无机盐工业
主管:中海油天津化工研究设计院有限公司
主办:中海油天津化工研究设计院有限公司
   中海油炼油化工科学研究院(北京)有限公司
   中国化工学会无机酸碱盐专业委员会
ISSN 1006-4990 CN 12-1069/TQ

无机盐工业 ›› 2020, Vol. 52 ›› Issue (2): 35-37.doi: 10.11962/1006-4990.2019-0177

• 研究与开发 • 上一篇    下一篇

活性炭模板制备铝酸铁及其在软PVC中的阻燃应用

陈灵智,刘娜,孙会娟,吴瑞红   

  1. 衡水学院应用化学系,河北衡水 053000
  • 收稿日期:2019-08-10 出版日期:2020-02-10 发布日期:2020-02-26
  • 作者简介:陈灵智(1980— ),女,博士,讲师,无机阻燃剂及阻燃材料的研发;E-mail:chenlingzhi80@126.com。
  • 基金资助:
    衡水学院高层次人才启动基金项目(2018GC07);河北省科技计划资助项目(17211414)

Preparation of iron aluminate with activated carbon template and its flame retardant application on flexible PVC

Chen Lingzhi,Liu Na,Sun Huijuan,Wu Ruihong   

  1. Department of Applied Chemistry,Hengshui University,Hengshui 053000,China
  • Received:2019-08-10 Published:2020-02-10 Online:2020-02-26

摘要:

以硫酸铁和硫酸铝为原料,以磷酸处理过的活性炭为模板制备铝酸铁阻燃剂。并通过X射线衍射(XRD)和红外吸收光谱(FT-IR)对合成铝酸铁阻燃剂做了表征。用极限氧指数、烟密度测试其对PVC的阻燃消烟性,当铝酸铁阻燃剂的添加量为5%(质量分数)时,阻燃后软PVC的极限氧指数达到32.8%,烟密度等级为55.45%,拉伸强度为18.36 MPa,断裂伸长率为214%,并通过热重分析对阻燃前后PVC的热降解行为做了研究。结果表明:以活性炭为模板制备的铝酸铁阻燃剂对软质PVC具有较好的阻燃消烟性能。

关键词: 铝酸铁, 软PVC, 消烟, 阻燃

Abstract:

With iron sulfate and aluminum sulfate as raw materials,iron aluminate flame retardant was prepared using acti-vated carbon treated with phosphoric acid as template.The prepared iron aluminate was investigated by X-ray diffraction(XRD) and infrared spectroscopy(FT-IR).The flame retardant and smoke dissipation property of iron aluminate flame retar-dant on flexible polyvinyl chloride(PVC) were characterized by the limiting oxygen index test(LOI) and smoke density test(SDR).The results showed when the amount of 5%(mass fraction) iron aluminate was used,LOI and SDR was 32.8% and 55.45%,respectively,tensile strength was 18.36 MPa,elongation was 214%.The thermal degradation of flame retardant PVC were studied by using thermal analysis(TG).The results demonstrated that iron aluminate can be used as a highly effective flame retardant for flexible PVC.

Key words: iron aluminate, flexible PVC, smoke dissipation, flame retardant

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