蒙砂粉熟化过程与蚀刻玻璃表面的研究
收稿日期: 2021-09-23
网络出版日期: 2022-07-14
基金资助
湖南省重点研发计划项目(2022GK2040)
Study on aging process of masking powder and etching on glass surface
Received date: 2021-09-23
Online published: 2022-07-14
固体蒙砂粉的熟化质量是决定玻璃蚀刻效果的重要因素。用X射线衍射（XRD）、能谱仪（EDS）、拉曼光谱、粘度计、Zeta电位和碱滴定等方法研究了用柠檬酸和氟化氢铵为主要成分配制的蒙砂粉的理化性质随熟化时间的变化规律，考察和评价了熟化时间对GG6手机盖板玻璃蚀刻效果的影响。结果表明：熟化时间为36 h，得到的熟化液的黏度和氢离子浓度最大，GG6玻璃蚀刻后的粗糙度为265 nm、雾度为84%、透光率为92.4%、光泽度为11.7%，符合工业上手机玻璃盖板的蚀刻加工质量要求，蚀刻后的GG6玻璃表面形成一层微量的氟硅酸物晶体，构成的微纳蚀孔结构更均匀。测定蒙砂液的理化性质能有助于更好地了解蒙砂粉的熟化过程，对蒙砂粉蚀刻工艺具有指导作用，提高玻璃防眩工艺的生产效率。
葛盛卓 , 张喜华 , 陈小群 , 蒋崇文 . 蒙砂粉熟化过程与蚀刻玻璃表面的研究[J]. 无机盐工业, 2022 , 54(7) : 91 -97 . DOI: 10.19964/j.issn.1006-4990.2021-0578
The aging quality of solid masking powder is an important factor to determine the etching effect of glass.X-ray diffraction（XRD），energy dispersive spectrometer（EDS），Raman spectra，Viscometer，Zeta potential and alkali titration were used to study the change law of physical and chemical properties with the aging time of the masking powder mainly consisting of citric acid and ammonium bifluoride，and the effect of aging time on the etching effect of GG6 mobile phone cover glass was investigated and evaluated.The results showed that the viscosity and the hydrogen ion concentration of the suspension were the maximum when the aging time was 36 h.The leading roughness，haze，transparency and glossy of the etched glass were 265 nm，84%，92.4% and 11.7%，respectively，which met the etching quality requirements of industrial mobile phone glass cover plate.After etching，the GG6 glass surface had a layer of fluorosilicic acid crystal，which constituted a more uniform micro-nano pore structure.The determination of the physical and chemical properties of the masking liquid was helpful to better understand the curing process of frosted powder，and had a certain theoretical guidance for the etching process of frosted powder，so as to effectively improve the production efficiency of glass anti-glare process.
Key words： masking powder; cover glass; anti-glare; aging; etching
| 1 | 沈斌，冯小江，李培春.浅谈智能手机玻璃盖板发展及应用研究［J］.科技创新与应用，2017（28）：151，153. |
| 1 | SHEN Bin， FENG Xiaojiang， LI Peichun.Brief introduction to development and application of smart phone cover glass［J］.Technology Innovation and Application，2017（28）：151，153. |
| 2 | DU Jiangtao， ZHANG Xin， KING D.An investigation into the risk of night light pollution in a glazed office building：The effect of shading solutions［J］.Building and Environment，2018，145：243-259 |
| 3 | DOBROWOLSKI J A， POITRAS D， MA Penghui，et al.Toward perfect antireflection coatings：Numerical investigation［J］.Applied Optics，2002，41（16）：3075-3083. |
| 4 | YE Hui， LI Yaguo， YUAN Zhigang，et al.Ultrasonic-assisted wet chemical etching of fused silica for high-power laser systems［J］.International Journal of Applied Glass Science，2018，9（2）：288-295 |
| 5 | PIRET N， SANTORO R， DOGOT L，et al.Influence of glass composition on the kinetics of glass etching and frosting in concentrated HF solutions［J］.Journal of Non-Crystalline Solids，2018，499：208-216. |
| 6 | STARO? A， D?UGOSZ O， SZOSTAK A.Study of the influence of etching mixture components on the frosted glass effect［J］.Journal of Non-Crystalline Solids，2021，554.Doi：10.1016/j.jnoncrysol. 2020.120583 . |
| 7 | RYU H， KIM P K，LIM G.Advanced glass etching method exhibiting the controllable etch stop using metal etchant［J］.Journal of Micromechanics and Microengineering，2012，22（12）：1519- |
| 7 | 1529. |
| 8 | LIU Fanfan， ZHOU Aiguo， CHEN Jinfeng，et al.Preparation of Ti3C2 and Ti2C MXenes by fluoride salts etching and methane adsorptive properties［J］.Applied Surface Science，2017，416：781-789 |
| 9 | 温丰源，李霞.氟化氢铵的生产工艺与最新进展［J］.无机盐工业，2013，45（10）：5-7. |
| 9 | WEN Fengyuan， LI Xia.Production technology of ammonium bifluoride and latest progress thereof［J］.Inorganic Chemicals Industry，2013，45（10）：5-7. |
| 10 | 王海风，王丹，王青，等.防眩玻璃制备工艺的研究［J］.玻璃与搪瓷，2012，40（4）：6-9，14. |
| 10 | WANG Haifeng， WANG Dan， WANG Qing，et al.Study on the preparation process of anti-glare glass［J］.Glass & Enamel，2012， |
| 10 | 40（4）：6-9，14. |
| 11 | 刘存海，张佳.微氟循环玻璃蚀刻的工艺研究［J］.陕西师范大学学报：自然科学版，2014，42（1）：62-64. |
| 11 | LIU Cunhai， ZHANG Jia.Study on micro fluorine recycling etched glass［J］.Journal of Shaanxi Normal University：Natural Science Edition，2014，42（1）：62-64. |
| 12 | SURYANI S， HERYANTO H， RUSDAENI R，et al.Quantitative analysis of diffraction and infra-red spectra of composite cement/BaSO4/Fe3O4 for determining correlation between attenuation coefficient，structural and optical properties［J］.Ceramics International，2020，46（11）：18601-18607. |
| 13 | 张鹏，张煜，段江飞，等.离子交换法合成硫酸钡的研究［J］.无机盐工业，2020，52（5）：40-44. |
| 13 | ZHANG Peng， ZHANG Yu， DUAN Jiangfei，et al.Research on synthesis of barium sulfate by ion-exchange method［J］.Inorganic |
| 13 | Industry Chemicals，2020，52（5）：40-44. |
| 14 | SAINZ M A， SERRANO F J， AMIGO J M，et al.XRD microstructural analysis of mullites obtained from kaolinite-alumina mixtures［J］.Journal of the European Ceramic Society，2000，20（4）：403-412. |
| 15 | SU Shuangqing， MA Hongwen， CHUAN Xiuyun.Hydrothermal synthesis of zeolite A from K-feldspar and its crystallization me- |
| 15 | chanism［J］.Advanced Powder Technology，2016，27（1）：139-144 |
| 16 | 冯敏，王玉芳，王翚，等.柠檬酸与钛络合过程的拉曼光谱分析［J］.光散射学报，2008，20（3）：265-268. |
| 16 | FENG Min， WANG Yufang， WANG Hui，et al.Raman spectra analysis of Ti and ditric acid coordination［J］.The Journal of Light Scattering，2008，20（3）：265-268. |
| 17 | LI Jinjiang， CHATTERJEE K， MEDEK A，et al.Acid-base characteristics of bromophenol blue-citrate buffer systems in the amor- |
| 17 | phous state［J］.Journal of Pharmaceutical Sciences，2004，93（3）：697-712. |
| 18 | JUDGE J S.A study of the dissolution of SiO2 in acidic fluoride solutions［J］.Journal of the Electrochemical Society，1971，118（11）：1772-1775. |
| 19 | CACUA K， ORDO?EZ F， ZAPATA C，et al.Surfactant concentration and pH effects on the zeta potential values of alumina nanofluids to inspect stability［J］.Colloids and Surfaces A：Physicochemical and Engineering Aspects，2019，583.Doi：10.1016/j.colsurfa.2019.123960 . |
| 20 | BARBOUX P， LAGHZIZIL A， BESSOLES Y，et al.Paradoxical crystalline morphology of frosted glass［J］.Journal of Non-Cryst- alline Solids，2004，345-346：137-141. |
| 21 | 吴光辉，邓安民，崔瑞元.水剂玻璃蒙砂粉的研究［J］.玻璃与搪瓷，2001，29（2）：22-25. |
| 21 | WU Guanghui， DENG Anmin， CUI Ruiyuan.The studies on aqueous type of glass frosting powder［J］.Glass & Enamel，2001，29（2）：22-25. |
| 22 | 李筱凡，郝霞，王琦，等.常温下对高铝玻璃的高透过防眩表面处理［J］.硅酸盐学报，2021，49（5）：1000-1005. |
| 22 | LI Xiaofan， HAO Xia， WANG Qi，et al.Treatment for high-transmittance and anti-glare surface of high alminum glass at normal temperature［J］.Journal of the Chinese Ceramic Society，2021，49（5）：1000-1005. |
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