无机盐工业
主管:中海油天津化工研究设计院有限公司
主办:中海油天津化工研究设计院有限公司
   中海油炼油化工科学研究院(北京)有限公司
   中国化工学会无机酸碱盐专业委员会
ISSN 1006-4990 CN 12-1069/TQ

无机盐工业 ›› 2012, Vol. 44 ›› Issue (12): 40-.

• 论文 • 上一篇    下一篇

植物副产物浸出分离氧化型锰银矿的研究

余丽秀1,孙亚光2,张 然1,宋广毅1   

  1. 1.中国地质科学院郑州矿产综合利用研究所,河南郑州 450006;
    2.河南工业大学材料科学与工程学院
  • 发布日期:2012-12-11

Study on leaching separation of oxidized manganese-silver ore with plant by-product

Yu Lixiu1,Sun Yaguang2,Zhang Ran1,Song Guangyi1   

  1. 1.Zhengzhou Institute for Multipurpose Utilization of Mineral Resources,CAGS,Zhengzhou 450006,China;
    2.School of Material Science and Engineering,Henan University of Technology
  • Online:2012-12-11

摘要: 介绍了利用植物副产物(秸秆、粮食加工副产壳类等)作为还原剂还原浸出氧化型锰银精矿中的锰、浸锰渣氰化浸银的锰银分离工艺。玉米秸秆还原浸锰条件:秸秆粉在95 ℃预降解糖化0.5 h、降解糖化液与精矿的体积质量比为3 mL/g、硫酸与锰的物质的量比为1.4、秸秆与精矿的质量比为0.275、95 ℃浸出5 h,在此条件下锰的浸出率约92%。浸锰渣氰化浸银条件:每吨浸锰渣氰化钠用量为3 kg、常温浸银3 h,在此条件下银的浸出率达到92.20%。研究的锰银分离工艺具有较好的综合效果。

关键词: 锰银矿, 植物副产物, 还原浸锰, 浸锰渣浸银

Abstract: The manganese-silver separation process,which uses plant by-product(straw and husk by-produced from grain processing etc.) as reducing agent for reduction leaching manganese in manganese-silver concentrate and for silver leaching from residue of manganese-leaching with cyanide was introduced.The conditions of corn straw reduction leaching manganese were as follows:straw powder pre-degradation and saccharification at 95 ℃ for 0.5 h,volume-mass ratio of degradation saccharification liquid to manganese-silver concentrate was 3 mL/g,amount of substance ratio-of-sulfuric acid to manganese was 1.4,mass ratio of straw to ore powder was 0.275,and leaching temperature and time were 95 ℃ and 5 h,respectively.The manganese leaching rate was about 92% under those conditions.Ag leaching rate of 92.20% could be achieved under the conditions when the dosage of NaCN was 3 kg per ton of the residue of manganese-leaching and the leaching temperature and time were room temperature and 3 h,respectively.The separation technology of manganese and silver had a very good comprehensive effect.

Key words: manganese-silver ore, plant by-product, reduction leaching of manganese, leaching silver from manganese slag

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