关键词: 3次纳米自组装, 主客体催化材料, 共浸剂, 反应活性

Abstract: Low-temperature nitrogen adsorption method，XPS，and FT-IR spectroscopy of adsorbed CO techniques were used to analyze the macroporous host-guest catalytic materials prepared according to the principle of the third nano self-assembly. Result showed that the host-guest catalytic materials had excellent physical properties.The analysis of infrared spectra indicated，the series of host-guest nano catalytic materials mainly for line type CO adsorption state and with the increase of co-infusion agent，it was helpful for  the strong interaction between the catalyst and the active component Mo and Ni conversion activity；while XPS confirmed from the side of the valence sulfides in Mo and its existing forms，when the content of co-infusion agent increased from criterion+20 to criterion+30，the proportion of Mo4+ increased from 73.63% to 80.01%； The catalytic material FA70-Z30′s hydrogenation evaluation showed that the conversation rates of HDS，HDN，and HDAr reached 81.3%，47.6%，and 55.8%，respectively，and it had a better coking inhibition and hydrogenation performance.

Key words: third nano self-assembly, host-guest catalytic material, co-infusion agent, reaction activity