无机盐工业
主管:中海油天津化工研究设计院有限公司
主办:中海油天津化工研究设计院有限公司
   中海油炼油化工科学研究院(北京)有限公司
   中国化工学会无机酸碱盐专业委员会
ISSN 1006-4990 CN 12-1069/TQ
研究与开发

碱式碳酸镁基复合阻燃剂的制备及其阻燃性能研究

  • 郑楠 ,
  • 田朋 ,
  • 朱兴坤 ,
  • 孙雪 ,
  • 庞洪昌 ,
  • 宁桂玲
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  • 大连理工大学精细化工国家重点实验室,辽宁大连 116024
郑楠(1994— ),女,硕士研究生,从事碱式碳酸镁基EVA复合阻燃材料的制备与性能研究。

收稿日期: 2020-08-13

  网络出版日期: 2021-02-06

基金资助

消防电缆专用特种氧化镁的制备及性能研究(DUT19JC57);中央高校基本科研业务费,核用高纯硼酸裸露晶面重构及速溶性和腐蚀性调控研究;国家自然科学基金(U1808210)

Preparation and flame retardant properties of basic magnesium carbonate composite flame retardant

  • Nan Zheng ,
  • Peng Tian ,
  • Xingkun Zhu ,
  • Xue Sun ,
  • Hongchang Pang ,
  • Guiling Ning
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  • State Key Laboratory of Fine Chemicals,Dalian University of Technology,Dalian 116024,China

Received date: 2020-08-13

  Online published: 2021-02-06

摘要

采用硅烷表面处理的碱式碳酸镁纳米片和氢氧化镁以及氢氧化铝为复合阻燃剂,通过密炼模压法制备了一系列复配阻燃剂协效阻燃EVA的复合材料。利用拉伸性能测试仪、熔融指数仪、垂直燃烧测试仪和锥形量热仪分别测试了复合材料的力学性能、加工流动性能和阻燃性能,利用热重分析仪测试了复配阻燃剂的热分解行为。结果表明,复配阻燃剂以适当比例协效阻燃EVA在更宽的燃烧温度范围内发生分解,能够起到更好的阻燃效果。并且复配阻燃剂/EVA复合材料的热释放速率和烟释放率大幅度降低,分别为181.06 kW/m2和0.032 m2/s。另外,复配阻燃剂/EVA复合材料的拉伸强度达到9.73 MPa,断裂伸长率为155.07%,每10 min熔融指数为1.00 g,符合电线电缆行业标准。

本文引用格式

郑楠 , 田朋 , 朱兴坤 , 孙雪 , 庞洪昌 , 宁桂玲 . 碱式碳酸镁基复合阻燃剂的制备及其阻燃性能研究[J]. 无机盐工业, 2021 , 53(2) : 47 -50 . DOI: 10.11962/1006-4990.2020-0214

Abstract

A series of flame retardantcy EVA matrix composites were prepared by mixing and compression molding with silane surface treated basic magnesium carbonate nanosheets,magnesium hydroxide and aluminum hydroxide as composite flame retardants.The mechanical properties,processability and flame retardancy of the composites were investigated by uni-versal tensile test,melt index test,vertical buring test and cone calorimetric test respectively.And the thermal decomposition behavior of the composite flame retardant was studied by thermogravimetric analysis.The results showed that the composite flame retardant can decompose in a wider combustion temperature range with a proper proportion of flame retardant/EVA,which has a better flame retardant effect.And the heat release rate and smoke release rate of the composite flame retardant/EVA composite were significantly reduced to 181.060 kW/m2 and 0.032 m2/s,respectively.In addition,the tensile strength of the composite flame retardant/EVA composite was 9.73 MPa,the elongation at break was 155.07%,and the melt index was 1.00 g per 10 min,which can be used in the wire and cable industry.

参考文献

[1] Wegner G, Wagemann K. Polymers and the environment-current pro-blems and future research[J]. Advanced Materials, 2010,6(9):629-634.
[2] Huang H H, Tian M, Yang J, et al. Stearic acid surface modifying Mg(OH)2:Mechanism and its effect on properties of ethylene vinyl acetate/Mg(OH)2 composites[J]. Journal of Applied Polymer Scien-ce, 2008,107(5):3325-3331.
[3] Yang J H, Zhang Y, Zhang Y X. Mechanical properties and microst-ructure of HDPE/Al(OH)3/silicone oil composite[J]. Journal of App-lied Polymer Science, 2002,83(9):1896-1903.
[4] 郭如新. 水镁石、水菱镁石和斜方云石资源、加工与应用[J]. 无机盐工业, 2012,44(2):13-16.
[5] Kangal O, Kokkilic O, Burat F. Production of huntite and hydroma-gnesite with flame retardant featured by flotation[J]. Minerals & Me-tallurgical Processing, 2009,26(2):109-113.
[6] Wang Zhengzhou, Qu Baojun, Fan Weicheng, et al. Combustion ch-aracteristics of halogen-free flame-retarded polyethylene containing magnesium hydroxide and some synergists[J]. Journal of Applied Polymer Science, 2001,81(1):206-214.
[7] 张宏鹏, 庞洪昌, 朱行坤, 等. GF对水镁石基阻燃剂阻燃EVA复合材料性能的影响[J]. 工程塑料应用, 2016,44(2):120-123.
[8] Bhattacharjya D, Selvamani T, Mukhopadhyay I. Thermal decompo-sition of hydromagnesite[J]. Journal of Thermal Analysis and Calo-rimetry, 2011.Doi: 10.1007/s10973-011-1656-9.
[9] de Silva R T, Mantilaka M M M G, Ratnayake S P, et al. Nano-MgO reinforced chitosan nanocomposites for high performance packaging applications with improved mechanical,thermal and barrier proper-ties[J]. Carbohydrate Polymers, 2017,157:739-747.
[10] Tian Peng, Han Xiuying, Ning Guiling, et al. Synjournal of porous hierarchical MgO and its superb adsorption properties[J]. ACS Applied Materials and Interfaces, 2013,5:12411-12418.
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