锂离子电池正极材料磷酸铁锂的研究进展
收稿日期: 2019-10-17
网络出版日期: 2020-04-22
基金资助
青海省自然青年基金资助项目(2019-ZJ-957Q);青海省自然青年基金资助项目(2018-ZJ-727)
Research progress of LiFePO4 cathode materials for Li-ion battery
Received date: 2019-10-17
Online published: 2020-04-22
王甲泰 , 赵段 , 马莲花 , 张彩虹 . 锂离子电池正极材料磷酸铁锂的研究进展[J]. 无机盐工业, 2020 , 52(4) : 18 -22 . DOI: 10.11962/1006-4990.2019-0240
LiFePO4 has the characteristics of high temperature stability,good cycle performance and environmental protection etc..It has become one of the cathode materials for lithium ion power batteries.However,due to the low electronic conductivity of LiFePO4 and the slow diffusion rate of lithium ions,the application of LiFePO4 in power battery industry is restricted. Therefore,it was summarized the improvement of LiFePO4 from three aspects：surface modification of LiFePO4 with carbon coated materials,doping LiFePO4,preparing submicron or nanometer LiFePO4 or the LiFePO4 with special morphology.The optimum method of improving LiFePO4 was analyzed and its development trend in the future was predicted.
Key words： Lithium ion battery; lithium iron phosphate; cathode material
| [1] | Padhi A K, Nanjundaswamy K S, Goodenough J B . Phospho-o-livi-nes as positive-electrode materials for rechargeable lithium batteri-es[J]. Journal of the Electrochemical Society, 1997,144(4):1188-1194. |
| [2] | Yoshino A . The birth of the lithium-ion battery[J]. Angewandte Che-mie International Edition, 2012,51(24):5798-5800. |
| [3] | Chung S Y, Bloking J T, Chiang Y M . Electronically conductive pho-spho-olivines as lithium storage electrodes[J]. Nature Materials, 2002,1(2):123-128. |
| [4] | Gao L, Xu Z, Zhang S . The co-doping effects of Zr and Co on struc-ture and electrochemical properties of LiFePO4 cathode materials[J]. Journal of Alloys and Compounds, 2018,739:529-535. |
| [5] | Wang Z H, Yuan L X, Ma J , et al. Electrochemical performance in Na-incorporated nonstoichiometric LiFePO4/C composites with cont-rollable impurity phases[J]. Electrochimica Acta, 2012,62:416-423. |
| [6] | Islam M S, Driscoll D J, Fisher C A J , et al. Atomic-scale investiga-tion of defects,dopants,and lithium transport in the LiFePO4 olivi-ne-type battery material[J]. Chemistry of Materials, 2005,17(20):5085-5092. |
| [7] | Qiao Y Q, Feng W L, Li J , et al. Ultralong cycling stability of carbon-nanotube/LiFePO4 nanocomposites as electrode materials for lithium-ion batteries[J]. Electrochimica Acta, 2017,232:323-331. |
| [8] | Tu X, Zhou Y, Song Y . Freeze-drying synjournal of three-dimensional porous LiFePO4 modified with well-dispersed nitrogen-doped carbon nanotubes for high-performance lithium-ion batteries[J]. Applied Surface Science, 2017,400:329-338. |
| [9] | Susantyoko R A, Alkindi T S, Kanagaraj A B , et al. Performance op-timization of freestanding MWCNT-LiFePO4 sheets as cathodes for improved specific capacity of lithium-ion batteries[J]. RSC Advan-ces, 2018,8(30):16566-16573. |
| [10] | Zhang Y, Xin P, Yao Q . Electrochemical performance of LiFePO4/C synthesized by sol-gel method as cathode for aqueous lithium ion batteries[J]. Journal of Alloys and Compounds, 2018,741:404-408. |
| [11] | Wu G, Liu N, Gao X , et al. A hydrothermally synthesized LiFePO4/C composite with superior low-temperature performance and cycle life[J]. Applied Surface Science, 2018,435:1329-1336. |
| [12] | Golestani E, Javanbakht M, Ghafarian-Zahmatkesh H , et al. Tarta-ric acid assisted carbonization of LiFePO4 synthesized through in situ hydrothermal process in aqueous glycerol solution[J]. Elec-trochimica Acta, 2018,259:903-915. |
| [13] | Lv C, Duan X, Deng J , et al. LiFePO4 mesocrystals coated with N-doped carbon from an ionic liquid for Li-ion batteries[J]. Cryst EngComm, 2017,19(9):1253-1257. |
| [14] | Wang X, Dong S, Wang H . Design and fabrication of N-doped gra-phene decorated LiFePO4@C composite as a potential cathode for electrochemical energy storage[J]. Ceramics International, 2018,44(1):464-470. |
| [15] | Xiong Q Q, Lou J J, Teng X J , et al. Controllable synjournal of N-C@LiFePO4 nanospheres as advanced cathode of lithium ion bat-teries[J]. Journal of Alloys and Compounds, 2018,743:377-382. |
| [16] | Dhaybi S, Marsan B, Hammami A . A novel low-cost and simple co-lloidal route for preparing high-performance carbon-coated LiFePO4 for lithium batteries[J]. Journal of Energy Storage, 2018,18:259-265. |
| [17] | Guan Y, Shen J, Wei X , et al. LiFePO4/activated carbon/grapheme composite with capacitive-battery characteristics for superior high-rate lithium-ion storage[J]. Electrochimica Acta, 2019,294:148-155. |
| [18] | Guan Y, Shen J, Wei X , et al. High-rate performance of a three-dimensional LiFePO4/graphene composite as cathode material for Li-ion batteries[J]. Applied Surface Science, 2019,481:1459-1465. |
| [19] | Wang Q, Peng D, Chen Y , et al. A facile surfactant-assisted self-assembly of LiFePO4/graphene composites with improved rate per-formance for lithium ion batteries[J]. Journal of Electroanalytical Chemistry, 2018,818:68-75. |
| [20] | Wang X, Dong S, Wang H . Design and fabrication of N-doped gra-phene decorated LiFePO4@C composite as a potential cathode for electrochemical energy storage[J]. Ceramics International, 2018,44(1):464-470. |
| [21] | Oh J, Lee J, Hwang T , et al. Dual layer coating strategy utilizing N-doped carbon and reduced graphene oxide for high-performance LiFePO4 cathode material[J]. Electrochimica Acta, 2017,231:85-93. |
| [22] | 毛佳宇, 肖杨 . 正极材料LiFePO4/C掺杂改性的研究进展[J]. 无机盐工业, 2016,48(1):13-16,34. |
| [23] | 谷和云, 李昇, 李二锐 , 等. 镁离子掺杂磷酸铁锂的制备及其电化学性能[J]. 无机盐工业, 2016,48(1):64-67. |
| [24] | Saroha R, Panwar A K, Sharma Y , et al. Development of surface functionalized ZnO-doped LiFePO4/C composites as alternative cathode material for lithium ion batteries[J]. Applied Surface Sci-ence, 2017,394:25-36. |
| [25] | Gao C, Zhou J, Liu G , et al. Synjournal of F-doped LiFePO4/C catho-de materials for high performance lithium-ion batteries using co-precipitation method with hydrofluoric acid source[J]. Journal of Alloys and Compounds, 2017,727:501-513. |
| [26] | Shi J Y, Zhang X Q, Zhang X K , et al. Titania and nitrogen-doped carbon co-modification:Their synergic effects on the electrochemi-chemical performance of LiFePO4[J]. Journal of Alloys and Compo-unds, 2018,750:139-146. |
| [27] | Madram A R, Faraji M . Site-dependent electrochemical performa-nce of Na and K co-doped LiFePO4/C cathode material for lithium-ion batteries[J]. New Journal of Chemistry, 2017,41(20):12190-12197. |
| [28] | Zhu J M, Xia T, Yan K K , et al. A novel Cu +-doped Li[Fe0.9Cu0.1Li0.1]PO4/C cathode material with enhanced electro-chemical properties [J]. RSC Advances, 2017,7(28):16984-16990. |
| [29] | Ren Yu, Bruce P G . Mesoporous LiFePO4 as a cathode material for rechargeable lithium ion batteries[J]. Electrochemistry Communi-cations, 2012,17:60-62. |
| [30] | Li Z, Peng Z, Zhang H , et al. [100]-Oriented LiFePO4 nanoflakes toward high rate Li-ion battery cathode[J]. Nano Letters, 2016,16(1):795-799. |
| [31] | Sun C, Rajasekhara S, Goodenough J B , et al. Monodisperse porous LiFePO4 microspheres for a high power Li-ion battery cathode[J]. Journal of the American Chemical Society, 2011,133(7):2132-2135. |
| [32] | Ma Z, Fan Y, Shao G , et al. In situ catalytic synjournal of high-grap-hitized carbon-coated LiFePO4 nanoplates for superior Li-ion bat-tery cathodes[J]. ACS Applied Materials & Interfaces, 2015,7(4):2937-2943. |
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