无机盐工业
主管:中海油天津化工研究设计院有限公司
主办:中海油天津化工研究设计院有限公司
   中海油炼油化工科学研究院(北京)有限公司
   中国化工学会无机酸碱盐专业委员会
ISSN 1006-4990 CN 12-1069/TQ

无机盐工业 ›› 2019, Vol. 51 ›› Issue (11): 88-96.doi: 10.11962/1006-4990.2018-0672

• 90 • 上一篇    

加氢精制催化剂载体脱钠工艺研究

张玉婷,张国辉,朱金剑,宋国良,张尚强,张景成,肖 寒,彭雪峰   

  1. 中海油天津化工研究设计院有限公司,天津 300131
  • 出版日期:2019-11-10 发布日期:2020-02-28
  • 作者简介:张玉婷(1983— ),女,硕士研究生,高级工程师,主要研究方向为炼油催化,已公开发表文章4篇;E-mail:zhuyb8@cnooc.com.cn。

Study on process of removing sodium from hydrogenation refining agent carrier

Zhang Yuting,Zhang Guohui,Zhu Jinjian,Song Guoliang,Zhang Shangqiang, Zhang Jingcheng,Xiao Han,Peng Xuefeng   

  1. CNOOC Tianjin Chemical Research & Design Institute Co.,Ltd.,Tianjin 300131,China
  • Published:2019-11-10 Online:2020-02-28

摘要: 采用多级离子交换法对加氢精制催化剂载体进行脱钠处理,考察了铵盐种类、浸泡时间、交换温度和铵盐浓度对脱钠效果的影响。以浸泡时间、交换温度和铵盐浓度3个主要影响因素做Box-Behnken实验设计,钠含量为响应函数,建立相应数学模型。实验结果表明,脱钠效果较优的铵盐为乙酸铵。最佳工艺条件:浸泡时间为60 min、交换温度为60 ℃、铵盐质量分数为5.5%。Box-Behnken实验设计法用于加氢精制催化剂载体脱钠工艺优化是可行的,数学模型的预测值与实验观察值相符。

关键词: 离子交换法;加氢精制催化剂载体;脱钠;Box-Behnken实验设计

Abstract: The method of multi stage ionexchange was used to remove sodium from hydrogenation refining agent carrier.The effect of factors,such as ammonium salts,soaking time,exchange temperature and ammonium salt concentration,were investi gated.The Box-Behnken experiment design was carried out with three main influencing factors: soaking time,exchange tempera ture and ammonium salt concentration.The sodium content was the response function and the corresponding mathematical model was established. Results showed that the ammonium salt with better removing sodium effect was ammonium acetate.The best experimental conditions were as follows:the soaking time was 60 min,the exchange temperature was 60 ℃and the mass frac tion of ammonium salt was 5.5%.Removing sodium from the hydrogenation refining agent carrier by Box-Behnken experiment design is feasible,and the prediction values of the mathematical model are in line with the experimental observation.

Key words: ion exchange method;hydrogenation refining agent carrier;sodium removal;Box-Behnken experiment design

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