无机盐工业
主管:中海油天津化工研究设计院有限公司
主办:中海油天津化工研究设计院有限公司
   中海油炼油化工科学研究院(北京)有限公司
   中国化工学会无机酸碱盐专业委员会
ISSN 1006-4990 CN 12-1069/TQ
催化材料

片状铋/钒酸铋复合催化剂的制备及其光催化性能

  • 冯飞 ,
  • 李书文 ,
  • 汪铁林 ,
  • 王为国 ,
  • 王存文
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  • 1.武汉工程大学化工与制药学院,湖北武汉 430205
    2.武汉工程大学绿色化工过程教育部重点实验室
冯飞(1994— ),女,硕士研究生,研究方向为光催化;E-mail: 1611209949@qq.com

收稿日期: 2020-07-15

  网络出版日期: 2021-01-08

Synthesis and photocatalytic performance of sheet-like Bi/BiVO4 composite catalyst

  • Fei Feng ,
  • Shuwen Li ,
  • Tielin Wang ,
  • Weiguo Wang ,
  • Cunwen Wang
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  • 1. School of Chemical Engineering and Pharmacy,Wuhan Institute of Technology,Wuhan 430205,China
    2. Key Laboratory of Green Chemical Engineering Process of Ministry of Education,Wuhan Institute of Technology

Received date: 2020-07-15

  Online published: 2021-01-08

摘要

用溶剂热法合成了一系列不同铋含量的片状铋/钒酸铋(Bi/BiVO4)复合光催化剂。采用X射线衍射(XRD)、X射线光电子能谱(XPS)、扫描电子显微镜(SEM)、透射电子显微镜(TEM)、紫外-可见漫反射光谱(UV-vis DRS)、电感耦合等离子发射光谱 (ICP-OES)、氮气吸附脱附和光电流响应等技术对所制备的催化剂进行了表征。通过氙灯下光催化降解亚甲基蓝的性能来评价样品的光催化活性,实验结果表明铋的自掺杂能显著提高钒酸铋的光催化活性。最后,通过自由基捕获实验对铋/钒酸铋光催化机理进行了探讨。

本文引用格式

冯飞 , 李书文 , 汪铁林 , 王为国 , 王存文 . 片状铋/钒酸铋复合催化剂的制备及其光催化性能[J]. 无机盐工业, 2021 , 53(1) : 107 -112 . DOI: 10.11962/1006-4990.2020-0064

Abstract

A series of sheet-like Bi/BiVO4 composite photocatalysts with different Bi contents were synthesized using solvo-thermal method.The prepared catalysts were characterized by using X-ray diffraction(XRD),X-ray photoelectron spectro-scopy(XPS),scanning electron microscopy(SEM),transmission electron microscopy(TEM),ultraviolet-visible diffuse reflec-tion spectroscopy(UV-Vis DRS),inductively coupled plasma optical emission spectroscopy(ICP-OES),nitrogen adsorp-tion-desorption analysis and photocurrent response measurements.The photocatalytic performance of the sample was assessed by photodecomposition of methylene blue(MB) under xenon lamp irradiation.The results showed that the photocatalytic ac-tivity of BiVO4 was enhanced significantly with Bi self-doping.Finally,the photocatalytic reaction mechanism of Bi/BiVO4 composite was discussed by free radical capture experiments.

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