氧化铈掺杂氧化钇稳定氧化锆的热膨胀特性

Abstract

Abstract: Effect of CeO₂ doping on coefficient of thermal expansion of Y_0.06Zr_0.94O_1.97 (Y₂O₃-ZrO₂ compound) was studied.Ce_xY_0.06Zr_0.94-xO_1.97(0.08≤x≤0.16) compound was prepared via co-precipitation method.After pressing molding,the roasting temperatures were determined according to heat shrinkage curve of the sample.Samples were respectively sintered at 1 250,1 350,1 450 ℃ for 3 h in high-temperature electric resistance furnace.Their micro-structures were analyzed by XRD and SEM,and the coefficients of thermal expansion were measured by thermal expansion instrument.Results indicated that the coefficient of thermal expansion of Ce_xY_0.06Zr_0.94-xO_1.97(0.08≤x≤0.16) was higher than that ofY_0.06Zr_0.94O_1.97,because the constant of crystal lattice was increased and material′s chemical bonds were effectively weakened by doping CeO₂ in Y₂O₃-ZrO₂.

Key words: Ce_xY_0.06Zr_0.94-xO_1.97, co-precipitation, micro-structure, thermal expansion

CLC Number:

TQ174.75

ZHAO Wen-Guang, WANG Ze-Fei, ZHANG Hui-Feng, AN Sheng-Li. Thermal expansion performance of Y₂O₃-ZrO₂ doped with CeO₂[J]. INORGANICCHEMICALSINDUSTRY, 2011, 43(3): 21-.

[1]	Long Junxi,Xu Xuetang,Wang Fan. Preparation of porous CoFe LDH nanosheets electrocatalyst by low-temperature co-precipitation method [J]. Inorganic Chemicals Industry, 2020, 52(12): 98-103.
[2]	Xiong Fan,Wang Tongzhen,Gao Qiang,Cheng Fengru,Luo Xiqing. Study on Synthesis and electrochemical performance of Li₂MnO₃-LiNi_0.8Co_0.1Mn_0.1O₂ composite cathodes materials [J]. Inorganic Chemicals Industry, 2020, 52(1): 68-72.
[3]	Su Wei,Zhang Linfeng,Lü Qingyang,Xia Yuyan,Yuan Hua. Synthesis of diphenyl carbonate by oxidative carbonylation over palladium loaded MnO_x-based bimetallic oxide catalysis [J]. Inorganic Chemicals Industry, 2019, 51(9): 91-96.
[4]	Lü Pin,Shi Chunhui,Li Wei,Zhong Jianchu. Controllable synthesis and characterization of thermal stabilizer Mg-Al-LDHs [J]. Inorganic Chemicals Industry, 2019, 51(6): 29-33.
[5]	ZHANG Zheng-Guo. Preparation of ternary cathode material for lithium ion batteries assisted by surfactant [J]. INORGANICCHEMICALSINDUSTRY, 2015, 47(2): 67-.
[6]	CAO Xiao-Guo, WANG Jia, ZHANG Hai-Yan, WU Qi-Bai. Preparation of Yb:YAG nano-powder by co-precipitation method [J]. INORGANICCHEMICALSINDUSTRY, 2014, 46(6): 21-.
[7]	WANG Qiong, YU Hai-Bin, 南 Jun. Preparation of Mg-Al composite oxides catalysts and its use in acetone gas phase condensation for isophorone [J]. INORGANICCHEMICALSINDUSTRY, 2014, 46(5): 69-.
[8]	TONG Meng-Liang, SHU Jun-Jie, WANG Luo-Qiang. Preparation and performance study on Mg-Al-hydrotalcite [J]. INORGANICCHEMICALSINDUSTRY, 2014, 46(4): 22-.
[9]	ZHAO Hui-Jun, ZHANG Juan, FAN Ji-Wei. Preparation and magnetic performance of Mn-Zn ferrites by co-precipitation method [J]. INORGANICCHEMICALSINDUSTRY, 2011, 43(8): 39-.
[10]	ZHU Jing, LIU Yong-Guang, WANG Ling, ZHAO Yan-Qin, DONG Chan. Study on synthesis and perfermance of LiNi_1-2xCo_xMn_xO₂concentration-gradient cathode material [J]. INORGANICCHEMICALSINDUSTRY, 2011, 43(7): 19-.
[11]	LIU Dong, LIN Xiu-Zhou, ZHU Xiang-Ming, LUO Xiao-Gang. Preparation of Fe₃O₄ nanoparticles by impinging stream reactor [J]. INORGANICCHEMICALSINDUSTRY, 2011, 43(3): 18-.
[12]	XU Hai-Quan, LIANG Xiao-Juan, CHEN Jing, LIU Xiang-Nong, YANG Yu-Xiang. Preparation of mica/Fe₃O₄ pearlescent pigment by co-precipitation method [J]. INORGANICCHEMICALSINDUSTRY, 2011, 43(10): 25-.
[13]	He Wenxiu;An Shengli;Zhang Yongqiang;Wang Yaxiong;Xu Xia. Effect of Ce-Zr-La doping on performance of cobalt-based catalysts [J]. INORGANICCHEMICALSINDUSTRY, 2010, 0(8): 0-0.
[14]	Zhao Peng;Yao Caizhen;Fan Xiaoyong. Synthesis of Li4Ti5O12 by co-precipitation method and study on its performances [J]. INORGANICCHEMICALSINDUSTRY, 2010, 0(8): 0-0.
[15]	Zhang Wei;Dai Wenyong;Sun Jie. Application of MgO in Al2O3-SiO2 refractory material [J]. INORGANICCHEMICALSINDUSTRY, 2010, 0(7): 0-0.

National Inorganic Salts Information Center

Inorganic Acid-Base-Salt Committee of CIESC

Thermal expansion performance of Y₂O₃-ZrO₂ doped with CeO₂

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Metrics

Comments

Recommended 10

Thermal expansion performance of Y2O3-ZrO2 doped with CeO2

Knowledge

Cite this article

share this article

Thermal expansion performance of Y₂O₃-ZrO₂ doped with CeO₂