适用于镁锂分离纳滤膜的筛选
收稿日期: 2019-10-20
网络出版日期: 2020-04-22
基金资助
青海省应用基础研究项目(2018-ZJ-916)
Screening of nanofiltration membrane for separation of magnesium and lithium
Received date: 2019-10-20
Online published: 2020-04-22
成琪 , 孟永涛 , 毕秋艳 , 马丽 , 关云山 . 适用于镁锂分离纳滤膜的筛选[J]. 无机盐工业, 2020 , 52(4) : 42 -48 . DOI: 10.11962/1006-4990.2019-0270
Nanofiltration membranes are widely used in various separation fields.There are many kinds of nanofiltration mem-branes on sale,and their separation performance varies greatly.Magnesium-lithium separation experiments were carried out on six kinds of nanofiltration membranes sold in the market：NT102,NT103,NT201,NF90,NF270 and XN-45.The separa-tion performance of the six kinds of nanofiltration membranes for magnesium-lithium was measured under different operating conditions by changing the dilution ratio,the ratio of magnesium to lithium,the temperature and the pH of raw liquid,and the operating pressure.Results showed that there were obvious differences of separation performance：NT201≈NT103>NF270≈XN-4>NF90≈NT102.NT201 and NT103 nanofiltration membranes showed the best separation performance for magnesium and lithium.
Key words： magnesium-lithium separation; nanofiltration membrane; screening
| [1] | Jaskula B W . Mineral commodity summaries:Lithium[R].U.S.Geo-logical Survey, 2014. |
| [2] | 杨晓婵 . 碳酸锂需求增长价格上扬[J].现代材料动态, 2013(1):10. |
| [3] | 邢佳韵, 彭浩, 张燕飞 , 等. 世界锂资源供需形势展望[J]. 资源科学, 2015,37(5):988-997. |
| [4] | 宋彭生, 项仁杰 . 盐湖锂资源开发利用及对中国锂产业发展的建议[J]. 矿床地质, 2014,33(5):977-992. |
| [5] | Bowen W R, Mukhtar H . Characterisation and prediction of separa-tion performance of nanofiltration membranes[J]. Journal of Mem-brane Science, 1996,112(2):263-274. |
| [6] | 王晓琳, 涂丛慧, 方彦彦 , 等. 纳滤膜孔结构、荷电性质、分离机理及动电性质研究进展[J]. 膜科学与技术, 2011,31(3):127-134. |
| [7] | Sun S Y, Cai L J, Nie X Y , et al. Separation of magnesium and lithi-um from brine using a Desal nanofiltration membrane[J].Journal of Water Process Engineering, 2015(7):210-217. |
| [8] | Li W, Shi C, Zhou A Y , et al. A positively charged composite nano-filtration membrane modified by EDTA for LiCl/MgCl2 separation[J]. Separation and Purification Technology, 2017,186:233-242. |
| [9] | 邢红, 王肖虎, 毛新宇 . 膜法盐湖卤水提锂工艺研究[J]. 盐业与化工, 2016,45(1):24-26. |
| [10] | 方建慧 . 纳滤膜在海水淡化中的应用研究[J]. 膜科学与技术, 2006,26(1):50-54. |
| [11] | Bargeman G, Vollenbroek J M, Straatsma J , et al. Nanofiltration of multi-component feeds.Interactions between neutral and charged components and their effect on retention[J]. Journal of Membrane Science, 2005,247(1):11-20. |
| [12] | 温现明 . 荷电膜在盐湖卤水中的传递性质研究[D]. 西宁:中国科学院研究生院(青海盐湖研究所), 2006. |
| [13] | Hoffer E, Kedem O . Hyperfiltration in charged membranes:the fixed charge model[J]. Desalination, 1967,2(1):25-39. |
| [14] | Simons R, Kedem O . Hyperfiltration in porous fixed charge mem-branes[J]. Desalination, 1973,13(1):1-16. |
| [15] | 朱安娜, 祝万鹏, 张玉春 . 纳滤过程的污染问题及纳滤膜性能的影响因素[J]. 膜科学与技术, 2003,23(1):43-49. |
| [16] | Sun Y L, Sun M H, Cheng W D , et al. The examination of water po-tentials by simulating viscosity[J]. Computational Materials Sci-ence, 2007,38(4):737-740. |
| [17] | Mohammad A W, Teow Y H, Ang W L , et al. Nanofiltration mem-branes review:Recent advances and future prospects[J]. Desalina-tion, 2015,356:226-254. |
| [18] | Manttari M, Pihlajamaki A, Nystrom M . Effect of pH on hydrophili-city and charge and their effect on the filtration efficiency of NF membranes at different pH[J]. Journal of Membrane Science, 2006,280:311-320. |
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