].Journal of Hazardous Materials,2020,387.Doi:10.1016/j.jhazmat.2019.121971.
60 QIU Shuilai, LIANG Jing, HOU Yanbei, et al.Hindered phenolic antioxidant passivation of black phosphorus affords air stability and free radical quenching[J].Journal of Colloid and Interface Science,2022,606: 1395-1409.
61 QIU Shuilai, ZHOU Yifan, XING Weiyi, et al.Conceptually novel few-layer black phosphorus/supramolecular coalition:Noncovalent functionalization toward fire safety enhancement[J].Industrial & Engineering Chemistry Research,2021,60(34):12579-12591.
62 HE Lingxin, ZHOU Xia, CAI Wei, et al.Electrochemical exfoliation and functionalization of black phosphorene to enhance mechanical properties and flame retardancy of waterborne polyurethane[J].Composites Part B:Engineering,2020,202.Doi:10.1016/j.compositesb.2020.108446.
63 QIU Shuilai, HOU Yanbei, ZHOU Xia, et al.Light stabilizer and diazo passivation of black phosphorus nanosheets:Covalent functionalization endows air stability and flame retadancy enhancements[J].Chemical Engineering Journal,2021,425.Doi:10.1016/j.cej.2021.131532.
64 QU Zhencai, WU Kun, MENG Weihua, et al.Surface coordination of black phosphorene for excellent stability,flame retardancy and thermal conductivity in epoxy resin[J].Chemical Engineering Journal,2020,397.Doi:10.1016/j.cej.2020.125416.
65 QIU Shuilai, ZHOU Yifan, REN Xiyun, et al.Construction of hierarchical functionalized black phosphorus with polydopamine:A novel strategy for enhancing flame retardancy and mechanical properties of polyvinyl alcohol[J].Chemical Engineering Journal,2020,402.Doi:10.1016/j.cej.2020.126212.
66 蔡炜.聚氨酯/黑磷纳米复合材料设计及其阻燃和光热蒸汽转化性能研究[D].合肥:中国科学技术大学,2020.
66 CAI Wei.Fabrication of polyurethane/black phosphorous nanocomposites:Investigation on flame retardancy and solar steam co-nversion[D].Hefei:University of Science and Technology of China,2020.
67 DUAN Zunbin, WANG Yanfang, BIAN Shi, et al.Size-dependent flame retardancy of black phosphorus nanosheets[J].Nanoscale,2022,14(7):2599-2604.
68 ZOU Bin, QIU Shuilai, REN Xiyun, et al.Combination of black phosphorus nanosheets and MCNTs via phosphoruscarbon bonds for reducing the flammability of air stable epoxy resin nanocomposites[J].Journal of Hazardous Materials,2020,383.Doi:10.1016/j.jhazmat.2019.
69 DU Xiaosheng, QIU Jinghong, DENG Sha, et al.Flame-retardant and form-stable phase change composites based on black phosphorus nanosheets/cellulose nanofiber aerogels with extremely high energy storage density and superior solar-thermal conversion efficiency[J].Journal of Materials Chemistry A,2020,8(28):14126-14134.
70 DU Xiaosheng, QIU Jinghong, DENG Sha, et al.Flame-retardant and solid-solid phase change composites based on dopamine-decorated BP nanosheets/Polyurethane for efficient solar-to-thermal energy storage[J].Renewable Energy,2021,164: 1-10.
71 XIAO Yifan, LI Jiaxuan, WU Jun, et al.Glass fiber reinforced PET modified by few-layer black phosphorus[J].Polymers for Advanced Technologies,2021,32(9):3515-3522.
72 WANG Yan, SHI Zixing, FANG Jianhua, et al.Graphene oxide/polybenzimidazole composites fabricated by a solvent-exchange method[J].Carbon,2011,49(4):1199-1207.
73 宁廷州,付玲,张敬芝.电器封装用高效导热/阻燃环氧复合材料的制备[J].包装工程,2020,41(3):156-163.
73 NING Tingzhou, FU Ling, ZHANG Jingzhi.Preparation of epoxy composites with highly efficient thermal conductivity/flame retardancy for electrical packaging[J].Packaging Engineering,2020,41(3):156-163.
74 CAI Wei, MU Xiaowei, PAN Ying, et al.Black phosphorous nanosheets:A novel solar vapor generator[J].Solar RRL,2020,4(4).Doi:10.1002/solr.201900537.
75 YUE Xiaopeng, LI Chaofan, NI Yonghao, et al.Flame retardant nanocomposites based on 2D layered nanomaterials:A review[J].Journal of Materials Science,2019,54(20):13070-13105.
76 HE Wentao, SONG Pingan, YU Bin, et al.Flame retardant polymeric nanocomposites through the combination of nanomaterials and conventional flame retardants[J].Progress in Materials Science,2020,114.Doi:10.1016/j.pmatsci.2020.100687.
77 尹思浩,任新林,廉培超,等.黑磷制备及其在阻燃领域的应用研究进展[J].磷肥与复肥,2019,34(9):48-52.
77 YIN Sihao, REN Xinlin, LIAN Peichao, et al.Research progress on preparation and flame retardant application of black phosphorus[J].Phosphate & Compound Fertilizer,2019,34(9):48-52.
78 SAATY R W.The analytic hierarchy process-What it is and how it is used[J].Mathematical Modelling,1987,9(3/4/5):161-176.
文章导航

/