无机盐工业
主管:中海油天津化工研究设计院有限公司
主办:中海油天津化工研究设计院有限公司
   中海油炼油化工科学研究院(北京)有限公司
   中国化工学会无机酸碱盐专业委员会
ISSN 1006-4990 CN 12-1069/TQ

无机盐工业 ›› 2015, Vol. 47 ›› Issue (2): 39-.

• 论文 • 上一篇    下一篇

氧化锆纤维对纳米SiO2复合绝热材料性能的影响

张成贺1,袁玉珍1,李呈顺2,刘 超2,刘俊成1,王翠玲2   

  1. 1.山东理工大学,山东淄博 255049;2.山东鲁阳股份有限公司
  • 出版日期:2015-02-10 发布日期:2015-03-02

Effect of ZrO2 fibers on performance of nano-sized SiO2 composite insulation materials

Zhang Chenghe1,Yuan Yuzhen1,Li Chengshun2,Liu Chao2,Liu Juncheng1, Wang Cuiling2   

  1. 1.Shandong University of Technology,Zibo 255049,China;2.Shandong Luyang Co.,Ltd.
  • Published:2015-02-10 Online:2015-03-02

摘要: 针对纳米二氧化硅复合绝热材料强度不高、高温环境下收缩严重的问题,采用氧化钇稳定的氧化锆纤维作为功能性添加材料,研究了不同煅烧温度下氧化锆纤维的添加量对绝热材料线收缩率的影响,以及引入氧化锆纤维对绝热材料耐压强度的影响,结合SEM等表征方法及固体烧结动力学理论阐释了氧化锆纤维的增强和抑制绝热材料高温收缩的机理。结果表明:煅烧温度高时,绝热材料线收缩率大。氧化锆纤维的添加能有效降低绝热材料的高温线收缩率。当添加量为6%(质量分数)时,1 000 ℃下线收缩率从13.3%降至2.6%。随着氧化锆纤维添加量的增加,绝热材料的耐压强度先增大后减小。

关键词: 纳米二氧化硅复合绝热材料, 氧化锆纤维, 线收缩率

Abstract: ZrO2 fibers stabilized by Y2O3 as functional additives were adoped into nano-sized SiO2 composite insulation materials to improve the compressive strength and reduce the linear shrinkage at high temperatures.The effects of the mass ratio of ZrO2 fibers on linear shrinkage at different calcination temperatures were investigated.And the effect of ZrO2 fibers on compressive strength was also analyzed.The mechanisms of increasing strength and shrinkage restraint were illuminated by the kinetics of solid sintering and characteristic methods of SEM and so on. Results showed that the linear shrinkage of the insulation materials was high at the high calcination temperature.The additive of ZrO2 fibers could significantly reduce the linear shrinkage.When the mass ratio of addition amount was 6%(mass fraction),the linear shrinkage decreased from 13.3% to 2.6% at 1 000 ℃.The compressive strength of the insulation materials increased at first and then decreased with the increasing amount of ZrO2 fibers.

Key words: nano-sized SiO2 composite insulation materials, ZrO2 fibers, linear shrinkage

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