无机盐工业
主管:中海油天津化工研究设计院有限公司
主办:中海油天津化工研究设计院有限公司
   中海油炼油化工科学研究院(北京)有限公司
   中国化工学会无机酸碱盐专业委员会
ISSN 1006-4990 CN 12-1069/TQ
综述与专论

冶炼废渣吸附脱除硫化氢的研究进展

  • 姜琦 ,
  • 何永美 ,
  • 吴泳霖 ,
  • 蒋明
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  • 云南农业大学资源与环境学院,云南昆明 650201
姜琦(1997— ),男,硕士研究生,研究方向为大气污染控制工程;E-mail: ray12121@163.com

收稿日期: 2021-02-10

  网络出版日期: 2021-11-15

基金资助

国家自然科学基金(51768074)

Research progress of adsorption removal of hydrogen sulfide by smelting waste slag

  • Qi JIANG ,
  • Yongmei HE ,
  • Yonglin WU ,
  • Ming JIANG
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  • College of Resources and Environment,Yunnan Agricultural University,Kunming 650201,China

Received date: 2021-02-10

  Online published: 2021-11-15

摘要

硫化氢(H2S)是一种对大气环境和人体健康有严重危害的高毒性污染物,广泛存在于自然界及多种生产过程中。干法脱硫因其操作简单、稳定性强、脱硫效率高等优点广泛应用于含H2S尾气的脱除,吸附法是最常用的干法脱硫方式。但吸附剂在吸附过程中的损耗较大,对脱硫效果有一定的制约,增加了成本。来源广、数量大的冶炼废渣具有表面物理化学性质突出的特点,是一种潜在的新型H2S吸附剂。通过综述不同冶炼废渣吸附剂脱除H2S的研究进展,分析了其优点及不足,并讨论了影响吸附的因素及吸附剂的再生。最后针对目前存在的研究方案单一、吸附剂改性方式少等问题,提出未来研究方向包括设置多组分动态穿透吸附实验、探究多种改性方式等。

本文引用格式

姜琦 , 何永美 , 吴泳霖 , 蒋明 . 冶炼废渣吸附脱除硫化氢的研究进展[J]. 无机盐工业, 2021 , 53(11) : 36 -41 . DOI: 10.19964/j.issn.1006-4990.2021-0095

Abstract

Hydrogen sulfide(H2S) is a kind of highly toxic pollutant which seriously endangers atmospheric environment and human health.H2S widely exists in nature and many production processes.Dry desulfurization is widely used in the removal of H2S-containing exhaust gas due to its advantages such as easy operation,strong stability and high desulfurization efficiency.Adsorption is the most common method of dry desulfurization.However,the adsorbent is consumed in large quantities during the adsorbing process,which restricts the desulfurization effect and increases the cost.Smelting waste slag is a potential desulfurizer,which has the characteristics of wide sources,large quantity and excellent surface physicochemical properties.The research progress of H2S removal by different adsorbents of smelting waste slags was summarized,its advantages and disadvantages were analyzed,and factors of affecting adsorption and regeneration of adsorbent were discussed.Finally,in view of the existing problems such as single research scheme and few modification methods of adsorbent,future research directions were proposed,including setting up multi-component dynamic breakthrough adsorption test and exploring a variety of modification methods.

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