钢渣改性用于烟气脱硫研究进展
收稿日期: 2021-12-27
网络出版日期: 2022-11-23
基金资助
安徽省重点研究与开发计划项目(202104g01020006);安徽省博士后研究人员科研活动经费资助项目(2019B336);冶金工程与资源综合利用安徽省重点实验室（安徽工业大学）(SKF21-03);马鞍山市博士后研究人员科研活动经费资助项目(2020A11)
Research progress on flue gas desulfurization by modification of steel slag
Received date: 2021-12-27
Online published: 2022-11-23
钢渣结构上疏松多孔、组分上富含氧化钙、氧化镁等碱性氧化物，因此其在溶液中碱性较高，酸中和能力强，能有效去除烟气中二氧化硫实现有效脱硫。目前钢渣主要用于湿法脱硫工艺，基本机理是气液两相间的传质过程，包括二氧化硫由气相进入液相、液相中钢渣碱性物质溶解析出、进入液相的二氧化硫与钢渣中碱性物质发生化学反应3个过程，但脱硫效果主要受前两个过程影响，主要影响因素包括入口二氧化硫质量浓度、液气比、浆液pH、反应温度、钢渣粒径等。但目前对钢渣中除氧化钙、氧化镁外其他组分对脱硫效果的影响机理研究还不够深入。因此，下一步要积极探索钢渣中不同化学组分在烟气脱硫过程中的协同作用和机理，完善钢渣用于烟气脱硫的理论基础，进而实现钢渣脱硫的工业化应用。
杜晓燕 , 龙红明 , 刘秀玉 , 朱庆明 , 韩伟胜 . 钢渣改性用于烟气脱硫研究进展[J]. 无机盐工业, 2022 , 54(11) : 39 -44 . DOI: 10.19964/j.issn.1006-4990.2021-0778
Steel slag has the structural characteristics of loose and porous，and rich in alkaline oxides such as CaO and MgO，so it is highly alkaline in the solution and has strong acid neutralization ability，which can effectively remove sulfur dioxide from flue gas and realize effective desulfurization.At present，steel slag-based desulfurization absorption materials are mainly used in wet desulfurization processes.The basic mechanism is the mass transfer between the gas phase and the liquid phase，which contains three steps：1）SO2 enters the liquid phase from the gas phase；2）the alkaline substance is dissolved out of steel slag，and 3）chemical reaction occurs between SO2 and alkaline substances in the liquid phase.However，the overall desulfurization efficiency is mainly affected by the first two steps.The main factors include inlet SO2 mass concentration，liquid-gas ratio，slurry pH，reaction temperature，steel slag particle size and so on.However，at present，the research on the influence mechanism of other components in steel slag except CaO and MgO on the desulfurization effect is not enough.Therefore，it is necessary to actively explore the synergistic mechanism of different chemical components in steel slag in the desulfurization absorption process，consolidate the theoretical basis of steel slag for flue gas desulfurization and then realize the industrial application of steel slag desulfurization.
Key words： steel slag; modification; gasdesulfurization; mechanism
| 1 | 杨丽韫,陈军,袁鹏,等.钢渣去除废水中重金属离子的研究综述[J].钢铁,2017,52(8):1-9. |
| 1 | YANG Liyun, CHEN Jun, YUAN Peng, et al.Research review of heavy metal ions removal from waste water by steelmaking slag[J].Iron ＆ Steel,2017,52(8):1-9. |
| 2 | 张顺雨.钢渣成分在烟气脱硫过程中的协同作用与机理[D].唐山：华北理工大学，2017. |
| 2 | ZHANG Shunyu.Synergistic effect and mechanism of steel slag composition in flue gas desulfurization[D].Tangshan：North China University of Science and Technology，2017. |
| 3 | 魏建鹏.石灰石-石膏湿法脱硫系统节能降耗策略研究[C]//中国环境科学学会2021年科学技术年会——环境工程技术创新与应用分会场.天津：《环境工程》编辑部，2021. |
| 4 | 苏少龙,曲晓龙,钟读乐,等.工业烟气脱硫工艺进展[J].无机盐工业,2019,51(11):13-15，87. |
| 4 | SU Shaolong, QU Xiaolong, ZHONG Dule, et al.Progress of industrial flue gas desulfurization process[J].Inorganic Chemicals Industry,2019,51(11):13-15，87. |
| 5 | 龙勇.高硫煤烟气氨法脱硫装置升级改造[J].氮肥与合成气,2021,49(11):14-16. |
| 5 | LONG Yong.Upgrading of high-sulfur coal flue gas ammonia desulfurization unit[J].Nitrogenous Fertilizer ＆ Syngas,2021,49(11):14-16. |
| 6 | 樊河雲,李瑛,赖立践,等.钢渣/碱式碳酸镁新型复合脱硫剂的性能研究[J].工业加热,2017,46(4):47-51. |
| 6 | FAN Heyun, LI Ying, LAI Lijian, et al.The desulfurization performance research of new-type composite desulphurizer of basic magnesium carbonate desulfurization agent with steel slag[J].Industrial Heating,2017,46(4):47-51. |
| 7 | 张顺雨,贵永亮,宋春燕,等.钢渣烧结烟气脱硫现状[J].矿产综合利用,2018(1):1-5. |
| 7 | ZHANG Shunyu, GUI Yongliang, SONG Chunyan, et al.Present situation of sintering flue gas desulfurization with steel slag[J].Multipurpose Utilization of Mineral Resources,2018(1):1-5. |
| 8 | 张国成,白晓光,邬虎林,等.钢渣脱硫剂用于湿法石灰石-石膏法脱硫工艺的试验研究[J].钢铁研究学报,2020,32(7):647-653. |
| 8 | ZHANG Guocheng, BAI Xiaoguang, WU Hulin, et al.Experimental study on desulfurization process of wet limestone-gypsum with steel slag desulfurizer[J].Journal of Iron and Steel Research,2020,32(7):647-653. |
| 9 | 王高峰,王义忠,於珩,等.转炉钢渣用于烟气脱硫实践研究[C]//陕西省金属学会.第五届全国冶金渣固废回收及资源综合利用、节能减排高峰论坛.昆明：2020. |
| 10 | 王会刚,彭犇,岳昌盛,等.钢渣改性研究进展及展望[J].环境工程,2020,38(5):133-137，106. |
| 10 | WANG Huigang, PENG Ben, YUE Changsheng, et al.Research progress and prospect of steel slag modification[J].Environmental Engineering,2020,38(5):133-137，106. |
| 11 | 丁希楼,郭应春,唐胜卫,等.废钢渣粉渣湿法脱硫工艺实验研究[J].环境工程,2009,27(3):99-102. |
| 11 | DING Xilou, GUO Yingchun, TANG Shengwei, et al.Experimental study on wet flue gas desulfurization with scrap slag powder residue[J].Environmental Engineering,2009,27(3):99-102. |
| 12 | 孟子衡,王晨晔,王兴瑞,等.焦炉烟气钢渣湿法联合脱硫脱硝试验研究[J].洁净煤技术,2020,26(6):210-216. |
| 12 | MENG Ziheng, WANG Chenye, WANG Xingrui, et al.Experimental study on simultaneous desulfurization and denitrification by steelmaking slag for coke oven flue gas[J].Clean Coal Technology,2020,26(6):210-216. |
| 13 | 徐露,范鼎东,夏能伟,等.钢渣微粉用于烧结烟气干法脱硫的试验研究[J].烧结球团,2015,40(3):48-52. |
| 13 | XU Lu, FAN Dingdong, XIA Nengwei, et al.Experimental study on dry sintering flue gas desulfurization with steel slag powder[J].Sintering and Pelletizing,2015,40(3):48-52. |
| 14 | 邱伟,刘盛余,能子礼超,等.氢氧化钠-钢渣双碱法烧结烟气脱硫工艺[J].环境工程学报,2013,7(3):1095-1100. |
| 14 | QIU Wei, LIU Shengyu, NENG Zilichao, et al.Study of NaOH-steel slag double alkali sintering flue gas desulphurization process[J].Chinese Journal of Environmental Engineering,2013,7(3):1095-1100. |
| 15 | 刘盛余,邱伟,汪雪婷,等.柠檬酸强化钢渣湿法烧结烟气脱硫及机理[J].环境工程学报,2015,9(3):1323-1328. |
| 15 | LIU Shengyu, QIU Wei, WANG Xueting, et al.Mechanism and process of steel slag agglomeration gas desulfurization enhanced by citric acid[J].Chinese Journal of Environmental Engineering,2015,9(3):1323-1328. |
| 16 | 孟子衡.低温烟气钢渣联合脱硫脱硝过程强化工艺与机理研究[D].北京：中国科学院大学（中国科学院过程工程研究所），2020. |
| 16 | MENG Ziheng.Intensification technology and mechanism for simultaneous desulphurization and denitration from low-temperature flue gas by steel slag[D].Beijing：Institute of Process Engineering，Chinese Academy of Sciences，2020. |
| 17 | 杨小白,韩云龙,李迎根,等.活性炭混合钢渣烧结烟气脱硫脱硝实验研究[J].过程工程学报,2019,19(2):440-446. |
| 17 | YANG Xiaobai, HAN Yunlong, LI Yinggen, et al.Experimental study on desulfurization and denitration of sintering flue gas by activated carbon mixed with steel slag[J].The Chinese Journal of Process Engineering,2019,19(2):440-446. |
| 18 | 王彦斐.添加钢渣的水菱镁复合脱硫剂脱硫性能及实验研究[D].昆明：昆明理工大学，2019. |
| 18 | WANG Yanfei.Desulfurization performance and experimental study of hydromagnesite composite desulfurizer added with steel slag[D].Kunming：Kunming University of Science and Technology，2019. |
| 19 | 陈捷.Na2CO3（CaCO3）/铁渣复合脱硫剂脱硫性能的研究[D].昆明：昆明理工大学，2016. |
| 19 | CHEN Jie.Study on desulfurization performance of Na2CO3（CaCO3）/iron slag composite desulfurizer[D].Kunming：Kunming University of Science and Technology，2016. |
| 20 | 刘盛余,邱伟,吴萧,等.鼓泡塔中钢渣湿法烧结烟气脱硫过程及机理[J].应用基础与工程科学学报,2017,25(1):46-55. |
| 20 | LIU Shengyu, QIU Wei, WU Xiao, et al.Mechanism and process of sintering flue gas desulfurization by steel slag in bubbling tower[J].Journal of Basic Science and Engineering,2017,25(1):46-55. |
| 21 | 张顺雨,贵永亮,袁宏涛,等.钢渣用于烧结烟气脱硫反应机理分析[J].铸造技术,2016,37(12):2650-2653. |
| 21 | ZHANG Shunyu, GUI Yongliang, YUAN Hongtao, et al.Mechanism analysis of desulfurization with steel slag for sintering flue gas[J].Foundry Technology,2016,37(12):2650-2653. |
| 22 | LIU Xiaolong, YE Meng, WANG Xue, et al.Gas-phase and particle-phase PCDD/F congener distributions in the flue gas from an iron ore sintering plant[J].Journal of Environmental Sciences,2017,54: 239-245. |
| 23 | CHEN Shuhao, WANG Xinhua, HE Xiaofei, et al.Industrial application of desulfurization using low basicity refining slag in tire cord steel[J].Journal of Iron and Steel Research,International，2013,20(1):26-33. |
| 24 | 兰颖,马平.湿法烟气脱硫系统脱硫效率的影响因素分析[J].电力科学与工程,2013,29(7):58-63. |
| 24 | LAN Ying, MA Ping.Analysis of the factors of desulfurization efficiency in wet flue gas desulfurization system[J].Electric Power Science and Engineering,2013,29(7):58-63. |
| 25 | 王丽秋,王小方,李会泉,等.焦炉烟气湿法钢渣联合脱硫脱硝工艺及机理研究[J].燕山大学学报,2016,40(4):348-354. |
| 25 | WANG Liqiu, WANG Xiaofang, LI Huiquan, et al.Research on technical method and mechanism of combined desulfurization and denitrification of flue gas from coking furnace with steel slag[J].Journal of Yanshan University,2016,40(4):348-354. |
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