锂离子电池用固态电解质的研究现状与展望
收稿日期: 2020-02-19
网络出版日期: 2020-07-13
Research status and prospect of solid electrolyte for lithium ion batteries
Received date: 2020-02-19
Online published: 2020-07-13
闫雅婧 . 锂离子电池用固态电解质的研究现状与展望[J]. 无机盐工业, 2020 , 52(7) : 22 -25 . DOI: 10.11962/1006-4990.2019-0676
At present,commercial lithium ion batteries（LIBs） mostly use organic liquid electrolyte,which is flammable,explosive,leaky and other security risks.The use of solid electrolyte instead of organic liquid electrolyte could effectively improve the safety of batteries.The solid electrolyte for Li-ion battery can be divided into inorganic electrolyte and organic（polymer） electrolyte.Inorganic solid electrolyte has good adaptability to high temperature or other corrosive environment,which is suitable for rigid battery in extreme working environment;polymer solid electrolyte has obvious advantages in flexibility and processability,which is suitable for flexible battery and other fields,but these materials still have problems to be solved.Inorganic-organic complex is expected to integrate the advantages of the two materials,learn from each other and improve the comprehensive performance and practical value of solid electrolyte.
| [1] | 王蔼廉, 计文希, 陈婧, 等. 锂电池用固态电解质研究进展[J]. 高分子通报, 2019(9):1-14. |
| [2] | 刘黎, 焦丽芳, 袁华堂, 等. 锂离子电池电极材料Li1+xV3O8 研究进展[J]. 化工进展, 2011,30(1):189-194. |
| [3] | 赵艳艳, 张玉荣. 锂离子电池正极材料 Li(1-2x)MgxMnPO4/C的合成与表征[J]. 化学研究, 2011,22(1):17-21. |
| [4] | 李旺, 周兰, 刘佳丽. 镍锰酸锂正极材料及其适配性电解液研究最新进展[J]. 无机盐工业, 2019,51(6):5-10. |
| [5] | 谢元, 李俊华, 王佳, 等. 锂离子电池三元正极材料的研究进展[J]. 无机盐工业, 2018,50(7):18-22. |
| [6] | 叶嘉明, 李昌明. 锂离子电池负极材料磷酸钛锂研究进展[J]. 无机盐工业, 2019,51(5):17-22. |
| [7] | 吴大钊. PVdF-HFP基锂离子电池隔膜增强改性研究[D]. 苏州:苏州大学, 2015. |
| [8] | 王立仕. 基于LiPF6的几种锂离子电池电解液的性能研究[D]. 乌鲁木齐:新疆大学, 2006. |
| [9] | 闫雅婧. 基于LiPF6的锂离子电池电解液的发展现状[J]. 煤炭与化工, 2013,36(9):28-31. |
| [10] | Chen R, Qu W, Guo X, et al. The pursuit of solid-state electrolytes for lithium batteries:from comprehensive insight to emerging horizons[J]. Materials Horizons, 2016,3(6):487-516. |
| [11] | 赵嫣然. 全固态锂二次电池用新型自支撑复合电解质的研究[D]. 北京:北京理工大学, 2016. |
| [12] | Boukamp B A, Huggins R A. Lithium ion conductivity in lithium nitride[J]. Physics Letters A, 1976,58(4):231-233. |
| [13] | 李林. LiPON固态电解质与全固态薄膜锂离子电池制备及特性研究[D]. 兰州:兰州大学, 2018. |
| [14] | Nagao M, Hayashi A, Tatsumisago M, et al. In situ SEM study of a lithium deposition and dissolution mechanism in a bulk-type solidstate cell with a Li2S-P2S5 solid electrolyte[J]. Physical Chemistry Chemical Physics, 2013,15(42):18600-18606. |
| [15] | 黄祯, 杨菁, 陈晓添, 等. 无机固体电解质材料的基础与应用研究[J]. 储能科学与技术, 2015,4(1):1-18. |
| [16] | 张舒, 王少飞, 凌仕刚, 等. 锂离子电池基础科学问题(X)——全固态锂离子电池[J]. 储能科学与技术, 2014,3(4):376-394. |
| [17] | Inaguma Y, Chen L Q, Itoh M, et al. High ionic-conductivity in lithium lanthanum titanate[J]. Solid State Communications, 1993,86(10):689-693. |
| [18] | Hong H Y P. Crystal structure and ionic conductivity of Li14Zn(GeO4)4 and other new Li+ superionic conductors[J]. Mater.Res.Bull., 1978,13(8):117-124. |
| [19] | 张克杰, 陈鹏, 谢旺旺, 等. 磷酸铁锂优缺点及改性研究进展[J]. 无机盐工业, 2018,50(6):13-17. |
| [20] | 李卫, 田文怀, 其鲁. 锂离子电池正极材料技术研究进展[J]. 无机盐工业, 2015,47(6):1-5. |
| [21] | Chojnacka J, Acosta J L, Morales E. New gel electrolytes for batteries and supercapacitor applications[J]. Power Sources, 2001,97/98:819-821. |
| [22] | Zhang S S, Xu K, Jow T R. Li-ion cell with poly(acrylonitrile-methyl methacrylate)-based gel polymer electrolyte[J]. Solid State Ionics, 2003,158:375-380. |
| [23] | 吴宇平, 袁翔云, 董超. 锂离子电池——应用与实践[M]. 北京: 化学工业出版社, 2011. |
| [24] | 郭炳坤, 李新海, 杨松青. 化学电源:电池原理及制造技术[M]. 长沙: 中南工业大学出版社, 2000. |
| [25] | 郑洪河. 锂离子电池电解质[M]. 北京: 化学工业出版社, 2007. |
| [26] | Manuel S A, Nahm K S. Review on composite polymer electrolytes for lithium batteries[J]. Polymer, 2006,47(16):5952-5964. |
| [27] | Tarascon J M, Armand M. Issues and challenges facing rechargeable lithium batteries[J]. Nature, 2001,414(6861):359-367. |
| [28] | 张拴芬. 纳米TiO2/PVDF-HFP微孔膜的制备及性能研究[D]. 太原:中北大学, 2013. |
| [29] | Masuda Y, Seki M, Nakayama M, et al. Study on ionic conductivity of polymer electrolyte plasticized with PEG-aluminate ester for rechargeable lithium ion battery[J]. Solid State Ionics, 2006,177:843-846. |
| [30] | Li J, Yao W, Martin S, et al. Lithium ion conductivity in single crystal LiFePO4[J]. Solid State Ionics, 2008,179(35/36):2016-2019. |
/
| 〈 |
|
〉 |
