失活商用SCR催化剂的再生与资源化利用现状
收稿日期: 2020-07-19
网络出版日期: 2021-01-08
Status of regeneration and resource utilization of deactivated commercial SCR catalyst
Received date: 2020-07-19
Online published: 2021-01-08
龚鹏 , 张兵 , 刘思浩 . 失活商用SCR催化剂的再生与资源化利用现状[J]. 无机盐工业, 2021 , 53(1) : 14 -17 . DOI: 10.11962/1006-4990.2020-0066
With the increasingly strict environmental protection policy,the disposal of waste SCR catalyst from flue gas deni-trification becomes more and more serious.The application conditions and deactivation reasons of SCR catalyst were intro-duced,and the market prospect and the limitations of the industrial chain combined with the policies related to the disposal of waste SCR catalyst were analyzed.The research progress of regeneration and recovery of deactivated SCR catalyst at home and abroad was summarized emphatically.The regeneration method was corresponding to the deactivation mechanism.Three ways of recycling waste SCR catalyst were summarized.Through comparative analysis,it was pointed out that the preparation of new SCR catalyst is the most efficient and economic way.
Key words： selective catalytic reduction; catalyst; inactivation; regeneration; resource reuse
| [1] | 王丽琼. 基于LMDI-SMC中国氮氧化物减排绩效动态演化规律研究[J]. 生态环境学报, 2019,28(1):90-96. |
| [2] | 陈德君, 苏培东. 川藏铁路康林段有害气体特征及危害研究[J]. 铁道工程学报, 2019,36(6):18-22. |
| [3] | 蔺卓玮, 陆强, 唐昊, 等. 平板式V2O5-MoO3/TiO2型SCR催化剂的中低温脱硝和抗中毒性能研究[J]. 燃料化学学报, 2017,45(1):113-122. |
| [4] | 周惠, 黄华存, 董文华. SCR脱硝催化剂失活及再生技术的研究进展[J]. 无机盐工业, 2017,49(5):9-13. |
| [5] | 赵雪, 程茜, 侯俊先. 脱硫脱硝行业2017年发展综述[J].中国环保产业, 2018(7):10-24. |
| [6] | 张立萍, 吕灵灵, 董莉, 等. 废SCR催化剂资源回收利用研究进展[J]. 云南化工, 2019,46(8):77-79,83. |
| [7] | Yu Y K, He C, Chen J S, et al. Regeneration of deactivated commer-cial SCR catalyst by alkali washing[J]. Catalysis Communications, 2013,39:78-81. |
| [8] | Raziyeh Khodayari, Ingemar Odenbrand C U.Regeneration of commercial SCR catalysts by washing and sulphation:effect of sulphate groups on the activity[J]. Applied Catalysis B,Environmental, 2001,33(4):277-291. |
| [9] | 马建蓉, 黄张根, 刘振宇, 等. 再生方法对V2O5/AC催化剂同时脱硫脱硝活性的影响[J]. 催化学报, 2005,26(6):463-469. |
| [10] | 高凤雨, 唐晓龙, 易红宏, 等. 商用SCR催化剂的钠中毒及再生[J]. 中南大学学报:自然科学版, 2015,46(6):2382-2390. |
| [11] | 尹海芮, 王远洋. 燃煤电厂烟气脱硝废弃SCR催化剂的再生和回收研究进展[J]. 现代化工, 2019,39(9):16-20. |
| [12] | Yu Y K, Chen J S, Wang J X, et al. Performances of CuSO4/TiO2 catalysts in selective catalytic reduction of NOx by NH3[J]. Chine-se Journal of Catalysis, 2016,7(2):281-287. |
| [13] | Ye T, Chen D, Yin Y, et al. Experimental research of an active so-lution for modeling in situ activating selective catalytic reduction catalyst[J]. Catalysts, 2017,7(9):258-275. |
| [14] | 姚杰, 胡凯妮, 朱文韬, 等. 再生后SCR脱硝催化剂的运行情况分析[J]. 山东化工, 2019,48(17):224-226. |
| [15] | 竹涛, 张星, 高放, 等. 废弃SCR催化剂再生研究进展[J]. 环境工程, 2018,36(10):92-96,183. |
| [16] | 李俊峰, 张兵兵, 李翼然. 基于钒钛基SCR法废脱硝催化剂的回收利用[J]. 广州化工, 2014,42(24):130-132. |
| [17] | 曾瑞, 郝永利. 废弃SCR催化剂回收利用项目建设格局的分析[J]. 中国环保产业, 2014(9):41-45. |
| [18] | 周昊, 国旭涛, 周明熙. 一种废弃SCR烟气脱硝催化剂冶金烧结处理方法:中国,105907950A[P]. 2016-08-31. |
| [19] | 朴荣勋, 马兰, 杨绍利, 等. 废弃脱硝催化剂铝热还原—真空磁悬浮精炼制备钛铝基合金试验研究[J]. 钢铁钒钛, 2019,40(3):39-45. |
| [20] | 李朴芳, 穆林, 王社斌. 碳热还原/熔融分离废SCR催化剂中有价金属[J]. 无机盐工业, 2020,52(1):93-98. |
| [21] | 戴泽军, 王乐乐, 唐浩, 等. 废弃钒钛系选择性催化还原催化剂重金属浸出特性[J]. 化工进展, 2018,37(10):3873-3878. |
| [22] | 刘子林, 王宝冬, 马瑞新, 等. 废SCR催化剂钠化焙烧回收钨和钒的机理探究[J]. 无机盐工业, 2016,48(7):63-67. |
| [23] | Kim J W, Lee W G, Hwang I S, et al. Recovery of tungsten from sp-ent selective catalytic reduction catalysts by pressure leaching[J]. Journal of Industrial and Engineering Chemistry, 2015,28:73-77. |
| [24] | 贾勇, 丁万丽, 丁希楼, 等. 废SCR脱硝催化剂中钨和钒的浸出实验研究[J]. 环境科学学报, 2016,36(10):3759-3764. |
| [25] | 闫巍, 余智勇, 张畅, 等. 废弃SCR催化剂中钒和钨的浸出及回收[J]. 化工环保, 2018,38(4):471-475. |
| [26] | 李智虎, 丁万丽, 李小海, 等. 废选择性催化还原脱硝催化剂中金属钨和钒的萃取分离及回收[J]. 硅酸盐学报, 2018,46(11):1639-1644. |
| [27] | Huo Y T, Chang Z D, Li W J, et al. Reused and valorization of vana-dium and tungsten from waste V2O5-WO3/TiO SCR catalyst[J]. Wa-ste Biommass Valor, 2015(6):159-165. |
| [28] | 陈颖敏, 谢宗, 王超凡. 燃煤电厂废弃SCR催化剂回收二氧化钛的研究[J]. 中国电力, 2016,49(6):151-156,180. |
| [29] | 吴晓东, 许腾飞, 刘雪松, 等. 一种从废钒钨钛催化剂中回收锐钛矿型钛钨粉的方法:中国,104789780A[P]. 2015-07-22. |
| [30] | 戚春萍, 武文粉, 王晨晔, 等. 燃煤电厂废旧SCR脱硝催化剂中TiO2载体的回收与再利用[J]. 化工学报, 2017,68(11):4239-4248. |
| [31] | 周子健, 刘小伟, 葛振武, 等. 基于失活商业脱硝催化剂制备的再生SCR催化剂性能研究[J]. 中国电机工程学报, 2017,37(9):2614-2622. |
| [32] | 何川, 王乐乐, 杨晓宁, 等. 废弃选择性催化还原催化剂混掺对新催化剂脱硝性能的影响[J]. 化工进展, 2018,37(2):581-586. |
/
| 〈 |
|
〉 |
