固废源钙基碳捕集剂制备及抗烧结性研究进展

doi:10.19964/j.issn.1006-4990.2022-0174

摘要/Abstract

摘要：

温室气体二氧化碳大量排放导致全球气候变暖，碳捕集成为当前重要的任务。利用大宗工业固体废弃物作为生产二氧化碳吸附剂的原料，不仅能有效缓解温室效应，而且原料价格低廉，又多位于二氧化碳排放源，可实现大宗固体废弃物的减量化、资源化。综述了钙基二氧化碳吸附材料的吸附机理及应用工艺流程。总结和比较了具有代表性和可用的工业固体废弃物（电石渣、钢渣、粉煤灰）的直接碳化潜力。介绍了几种提高吸附剂吸附性能的改性方法，包括水合改性、酸改性、掺杂改性等，并且对更适合工业应用的造粒工艺进行了简述，以期为高性能工业固体废弃物二氧化碳捕集材料的开发与应用提供重要的理论和技术支持，为研究人员进一步了解其技术进步和发展趋势提供参考。

关键词: 工业固体废弃物, 钙基, 二氧化碳捕集, 抗烧结

Abstract:

The massive emission of greenhouse gas CO₂ leads to global warming，and carbon capture has become an important task at present.The use of bulk industrial solid wastes as the raw materials for the production of CO₂ adsorbents can not only effectively alleviate the greenhouse effect，but also is cheap and mostly located in the source of CO₂ emissions，realizing the reduction and recycling of bulk solid waste.The adsorption mechanism and application process of calcium-based CO₂ adsorption materials were reviewed，the direct carbonization potential of the most representative and available industrial solid wastes（carbide slag，steel slag，fly ash） were summarized and compared，and several modification methods to improve the adsorption performance of adsorbents were introduced，including hydration modification，acid modification，doping modification，etc.，and the granulation process more suitable for industrial application was briefly described.It was expected to provide important theoretical and technical support for the development and application of high-performance industrial solid waste CO₂ capture materials，and provide reference for researchers to further understand its technical progress and development trends.

Key words: industrial solid waste, calcium-based, carbon dioxide capture, sintering resistance

中图分类号:

X756

季洪峰, 李灿华, 都刚, 张永柱, 徐文珍, 李明晖. 固废源钙基碳捕集剂制备及抗烧结性研究进展[J]. 无机盐工业, 2023, 55(3): 28-35.

JI Hongfeng, LI Canhua, DU Gang, ZHANG Yongzhu, XU Wenzhen, LI Minghui. Research progress of preparation and sintering resistance of calcium-based CO₂trapping materials from solid waste sources[J]. Inorganic Chemicals Industry, 2023, 55(3): 28-35.

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钙前驱体	改性方法	煅烧温度/℃	吸附温度/℃	循环次数	φ（CO₂）/ %	CO₂转化率/%
电石渣^[24]	—	840	700	20	15	30
电石渣^[25]	—	900	700	100	15	27
电石渣^[26]	丙酸	850	700	20	15	40
电石渣^[27]	掺杂Al	840	700	20	15	48
电石渣^[28]	掺杂Mg、Mn	900	700	10	15	52*
电石渣^[30]	掺Al造粒	850	650	25	15	52.64

钙前驱体	改性方法	煅烧温度/℃	吸附温度/℃	循环次数	φ（CO₂）/ %	CO₂转化率/%
钢渣^[35]	—	—	—	—	100	0.933 9
钢渣^[36]	H₂O	1 000	500	—	15	5.836
钢渣^[40]	CH₃COOH	1 000	400	—	100	3.08
钢渣^[42]	NH₄Cl	1 000	400	—	100	12.26
钢渣^[41]	CH₃COOH	900	700	20	15	15*
钢渣^[43]	CH₃COOH、Al	900	700	10	15	40*

钙前驱体	改性方法	煅烧温度/℃	吸附温度/℃	循环次数	φ（CO₂）/ %	CO₂转化率/%
粉煤灰^[47]	—	—	—	1	250 mL/min	0.84
粉煤灰^[49]	CaO	900	700	30	15	41
粉煤灰^[50]	柠檬酸 CaO	900	600	20	15	22
粉煤灰^[51]	CaO 高铝水泥	950	700	30	15	35

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