INORGANICCHEMICALSINDUSTRY ›› 2015, Vol. 47 ›› Issue (6): 70-.

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Regenerations of degradation products in anthraquinone process of hydrogen peroxide production over MgO/γ-Al2O3 catalysts

Zhao Jin,Yuan Enxian,Wang Li   

  1. Key Laboratory for Green Chemical Technology of Education Ministry,School of Chemical Engineering and Technology,Tianjin Universtiy,Collaborative Innovation Center of Chemical Science and Engineering (Tianjin),Tianjin 300072,China
  • Online:2015-06-10 Published:2015-05-22

Abstract: MgO/γ-Al2O3 catalysts were prepared by incipient wetness impregnation with γ-Al2O3  and Mg(NO3)2·6H2O as raw materials.XRD results showed that the position of characteristic diffraction peaks shifted to the low-angle direction,indica- ting the formation of MgAl2O4 phase on the surface of the γ-Al2O3  support.The regeneration reaction of degradation products (DP) and the transformation property of 2-ethyl-5,6,7,8-tetrahydro-9,10-anthrahydroquinone(H4EAQ) over MgO/γ- Al2O3  catalysts were carried out at atmospheric pressure and 50 ℃.The MgO/γ-Al2O3  catalysts exhibited the higher catalytic activity than γ-Al2O3 .The amounts of DP regeneration and H4EAQ transformation increased with increasing the MgO loading mass in MgO/Al2O3 catalysts and both they reached the maximum at the MgO mass fraction of 30%,together with the improvement in the DP regeneration and H4EAQ transformation of 54% and 231%,respectively,compared with γ-Al2O3 .

Key words: anthraquinone process;hydrogen peroxide;regeneration;degradation products;MgO/&gamma, -Al2O3