无机盐工业
主管:中海油天津化工研究设计院有限公司
主办:中海油天津化工研究设计院有限公司
   中海油炼油化工科学研究院(北京)有限公司
   中国化工学会无机酸碱盐专业委员会
ISSN 1006-4990 CN 12-1069/TQ
研究与开发

鸭湖构造深部卤水自然蒸发实验研究

  • 武丽平 ,
  • 袁红战 ,
  • 靳芳
展开
  • 1.青海省柴达木盆地盐湖资源勘探研究重点实验室,青海格尔木 816099
    2.青海省柴达木综合地质矿产勘查院
武丽平(1987— ),女,工程师,研究方向为盐湖工艺和盐湖资源勘查;E-mail:419274576@qq.com。

收稿日期: 2022-07-12

  网络出版日期: 2022-11-23

基金资助

青海省地质矿产勘查开发局2020年度局计划大地质类项目(青地矿科[2020]25号)

Study on natural evaporation experimental of deep brine in Yahu structure

  • Liping WU ,
  • Hongzhan YUAN ,
  • Fang JIN
Expand
  • 1. Qinghai Provincial Key Laboratory of Salt Lake Resources Exploration and Research in Qaidam Basin,Golmud 816099,China
    2. Qinghai Qaidam comprehensive geological and Mineral Exploration Institute

Received date: 2022-07-12

  Online published: 2022-11-23

摘要

通过自然蒸发实验,对鸭湖背斜构造深部卤水进行了研究,得到了该卤水在自然蒸发过程中各元素富集规律及析盐规律。受高含量钙影响,卤水蒸发路线在K+,Na+,Mg2+//Cl--H2O(25 ℃)介稳相图中偏移比较明显,可与Na+,K+,Mg2+,Ca2+//Cl--H2O(25 ℃,对NaCl饱和)介稳相图相结合对实验数据进行分析。卤水自然蒸发过程中矿物析出顺序为:石膏→石盐→光卤石→南极石→溢晶石;光卤石产量较小并且质量不高;锂最终浓缩至质量浓度约为2.9 g/L时,硼、锶、溴、碘、铷、铯等微量元素均有析出。实验数据和结论为针对该类型卤水进行更深入的综合开发利用研究提供了依据,如前期除钙后梯度提取硼酸、碳酸锂、溴素等产品。

本文引用格式

武丽平 , 袁红战 , 靳芳 . 鸭湖构造深部卤水自然蒸发实验研究[J]. 无机盐工业, 2022 , 54(11) : 71 -78 . DOI: 10.19964/j.issn.1006-4990.2022-0348

Abstract

Through the natural evaporation test,the deep brine of Yahu anticline structure was studied,and the enrichment law and salt evolution law of each element in the natural evaporation process of the brine were obtained.Affected by the high content of calcium,the brine evaporation route was shifted significantly in the K+,Na+,Mg2+//Cl--H2O(25 ℃) metastable phase diagram,which could be combined with the Na+,K+,Mg2+,Ca2+//Cl--H2O(25 ℃,Saturated with NaCl) metastable phase diagram to analyze the experimental data.The sequence of mineral precipitation during natural evaporation of brine was gypsum→halite→carnallite→Antarcticite→tachydrite.Carnallite production was small and its quality was not high.Li was concentrated to about 2.9 g/L,and trace elements such as B,Sr,Br,I,Rb and Cs were separated out.The experimental data and conclusions provided a basis for further comprehensive development and utilization of this type of brine,such as the gradient extraction of boric acid,lithium carbonate,bromine and other products after early calcium removal.

参考文献

1 邓天龙,王士强,郭亚飞.柴达木盆地盐湖卤水体系介稳相平衡与相图[M].北京:科学出版社,2017.
1 DENG Tianlong, WANG Shiqiang, GUO Yafei.Metastable phase equilibrium and phase diagram of salt lake brine system in Qaidam Basin[M].Beijing:Science Press,2017.
2 郑绵平,邓天龙,阿哈龙·奥伦.盐湖科学概论[M].北京:科学出版社,2018.
2 ZHENG Mianping, DENG Tianlong, Oren A.Introduction to salt lake science[M].Beijing:Science Press,2018.
3 穆延宗,乜贞,卜令忠,等.我国油(气)田水钾资源研究进展[J].地球科学进展,2016,31(2):147-160.
3 MU Yanzong, NIE Zhen, BU Lingzhong, et al.Progress in study of potash resources of oil(gas) field brine in China[J].Advances in Earth Science,2016,31(2):147-160.
4 中华人民共和国自然资源部. DZ/T 0212.1—2020 矿产地质勘查规范盐类 [S].北京:中国标准出版社,2020.
4 Ministry of natural resources of the People's Republic of China. DZ/T 0212.1—2020 Code for mineral geological exploration salt [S].Beijing:China Standards Press,2020.
5 刘颖,王云生,乜贞,等.柴西深层地下卤水资源及其综合利用研究进展[J].无机盐工业,2018,50(1):12-15,27.
5 LIU Ying, WANG Yunsheng, NIE Zhen, et al.Research progress on comprehensive utilization of deep underground brine resources in western Qaidam Basin[J].Inorganic Chemicals Industry,2018,50(1):12-15,27.
6 赵为永,魏学斌,雷涛,等.青海省南翼山构造深层卤水矿床特征及分布规律研究[J].能源与环保,2021,43(5):39-45.
6 ZHAO Weiyong, WEI Xuebin, LEI Tao, et al.Study on deposit characteristics and distribution of deep brine in Nanyishan,Qinghai Province[J].China Energy and Environmental Protection,2021,43(5):39-45.
7 李洪普,侯献华,郑绵平,等.柴达木盆地西部更新统砂砾型深层卤水钾矿成矿模式与找矿方向探讨[J].湖泊科学,2022,34(3):1043-1054.
7 LI Hongpu, HOU Xianhua, ZHENG Mianping, et al.Discussion on metallogenic model and prospecting direction of Pleistocene gravel brine Potassium deposit in western Qaidam Basin[J].Journal of Lake Sciences,2022,34(3):1043-1054.
8 刘溪溪,岳鑫,袁文虎,等.柴达木盆地西部狮子沟背斜构造区深部卤水水化学特征及演化分析[J].盐湖研究,2019,27(1):73-81.
8 LIU Xixi, YUE Xin, YUAN Wenhu, et al.Hydrochemical characteristics and evolutionary process of deep brines from shizigou anticline structure in Qaidam Basin,China[J].Journal of Salt Lake Research,2019,27(1):73-81.
9 韩光,樊启顺,刘久波,等.柴达木盆地中西部背斜构造深层卤水水化学特征与成因[J].盐湖研究,2021,29(4):1-11.
9 HAN Guang, FAN Qishun, LIU Jiubo, et al.Origin and hydrochemistry of deep brines from anticlinal reservoir in the western-central Qaidam Basin[J].Journal of Salt Lake Research,2021,29(4):1-11.
10 侯献华,冯磊,郑绵平,等.南翼山富钾锂卤水储层识别方法[J].地球科学,2022,47(1):45-55.
10 HOU Xianhua, FENG Lei, ZHENG Mianping, et al.Recognition method of potassium-rich lithium brine reservoir in Nanyishan[J].Earth Science,2022,47(1):45-55.
11 徐凯,许建新,常政,等.柴达木盆地南翼山油田卤水水化学及氢氧同位素地球化学特征[J].盐湖研究,2021,29(4):43-51.
11 XU Kai, XU Jianxin, CHANG Zheng, et al.Hydrochemical,hydrogen and oxygen isotopic characteristics of nanyishan oilfield brine,Qaidam Basin[J].Journal of Salt Lake Research,2021,29(4):43-51.
12 郭璞,潘洪峰,侯安平,等.南翼山构造主要地质特征及油气成藏模式[J].青海石油,2010,28(2):7-14.
12 GUO Pu, PAN Hongfeng, HOU Anping, et al.Main geological characteristics and hydrocarbon accumulation model of Nanyishan structure[J].Qinghai Petroleum,2010,28(2):7-14.
13 靳芳,李洪普,常东海.柴达木盆地南翼山背斜构造区卤水自然蒸发实验[J].无机盐工业,2021,53(11):86-90.
13 JIN Fang, LI Hongpu, CHANG Donghai.Experiment on natural evaporation of brine in Nanyishan anticline structural area of Qaidam Basin[J].Inorganic Chemicals Industry,2021,53(11):86-90.
14 靳芳,李洪普,武丽平,等.柴达木盆地深层卤水自然蒸发试验[J].化工矿物与加工,2022,51(5):54-58.
14 JIN Fang, LI Hongpu, WU Liping, et al.The natural evaporation experiments with deep brines from Qaidam Basin[J].Industrial Minerals & Processing,2022,51(5):54-58.
15 唐发满,杨红军,张生鹏,等.一里坪盐湖夏季卤水25 ℃等温蒸发[J].无机盐工业,2021,53(10):52-58.
15 TANG Faman, YANG Hongjun, ZHANG Shengpeng, et al.Isothermal evaporation of summer brine of Yiliping salt lake at 25 ℃[J].Inorganic Chemicals Industry,2021,53(10):52-58.
16 乔东慧.柴达木盆地东台吉乃尔盐湖卤水蒸发实验研究[D].成都:成都理工大学,2012.
16 QIAO Donghui.Evaporation studies for the salt lake brine in the dongtaijinaier salt lake,Qaidam Basin[D].Chengdu:Chengdu University of Technology,2012.
17 彭玲玲,魏学斌,赵为永,等.黑北凹地富钾地下卤水自然蒸发实验研究[J].无机盐工业,2019,51(6):11-16.
17 PENG Lingling, WEI Xuebin, ZHAO Weiyong, et al.Study on natural evaporation of underground potassium-rich brine in Heibei concave[J].Inorganic Chemicals Industry,2019,51(6):11-16.
18 T/QAS 025—2021 卤水-pH的测定-玻璃电极法[S].青海:青海省标准化协会,2021.
19 邓天龙,周桓,陈侠.水盐体系相图及应用[M].北京:化学工业出版社,2020.
19 DENG Tianlong, ZHOU Huan, CHEN Xia.Salt-water system phase diagrams and applications[M].BeiJing:Chemical Industry Press,2020.
20 本山正夫,门田稔,冈俊平.NaCl-KCl-MgCl2-CaCl2-H2O体系的25 ℃相平衡[J].日本海水学会会刊,1972,26(4):173-180 .
21 程怀德,李俊,海擎宇.白垩纪海水Ca异常与溢晶石形成的关系[J].化工矿产地质,2018,40(3):129-140.
21 CHENG Huaide, LI Jun, Qingyu HAI.Relationship between Cretaceous seawater Ca anomaly and tachyhydrite formation[J].Geology of Chemical Minerals,2018,40(3):129-140.
22 程怀德,马海州,山发寿,等.基于相化学研究老挝万象钾镁盐矿床形成的机制[J].地球学报,2010,31(2):194-202.
22 CHENG Huaide, MA Haizhou, SHAN Fashou, et al.A study of the formation mechanism of the Vientiane potash deposit based on phase chemistry[J].Acta Geoscientica Sinica,2010,31(2):194-202.
文章导航

/