无机盐工业
主管:中海油天津化工研究设计院有限公司
主办:中海油天津化工研究设计院有限公司
   中海油炼油化工科学研究院(北京)有限公司
   中国化工学会无机酸碱盐专业委员会
ISSN 1006-4990 CN 12-1069/TQ
研究与开发

显微拉曼成像技术在钽酸锂晶体的成分、缺陷和应力分布表征中的应用研究

  • 郭志峰
展开
  • 国家能源集团准能集团,内蒙古鄂尔多斯 010300
郭志峰(1984— ),男,硕士,高级工程师,主要研究方向为无机材料合成与检测;E-mail: 983645207@qq.com

收稿日期: 2021-02-19

  网络出版日期: 2021-10-11

基金资助

神华集团煤炭开采水资源保护与利用国家重点实验室开放基金(20170514)

Study on application of Raman mapping technology in characterization of composition,defects and stress distribution of lithium tantalate crystal

  • Zhifeng Guo
Expand
  • CHN ENERGY Zhungeer Energy Co.,Ltd.,Erdos 010300,China

Received date: 2021-02-19

  Online published: 2021-10-11

摘要

采用激光共聚焦显微拉曼光谱仪分别对钽酸锂晶体进行了显微拉曼成像测试研究,以865 cm-1特征峰峰强度对钽酸锂的成分分布进行了显微拉曼成像;以865 cm-1特征峰半高宽对晶体中锂含量分布进行了显微拉曼成像;以750 cm-1缺陷峰强度对晶体中的本征缺陷分布进行了显微拉曼成像;以865 cm-1特征峰峰位置对晶体中的应力分布进行了显微拉曼成像。测试结果表明,显微拉曼成像可以很好地对钽酸锂单晶片的化学成分和组分、本征缺陷、应力等化学物理性质的微观分布进行成像,未掺杂三氧化二铁比掺杂了三氧化二铁的钽酸锂晶体的成分和锂含量分布更加均匀,未掺杂三氧化二铁和掺杂了三氧化二铁的钽酸锂晶体的本征缺陷分布皆比较均匀且很少,未掺杂三氧化二铁比掺杂了三氧化二铁的钽酸锂晶体的应力分布更加均匀,掺杂了三氧化二铁的钽酸锂晶体存在明显的应力分布集中的区域。

本文引用格式

郭志峰 . 显微拉曼成像技术在钽酸锂晶体的成分、缺陷和应力分布表征中的应用研究[J]. 无机盐工业, 2021 , 53(10) : 70 -73 . DOI: 10.19964/j.issn.1006-4990.2021-0102

Abstract

The Raman mapping test of lithium tantalate crystal was studied by laser raman microscopy spectrometer.The com-position distribution of lithium tantalate crystal was imaged by Raman mapping in the characteristic peak intensity of 865 cm-1.The Li content distribution of crystal was imaged by Raman mapping in the characteristic peak FWHM of 865 cm-1.The de-fects distribution of crystal was imaged by Raman mapping in the defects peak intensity of 750 cm-1.The stress distribution of crystal was imaged by Raman mapping in the characteristic peak position of 865 cm-1.The test results showed the composi-tion,defects and stress distribution of lithium tantalate single crystal sheet could be well imaged by Raman mapping.The composition and Li content distribution of undoped lithium tantalate crystal were more uniform than that doped with Fe2O3.The distribution of intrinsic defects in undoped and doped lithium tantalate crystals with Fe2O3 was both relatively uniform and few.The stress distribution of undoped lithium tantalate crystal was more uniform than that doped with Fe2O3.There was an obvious stress concentration region in lithium tantalate crystal doped with Fe2O3.

参考文献

[1] Juvalta F, Jazbinsek M, Gunter P. Electro-optical properties of near-stoichiometric and congruent lithium tantalite at ultraviolet wave-lengths[J]. J.Opt.Soc.Am.B, 2006, 23:276-281.
[2] Xu P, Zhao L N, Lv X J, et al. Compact high-power red-green-blue laser light source generation from a single lithium tantalite with cascaded domain modulation[J]. Optics Express, 2009, 17:9509-9514.
[3] Imbrock J, Wevering S, Buse K. Nonvolatile holographic storage in photorefractive lithium tantalate crystals with laser pulses[J]. J.Opt.Soc.Am.B, 1999, 16:1392-1397.
[4] Lange K, Rapp B E, Rapp M. Surface acoustic wave biosensors:A review[J]. Anal.Bioanal.Chem., 2008, 391:1509-1519.
[5] Ganesamoorthy S, Nakamura M, Takekawa S, et al. A comparative study on the domain switching characteristics of near stoichiometric lithium niobate and lithium tantalate single crystals[J]. Materials Science and Engineering B, 2005, 120:125-129.
[6] Lines M E, Glass A M. Primary pyroelectric effect in LiTaO3[J]. Phys.Rev.Lett., 1977, 39:1362-1365.
[7] 吴娟霞, 徐华, 张锦. 拉曼光谱在石墨烯结构表征中的应用[J]. 化学学报, 2014(3):301-318.
[8] 杨昕梅, 孙泽, 黄龙, 等. 相变储能二元混合硝酸盐的Raman光谱研究[J]. 无机盐工业, 2016, 48(2):18-21.
[9] 张福生, 陈秀芳, 崔潆心, 等. Ge掺杂碳化硅晶体的生长缺陷[J]. 无机材料学报, 2016(11):1166-1170.
[10] 李亚, 丁敏娟, 李蓉, 等. 黏土基二氧化钛水热制备及其光催化性能研究[J]. 无机盐工业, 2018, 50(12):75-78.
[11] 胡成龙, 陈韶云, 陈建, 等. 拉曼光谱技术在聚合物研究中的应用进展[J]. 高分子通报, 2014(3):30-45.
[12] 路交, 朱珊珊, 崔笑宇, 等. 拉曼光谱成像技术及其在生物医学中的应用[J]. 中国激光, 2018(3):70-79.
[13] 沈大娲, 郑菲, 吴娜, 等. 拉曼光谱在文物考古领域的应用态势分析[J]. 光谱学与光谱分析, 2018(9):2657-2664.
[14] 赵业权, 贾宝申, 张学锋, 等. 掺镁近化学计量比LiTaO3晶体生长及光学性能[J]. 硅酸盐学报, 2007, 36(8):995-997.
[15] 师丽红, 孔勇发, 阎文博, 等. 近化学计量比钽酸锂晶体的拉曼光谱研究[J]. 人工晶体学报, 2005(6):1024-1029.
[16] 袁方方, 葛培琪, 高玉飞. KDP晶体缺陷对生长应力分布的影响[J]. 人工晶体学报, 2011(6):1435-1439.
[17] 王邦国, 李明伟, 周川. 三维运动下KDP晶体生长过程中的应力分析[J]. 人工晶体学报, 2014(12):3098-3103.
[18] 邓亚, 张宇民, 周玉锋. 碳化硅单晶材料残余应力检测技术研究进展[J]. 材料导报, 2019(S2):206-209.
文章导航

/