INORGANICCHEMICALSINDUSTRY ›› 2013, Vol. 45 ›› Issue (8): 21-.

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Experimental study on a new ammonia removal process in potassium carbonate production

Hu Baisong1,Zhang Fan2,Zhao Jingli1   

  1. 1.Hebei University of Technology,Tianjin 300130,China;2.Shijiazhuang Information Engineering Vocational College
  • Online:2013-08-10 Published:2013-08-14

Abstract: The ammonia is removed by evaporation in the existing potassium carbonate production process.As the ammonia cannot be removed completely,heat transfer of evaporator is decreased when a lot of NH3 and CO2 in the secondary steam,and evaporation energy consumption is increased accordingly.On the other hand,it is difficult to collect the volatilized NH3 and CO2,resulting in waste of resources and the increasing of production cost.The desorption method,a new ammonia removal process was introduced and the influence factors,such as temperature of solution,air/liquid ratio,trickle density,air-stripping time,and initial concentration,were investigated.Results showed that quantitatively,the initial temperature of solution,air/liquid ratio,trickle density,and air-stripping time has the greater influence on ammonium bicarbonate′s decomposition, whereas the initial concentration does not.The optimum technological parameters were determined as follows:the initial temperature of the solution was 85 ℃,air/liquid volume ration was 30∶1,trickle density was 55 m3/(m2·h),and air-stripping time was 2.5 h.Under the optimum conditions,the eliminated rate of ammonia was 95.48%.

Key words:  , potassium carbonate;ion exchange;desorption;ammonia removal

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