蒽醌法合成过氧化氢催化剂的研究进展
收稿日期: 2020-10-13
网络出版日期: 2021-04-23
基金资助
国家自然科学基金(21763014)
Research progress of anthraquinone synthesis catalyst for hydrogen peroxide
Received date: 2020-10-13
Online published: 2021-04-23
杨杰 , 安霓虹 , 魏建伟 , 王红琴 , 谢继阳 , 戴云生 . 蒽醌法合成过氧化氢催化剂的研究进展[J]. 无机盐工业, 2021 , 53(4) : 20 -24 . DOI: 10.11962/1006-4990.2020-0259
Hydrogen peroxide(H2O2, commonly known as hydrogen peroxide solution) is often used as bleaching agent and disinfectant due to its strong oxidability.Meanwhile, it is also used as chemical raw materials.At present, the main method of producing hydrogen peroxide in industry is anthraquinone method, and nearly 99% of the products in the world are obtained by the anthraquinone method.The research on catalysts with high activity, high selectivity and economic efficiency is the most challenging task in the synthesis of hydrogen peroxide.At the same time, it is also one of the research hotspots in the field of industrial catalysis.From the perspective of industrial application, noble metal catalysts with palladium as the activity are currently the most used and most mature catalysts.However, due to the high price of metal palladium, the preparation cost of the palladium catalyst is relatively high.Therefore, the research and development to reduce the cost of the catalyst has practical application value.Ruthenium and nickel catalysts have received extensive attention from researchers because of their lower price.The nickel catalyst has high activity but it is unstable;the ruthenium catalyst has good selectivity and high stability, but the activity is relatively low.In order to solve these current problems, researchers have carried out a lot of research work from the two aspects of carrier and auxiliary agents.Focusing on the production of hydrogen peroxide catalysts from anthraquinone, the research progress of various active components, carrier and auxiliary agents in anthraquinone hydrogenation catalysts was reviewed.The advantages and disadvantages of various active components were briefly discussed and the functions of various supports and promoters were summarized, so as to provide some useful enlightenment for the synthesis and preparation of hydrogen peroxide catalysts.
Key words: hydrogen peroxide; anthraquinone method; catalyst; precious metal
[1] | 张国成 . 过氧化氢生产技术[M]. 北京: 化学工业出版社, 2012: 84-88. |
[2] | 王松林, 程义, 张晓听 , 等. 蒽醌法生产过氧化氢催化剂的研究进展[J]. 化工进展, 2017,36(11):4057-4063. |
[3] | Jenkins C L . Fixed-bed hydrogen peroxide catalyst:US, 5853693[P]. 1998-12-29. |
[4] | 申卫卫, 宋金文, 朱成杰 , 等. 一种蒽醌加氢制备双氧水的钯催化剂及其制备方法:CN, 105363442[P]. 2016 -03-02. |
[5] | 陈雪荧, 乔明华, 贺鹤勇 . 载体对负载型Ni-B催化剂催化2-乙基蒽醌加氢制H2O2反应的性能的影响[J]. 催化学报, 2011,32(2):325-332. |
[6] | Liu Bo, Qiao Minghua, Deng Jiangfa , et al. Sketetal Ni catalyst prepared from a rapidly quenched Ni-Al alloy and its high selectivity in 2-ethylanthraquinone hydrogenation[J]. Journal of Catalysis, 2001,204:512-515. |
[7] | Hou Y, Wang Y, Mi Z . The beneficial effects of molydenum addition on Ni-B amorphous alloy catalyst used in 2-ethylanthraquinone hydrogenation[J]. Journal of Materials Science, 2005,40(24):6568-6588. |
[8] | Chen X, Wang S, Zhuang J , et al. Mesoporous silica-supported NiB amorphous alloy catalysts for selective hydrogenation of 2-ethlanthraquinone[J]. Journal of Catalysis, 2004,227(2):419-427. |
[9] | 朱向学, 李朝恒, 刘淑文 , 等. 过氧化氢生产用铂催化剂的制备及性能研究[J]. 分支催化, 2002,16(5):359-363. |
[10] | 戴云生, 谢继阳, 吴美岩 , 等. 一种用于蒽醌加氢制备双氧水的钌催化剂及其制备方法:CN, 108057438[P]. 2018-05-22. |
[11] | 郭艳艳 . 结构化催化剂制备双氧水的研究[D].北京. 北京化工大学, 2018. |
[12] | 王树东, 李晓彤 . 一种用于双氧水合成的高分散催化剂及其制备方法:CN, 105268433[P]. 2016 -01-27. |
[13] | 张红, 杨卫东, 杨吉存 . 一种蒽醌法生产双氧水用钯催化剂及其制法:CN, 110639512[P]. 2020 -01-03. |
[14] | 熊中强, 米镇涛, 张香文 . 负载型Pd-B非晶态合金加氢催化剂的制备与反应研究[D]. 北京:中国石油大学, 2005. |
[15] | Guo Yanyan, Dai Chengna, Lei Zhigang . Synjournal of hydrogen peroxide over Pd/SiO2/COR monolith catalysts by anthraquinone method[J]. Catalysit Today, 2016,276:36-45. |
[16] | Zhang Jianguo, Li Defu, Zhao Yujun , et al. A Pd/Al2O3/cordierite monolithic catalyst for hydrogenation of 2-ethylanthraquinone[J]. Catalysis Communications, 2008,9:2565-2569. |
[17] | Drelinkiewicz A, Hasik M . 2-Ethyl-9, 10-anthraquinone hydrogenation over Pd/polymers-Pd(Ⅱ) chlorcomplexes interactions[J]. Journal of Molecular Cayalysis A:Chemical, 2001,177:149-164. |
[18] | 刘国栋, 田亚杰 . 一种封装金属氧化物或金属纳米颗粒的MFI结构片层状分子筛催化剂、其制备方法及用途:CN, 107020147[P]. 2017 -04-25. |
[19] | 崔建华 . 一种蒽醌法制备过氧化氢的方法:CN, 106395755[P]. 2017 -02-15. |
[20] | Ma Qingqing, Wang Nan, Liu Guozhu , et al. Enhanced performance of Pd nanoparticles on SBA-15 grafted with alkyltrialkoxysilane in 2-ethyl-anthraquinone hydrogenation[J]. Microporoous and Mesoporous Materials, 2019,279:245-251. |
[21] | Bi Ruxin, Wang Qian, Miao Chenglin , et al. Pd/NiO/Al array catalyst for 2-ethylanthraquinone hydrogenation:Synergistic effect between Pd and NiO/Al support[J]. Catalysis Letters, 2019,149:1286-1296. |
[22] | 王丰, 徐贤伦 . 正交法研究钯/铝锆复合氧化物烷基蒽醌加氢催化剂[J]. 分子催化, 2008,22(5):418-423. |
[23] | 江燕, 吴昊, 张春燕 , 等. 2-乙基蒽醌加氢用高性能介孔Pd-Fe-Ba/γ- Al2O3催化剂的制备[J]. 化学与生物工程, 2016,33(11):21-26. |
[24] | 贾立明, 徐会青, 刘全杰 , 等. 一种蒽醌加氢催化剂及其制备方法和应用:CN, 108114729[P]. 2018 -06-05. |
[25] | 王榕, 林墀昌, 毛树禄 , 等. La2O3对Pd/Al2O3催化蒽醌氢化制H2O2性能的影响[J]. 催化学报, 2005,26(4):296-300. |
[26] | Hou Yongjiang, Wang Yaquan, He Fei , et al. Liquid phase hydrogenation of 2-ethylanthraquinone over La-doped Ni-B amorphousalloy catalysts[J]. Materials Letters, 2004,58:1267-1271. |
[27] | Wang Yunhao, Peng Mao, Ye Chenliang , et al. Enhanced catalytic performance of Pd-Ga bimetallic catalysts for 2-ethylanthraquinone hydrogenation[J]. Applied Organometallic Chemistry, 2019,33(9):5076. |
[28] | Hong Runrun, He Yufei, Feng Junting , et al. Fabrication of supported Pd-Ir/Al2O3 bimetallic catalysts for 2-ethylanthraquinone hydrogenation[J]. AlChE Journal, 2017,63:3955-3965. |
[29] | 张哲, 曹云芹, 李晶 , 等. 锌改性蒽醌法制过氧化氢用钯催化剂[J]. 化学推进剂与高分子材料, 2017,15(5):75-78. |
[30] | Wang Suli, Gao Kaige, Li Wei , et al. Effect of Zn addition on the direct synjournal of hydrogen peroxide over supported palladium catalysts[J]. Applied Catalysis A:General, 2017,531:89-95. |
[31] | 卓俊琳, 蔡卫权, 罗晓雷 . 一锅水热-浸渍法制备Pd-Fe/SiO2催化剂及其蒽醌加氢性能的影响[J]. 化工进展, 2016,35(12):3913-3918. |
[32] | Kosydar R, Drelinkiewicz A, Lalik E , et al. The role of alkali modifiers(Li,Na,K,Cs) in activity of 2%Pd/Al2O3 catalysts for 2-ethyl-9,10-anthraquione hydrogenation[J]. Applied Catalysis A:General, 2011,402:121-131. |
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