从浓缩盐湖卤水中萃取分离锂的实验研究

Abstract

Abstract:

Lithium was extracted by solvent extraction method from the concentrated high Mg/Li ratio brine from a salt lake in Qinghai Province,China.The influences of concentration of the extracting agent,the phase ratio of organic/aqueous（O/A）,the acidity[H ⁺] of brine and other related factors on lithium extraction efficiency were investigated systematically.The lithium-rich organic phase was back extracted and the influences of back extraction phase ratio and the concentration of HCl（back extractant） on the back extraction of lithium-loaded organic phase were also investigated.The extraction technology has a good application prospect for the separation of lithium from the high Mg/Li brine.

Key words: high Mg/Li brine, solvent extraction, lithium separation efficiency

CLC Number:

TQ131.11

Zhang Yongxing,Ma Yameng,Zhang Lizhen,Zhang Xiufeng,Tan Xiumin. Experimental research on extracting lithium from concentrated salt lake brine[J]. Inorganic Chemicals Industry, 2019, 51(3): 38-40.

Figures/Tables 4

References 11

[1]	高峰, 郑绵平, 乜贞 , 等. 盐湖卤水锂资源及其开发进展[J]. 地球学报, 2011,32(4):483-492.
[2]	冀康平 . 锂资源的开发与利用[J]. 无机盐工业, 2005,37(5):7-9.
[3]	王秋舒, 元春华, 许虹 . 全球锂矿资源分布与潜力分析[J]. 中国矿业, 2015,24(2):10-17.
[4]	谭秀民, 张永兴, 张利珍 , 等. 能源金属锂资源开发利用现状及发展建议[J].矿产保护与利用,2017(5):87-92.
[5]	刘跃龙, 陈文彦, 刘够生 . 中国矿山型锂矿资源分布及提取碳酸锂技术[J]. 无机盐工业, 2013,45(6):8-10.
[6]	李燕, 赵友璟, 王敏 . 纳滤技术在盐湖卤水镁锂分离领域的研究进展[J]. 无机盐工业, 2017,49(12):9-12.
[7]	孟庆伟, 张峰, 陈璐 , 等. 离子筛吸附与陶瓷膜耦合用于盐湖卤水提锂研究[J]. 化工学报, 2017,68(5):1899-1905.
[8]	张秀峰, 谭秀民, 张利珍 . 纳滤膜分离技术应用于盐湖卤水提锂的研究进展[J]. 无机盐工业, 2017,49(1):1-5.
[9]	朱慎林, 朴香兰, 缑泽明 . 中性磷类萃取剂从卤水中萃取锂的研究[J]. 清华大学学报:自然科学版, 2000,40(10):47-50.
[10]	陈正炎, 陈富珍, 古伟良 , 等. 从饱和氯化镁卤水萃取分离锂镁的相比研究[J]. 稀有金属, 1998,22(1):5-9.
[11]	叶帆 . 盐湖卤水萃取提锂及其机理研究[D]. 上海:华东理工大学, 2011.

[1]	Su Lei,Zhang Haijun,Wang Jin,Yu Xuefeng,Dong Changji,Sun Ze,Song Xingfu,Yu Jianguo. Study on preparation of molten salt grade potassium nitrate by reactive extraction method [J]. Inorganic Chemicals Industry, 2020, 52(5): 35-39.
[2]	Liao Xiaoting,Li Jun,Chen Ming. Process study on preparation of industrial grade ammonium dihydrogen phosphate from urea phosphate mother liquor [J]. Inorganic Chemicals Industry, 2020, 52(4): 79-83.
[3]	Zhou Xiumei，Sun Guixing. Optimization technology for stable operation of ammonium chloride crystal system in potassium dihydrogen phosphate production plant [J]. Inorganic Chemicals Industry, 2019, 51(12): 58-60.
[4]	CHEN Xi, LI Jun, JIN Yang, MO Shan, WU Shi-Qin. Research on demulsification by gravity sedimentation and stirring in emulsification solvent extraction process [J]. INORGANICCHEMICALSINDUSTRY, 2015, 47(5): 15-.
[5]	ZHANG Zhi-Qiang, ZHANG Cai-Mian, SUN Ying-Bo, TANG Qiang. Research on purification of wet process phosphoric acid by methyl isobutyl ketone [J]. INORGANICCHEMICALSINDUSTRY, 2014, 46(7): 20-.
[6]	JIANG Cai-Li, ZHENG Shao-Cong, ZHENG Yuan-Li, WANG Zhi-Juan. Preparation of potassium dihydrogen phosphate by triotylamine-isoamyl alcohol organic solvent extraction [J]. INORGANICCHEMICALSINDUSTRY, 2014, 46(2): 44-.
[7]	SUN Yi, LI Jun, ZHOU Kun, ZHANG Ya-Qing. Study on preparation of potassium dihydrogen phosphate from wet-process phosphoric acid by solvent extraction method [J]. INORGANICCHEMICALSINDUSTRY, 2013, 45(4): 34-.
[8]	ZHONG Ben-He, FANG Wei-Mao, LI Jun, YING Jian-Kang. Progress in purification technology（engineering） of wet process phosphoric acid in China [J]. INORGANICCHEMICALSINDUSTRY, 2013, 45(2): 8-.
[9]	ZHANG Zhi-Qiang, LIU Hai-Yang, XING Ying, LI Chun-Li, LI Hui-Fang, LIU Lin-Jun. Purification of wet-process phosphoric acid by solvent extraction with tri-n-butyl phosphate and diisopropyl ether [J]. INORGANICCHEMICALSINDUSTRY, 2012, 44(9): 42-.
[10]	YU Jian-Kun. Progress in synthesis of high purity lithium fluoride [J]. INORGANICCHEMICALSINDUSTRY, 2011, 43(5): 15-.
[11]	Chen Xuexi;Niu Weiwei;Du Lei. Study on the reflux extraction process of ammonium phosphate [J]. INORGANICCHEMICALSINDUSTRY, 2009, 0(11): 0-0.
[12]	Zhong Benhe;Li Jun;Guo Xiaodong;Wu Deqiao. Current research status and development direction of purification technology [J]. INORGANICCHEMICALSINDUSTRY, 2008, 0(2): 0-0.
[13]	Huang Peijin;Zhong Hui;Yang Siyi;Yang Jianyuan. Separation of strontium and calcium in production of inorganic chemicals [J]. INORGANICCHEMICALSINDUSTRY, 2008, 0(11): 0-0.

National Inorganic Salts Information Center

Inorganic Acid-Base-Salt Committee of CIESC

Experimental research on extracting lithium from concentrated salt lake brine

RichHTML

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

Figures/Tables 4

References 11

Related Articles 13

Metrics

Comments

Recommended 10