无机盐工业
主管:中海油天津化工研究设计院有限公司
主办:中海油天津化工研究设计院有限公司
   中海油炼油化工科学研究院(北京)有限公司
   中国化工学会无机酸碱盐专业委员会
ISSN 1006-4990 CN 12-1069/TQ
研究与开发

新型多孔炭的制备及其储锂性能

  • 刘金杭 ,
  • 杨志鹏 ,
  • 陈修栋 ,
  • 罗宇轩 ,
  • 余浪华 ,
  • 汪亚威 ,
  • 占昌朝 ,
  • 曹小华
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  • 1.九江学院化学化工学院, 江西 九江 332005
    2.江西省生态化工工程技术研究中心
    3.九江市有机硅化学与应用重点实验室
刘金杭(1985— ),男,博士,讲师,主要从事储能材料和理论计算研究;E-mail:429162235@qq.com

收稿日期: 2022-01-08

  网络出版日期: 2022-09-22

基金资助

国家自然科学基金(22065017);江西省自然科学基金(20202BABL213012);江西省教育厅科技项目(GJJ211801);大学生创新创业计划项目(202111843004);九江市科技计划项目(S2021QNZZ020)

Preparation of new porous carbon and its lithium storage performance

  • Jinhang LIU ,
  • Zhipeng YANG ,
  • Xiudong CHEN ,
  • Yuxuan LUO ,
  • Langhua YU ,
  • Yawei WANG ,
  • Changchao ZHAN ,
  • Xiaohua CAO
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  • 1. School of Chemistry and Chemical Engineering, Jiujiang University, Jiujiang 332005, China
    2. Jiangxi Province Engineering Research Center of Ecological Chemical Industry
    3. Jiujiang Key Laboratory of Organosilicon Chemistry and Application

Received date: 2022-01-08

  Online published: 2022-09-22

摘要

以竹笋为原料炭化获得生物质炭,再用氢氧化钾活化得到多孔生物质炭,采用扫描电镜(SEM)、透射电镜(TEM)、X射线衍射(XRD)和氮气物理吸附等方法对多孔生物质炭的微观结构和形貌进行了表征。以此多孔生物质炭作负极材料探究其电化学性能,结果表明在1 000 mA/g电流密度下,材料的首次充电比容量为286.9 mA·h/g,循环50次后充电比容量保持在201.8 mA·h/g,循环500次后充电比容量仍有221.5 mA·h/g,表明此多孔炭材料具有优良的电化学循环性能,使其有望成为具有竞争力的锂电池负极材料。

本文引用格式

刘金杭 , 杨志鹏 , 陈修栋 , 罗宇轩 , 余浪华 , 汪亚威 , 占昌朝 , 曹小华 . 新型多孔炭的制备及其储锂性能[J]. 无机盐工业, 2022 , 54(9) : 85 -89 . DOI: 10.19964/j.issn.1006-4990.2021-0754

Abstract

Bamboo shoots were used as raw material to carbonize to obtain biomass charcoal,and then activated with KOH to obtain porous biomass charcoal.The microstructure and morphology of porous biomass charcoal were characterized by scanning electron microscope(SEM),transmission electron microscope(TEM),X-ray diffraction(XRD) and physical adsorption of nitrogen,etc.By using this porous biomass carbon as a anode material to explore its electrochemical performance,the results showed that at a current density of 1 000 mA/g,the first?round charging specific capacity was 286.9 mA·h/g,and after 50 cycles,the charging specific capacity remained at 201.8 mA·h/g.After 500 cycles,the charging specific capacity was still 221.5 mA·h/g,indicating that the porous carbon material had excellent electrochemical cycling performance,making it a promising anode material for lithium batteries.

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