INORGANICCHEMICALSINDUSTRY ›› 2016, Vol. 48 ›› Issue (4): 57-.

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Thermodynamic analysis of reductive reaction of phosphogypsum with pyrite

Luo Shufeng1,Fu Quanjun2,Ma Xianlin1,Chen Wei2,Zhang Zhiye3,Wang Xinlong3,Yang Lin3,Sheng Yong2   

  1. 1.Sinochem Yunlong Co.,Ltd.,Kunming 655204,China;2.Sinofert Chengdu Research & Development
    Center;3.College of Chemical Engineering,Sichuan University
  • Online:2016-04-10 Published:2016-04-27

Abstract: Thermodynamic calculation software HSC Chemistry was used to analyze the reductive reaction of phosphogypsum as a kind of pollution from phosphorus chemical industry with pyrite.The decomposition temperature and phase composition at different temperatures were explored,and the results were compared with that of reductive reaction of phosphogypsum with pyrite.XRD results of the reductive reaction of phosphogypsum showed the products were Ca2Fe2O5 and CaO,and it was consistent with analog computation.It concluded that chemical thermodynamic equilibrium analysis could be used to study the reductive reaction characteristics of phosphogypsum with pyrite.

Key words: phosphogypsum, pyrite, HSC Chemistry, thermodynamic calculation

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